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Compound corrosion and scale inhibitor

A technology of corrosion and scale inhibitors and compound preparations, which is applied in the fields of scale removal and water softening, special treatment targets, water/sludge/sewage treatment, etc. It is difficult to pre-membrane effect and other issues, to achieve the effect of reducing power consumption, reducing the amount of supplementary water, and saving power consumption

Inactive Publication Date: 2016-04-20
HEBEI AGRICULTURAL UNIV. +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, most of the water treatment chemicals used at home and abroad are organic phosphine series chemicals, and the concentration ratio of this series of chemicals is generally below 5, resulting in a large waste of water resources
The corrosion inhibition effect of existing solid scale inhibitors on carbon steel generally cannot meet the national standard of carbon steel corrosion rate of 0.1-0.2mm / year, and in order to increase the corrosion inhibition effect of solid agents, the system is often required to be pre-coated and the temperature reaches 40 ~ 60 ℃, and the amount of cooling water is often large, it is difficult to pre-film in advance, and it is difficult to ensure that the pre-film effect meets the technical requirements

Method used

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  • Compound corrosion and scale inhibitor

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] Composite corrosion and scale inhibitors include liquid preparation A and liquid preparation B, wherein: the weight ratio of each component of liquid preparation A is: 5 g of hydroxyethylidene diphosphonic acid, 5 g of potassium aminotrimethylene phosphonate, hydrolyzed polymaleic anhydride 5g, 5g of maleic acid-acrylic acid copolymer, 15g of DISPERBYK series dispersant of German BYK company, 65g of water, put it into a beaker and stir evenly.

[0048] Liquid preparation B is a composite preparation made of solid medicament and water at a weight ratio of 1:1, wherein the weight ratio of solid medicament is: sodium humate 15g, sodium carbonate 25g, mercaptobenzothiazole 5g, zinc sulfate 5g, and It is put in a container and mixed with 50 g of water to prepare 100 g of liquid preparation B, and it can be stirred evenly.

[0049] Experimental water quality: make up water quality, calcium hardness is 350mg / L, total alkalinity is 350mg / L, chloride ion (Cl - ) content is 80mg...

Embodiment 2

[0081] The composite corrosion and scale inhibitor of the present invention includes liquid preparation A and liquid preparation B, wherein: the weight ratio of each component of liquid preparation A is: 5 g of hydroxyethylidene diphosphonic acid, 10 g of potassium aminotrimethylene phosphonate, hydrolysis poly Add 5 g of maleic anhydride, 10 g of acrylic acid-hydroxypropyl acrylate copolymer, 20 g of Elvacite series dispersants from DuPont, USA, and 50 g of water into a beaker and stir evenly.

[0082] Liquid preparation B is a compound preparation made of solid medicine and water at a weight ratio of 1:1, wherein the weight ratio of solid medicine is: sodium humate 12.5g, sodium carbonate 25g, mercaptobenzothiazole 5g, zinc sulfate 7.5g , put it in a container and mix with 50g of water to prepare 100g of liquid preparation B, and stir evenly.

[0083] Experimental water quality: make up water quality, calcium hardness is 300mg / L, total alkalinity is 300mg / L, chloride ion (Cl...

Embodiment 3

[0088] The composite corrosion and scale inhibitor of the present invention includes liquid preparation A and liquid preparation B, wherein: the weight ratio of the components of liquid preparation A is: 15 g of hydroxyethylidene diphosphonic acid, 10 g of potassium aminotrimethylene phosphonate, hydrolyzed Add 10g of polymaleic anhydride, 10g of maleic acid-acrylic acid copolymer, 25g of Disperse-AYD series W-22 type, and 30g of water, put them into a beaker and stir evenly.

[0089] Liquid preparation B is a composite preparation made of solid medicament and water at a weight ratio of 1:1, wherein the weight ratio of solid medicament is: sodium humate 5g, sodium carbonate 30g, mercaptobenzothiazole 5g, zinc sulfate 10g, It is put in a container and mixed with 50 g of water to prepare 100 g of liquid preparation B, and it can be stirred evenly.

[0090] Experimental water quality: make up water quality, calcium hardness is 250mg / L, total alkalinity is 250mg / L, chloride ion (C...

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Abstract

The invention provides a compound corrosion and scale inhibitor. The compound corrosion and scale inhibitor is a liquid preparation which is prepared by mixing a first liquid preparation with a second liquid preparation according to the ratio of 1:1; a compound preparation prepared from organic phosphonic acid, polycarboxylic acid, a dispersing agent and water is adopted as the first liquid preparation; a compound preparation prepared from solid agentia and water according to the weight ratio of 1:1 is adopted as the second liquid preparation, wherein a compound preparation which has the scale inhibition effect and is prepared from polymers, an alkaline agent, azoles and zinc salt is adopted as the solid agentia. The compound corrosion and scale inhibitor can achieve the effects of corrosion inhibition, scale inhibition and sterilization and algae removal which meet the national requirements, can be applied to a circulating cooling water system with the high concentration multiple, is convenient to put, does not need to be prefilmed, can be used at normal temperature and is good in using effect.

Description

technical field [0001] The invention relates to a water treatment agent for circulating water, in particular to a composite corrosion and scale inhibitor for treating circulating water with high concentration multiples, and is used for the treatment of circulating water with high concentration multiples (K>8). Background technique [0002] The recycling of industrial cooling water not only greatly saves production water consumption, reduces water pollution, but also greatly reduces the operating costs of enterprises. However, cooling water is easy to breed bacteria, fungi, algae, protozoa and other microorganisms during the circulation process. The mineral content in the water will also continue to increase and concentrate, eventually causing scaling and corrosion of production equipment and pipelines. The existence of dirt will not only affect the heat transfer efficiency, but also cause corrosion under scale. Therefore, cooling water must be dosed with chemical agents w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/14
CPCC02F5/14C02F2303/08
Inventor 张小燕张立勇郭华王立军李德忠刘俊良王卫兵李景
Owner HEBEI AGRICULTURAL UNIV.
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