Biofuel cell capable of directly oxidizing glucose and preparation method of biofuel cell

A biofuel cell, glucose oxidation technology, applied in biochemical fuel cells, battery electrodes, circuits, etc., can solve the problems of expensive electron transfer intermediates, short running time, low open circuit voltage, etc. The preparation method is simple and the effect of improving the power density

Active Publication Date: 2016-02-24
CHENGDU WISEDONE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, while more and more scholars are participating in this research field, the development of glucose biofuel cells is also facing bottlenecks. The bottlenecks are mainly manifested in two aspects: the output power of most glucose biofuel cells is still low and unstable. ;Most systems need to add electron transfer intermediates to improve electricity production capacity, but electron transfer intermediates are expensive and toxic, not suitable for development needs
In addition, microorganisms or enzymes are used as catalysts, although they are widely available and low in cost, but their activity is limited and the running time is short, for example, the survival time of enzymes in acetate buffer is only 8 hours to 2 days
Chinese patent application CN102569861A discloses an enzymatic biofuel cell, which adopts phenolic proton exchange membrane, and uses graphene-nano-gold composites to support laccase and glucose oxidase as catalysts for the cathode and anode respectively, although the battery run cycle, but its output power is still low
Enzyme biofuel cells represent an emerging energy source, but there are still many problems to be solved, such as low open circuit voltage, low output power, and short-term operation stability

Method used

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  • Biofuel cell capable of directly oxidizing glucose and preparation method of biofuel cell

Examples

Experimental program
Comparison scheme
Effect test

example 1

[0056] Example 1: Preparation of anode and cathode

[0057] Select the porous metal nickel mesh disk (diameter is 5cm) and clean the porous metal nickel mesh disk with acetone for 5 minutes, then use 6mol / L hydrochloric acid etching treatment for 15 minutes, then use ultrapure water to carry out ultrasonic cleaning, and finally Blow dry with a stream of nitrogen gas until ready to use.

[0058] The porous metal nickel mesh after the above treatment was put into 2 mmol / L silver nitrate solution and soaked for 30 minutes to prepare a nickel mesh electrode loaded with silver nanoparticles. Before assembling the biofuel cell, the nickel mesh electrode loaded with nano-silver particles was cleaned with ultrapure water, and then stored in 2 mol / L potassium hydroxide solution for later use.

[0059] Among them, the scanning electron microscope photos of the porous metal nickel mesh are as follows: Figure 2A and Figure 2B As shown, the scanning electron micrograph of the nickel m...

example 2

[0061] PEEK anion exchange membrane (Fumasep TM FAB, with a thickness of 100um) acts as a diaphragm between the anode chamber and the cathode chamber. The anolyte is a KOH buffer solution saturated with nitrogen gas with a concentration of 0.5mol / L, and the concentration of glucose is 0.5mol / L; the catholyte is a KOH buffer solution of 0.5mol / L, which contains saturated oxygen and the flow rate of oxygen It is 100sscm.

[0062] The nickel mesh electrode loaded with nano-silver particles prepared in Example 1 is used as an anode and a cathode and packed into the anode chamber and the cathode chamber respectively and connected to the anode and the cathode with an external circuit, and the direct oxidation of glucose is obtained after adding the above-mentioned anolyte and catholyte biofuel cell.

[0063] When testing the output power curve of the direct oxidation glucose biofuel cell in this example, let the battery run for a period of time to obtain a stable open circuit volt...

example 3

[0066] The nickel mesh electrode loaded with silver nanoparticles prepared in Example 1 was used as the anode and cathode and a biofuel cell was assembled according to Example 2, wherein the concentration of glucose in the anolyte was 0.1 mol / L.

[0067] The voltage-current curve and power density-current curve of the direct oxidation glucose biofuel cell in this example are shown in Figure 4 , open circuit voltage and battery internal resistance curves see Figure 5 . In this example, the concentration of glucose is 0.1 mol / L, and the results obtained in the polarization curve, power density curve and open circuit voltage are lower than those in Example 2.

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Abstract

The invention discloses a biofuel cell capable of directly oxidizing glucose and a preparation method of the biofuel cell. The biofuel cell comprises an anode chamber, a cathode chamber, a membrane for separating the anode chamber and the cathode chamber, and an outer circuit for connecting an anode in the anode chamber and a cathode in the cathode chamber; fuel in the anode chamber is the glucose; fuel in the cathode chamber is oxygen; the anode and the cathode are nickel net or copper net electrodes loaded with nano silver particles. The preparation method comprises the following steps of preparing an electrode, preparing electrolyte, assembling the biofuel cell and the like. The biofuel cell capable of directly oxidizing the glucose, provided by the invention, takes the nickel net or copper net electrodes loaded with the nano silver particles as the anode and the cathode, so that the power density of the cell is effectively improved, and the stability of the biofuel cell under different temprature conditions and different loading conditions is also guaranteed; the preparation method of the biofuel cell is relatively simple and easy, low in cost and is convenient to popularize and apply.

Description

technical field [0001] The invention relates to the technical field of biofuel cells, in particular to a direct oxidation glucose biofuel cell and a preparation method thereof. Background technique [0002] With the continuous shortage of energy in the future and the increasingly serious environmental crisis, it is becoming more and more important to develop new renewable energy sources that do not pollute the environment to replace oil, coal and other major fuels today. Obtaining energy from the environment to drive electronic devices has always been the dream of all mankind. As a new type of renewable energy, glucose biofuel cells can be directly converted into electrical energy under the catalysis of microorganisms or enzymes, with high energy conversion efficiency. ;It can operate effectively in remote and low temperature environments, and has strong environmental adaptability; the power generation process is green and environmentally friendly, and at most only produces ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/16H01M4/90
CPCH01M4/9041H01M8/16Y02E60/50
Inventor 吴桐惠志锋
Owner CHENGDU WISEDONE TECH
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