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Flexible wearable electrode and preparation method therefor

An electrode and flexible technology, applied in the field of electrodes, can solve the problems of battery short circuit, combustion, explosion, etc., and achieve the effect of easy operation and simple equipment

Inactive Publication Date: 2016-07-27
GUANGZHOU TINGYU ENERGY TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the current production process, the material electrode is loaded on the polymer fluid in the form of coating. Therefore, if the traditional process technology is used to make a flexible battery, the positive electrode material loaded on the metal film will be damaged due to repeated extrusion. It will be detached from the metal film due to pressure, which will affect the capacity and service life of the battery at the slightest, and cause the internal short circuit of the battery, which will cause combustion or even explosion.

Method used

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  • Flexible wearable electrode and preparation method therefor

Examples

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Effect test

Embodiment 1

[0036] Carbon cloth is used as the polyfluid, polyvinylidene fluoride is used as the binder, and N-methylpyrrolidone is used as the solvent of the binder. Dry at 180°C after cloth and roller pressing.

[0037]The electrode obtained in this example is used as the negative electrode material, and it is tested after being assembled into a lithium-ion button battery. The energy density during 0.1C charge and discharge is 4.30mAh / cm 2 ; The capacity ratio when the electrode is bent at 90° is 97.2%.

Embodiment 2

[0039] Carbon cloth is used as the polyfluid, polyvinylidene fluoride is used as the binder, and N-methylpyrrolidone is used as the solvent of the binder, and the filling composition ratio is graphene loaded with lithium titanate: polyvinylidene fluoride = 1:0.15 , The electrodes were dried at 180°C after coating and rolling.

[0040] The electrode obtained in this example is used as the negative electrode material, and it is tested after being assembled into a lithium-ion button battery. The energy density when charging and discharging at 0.1C is 2.6mAh / cm 2 ; The capacity ratio is 98.5% when the electrode is bent at 90°.

Embodiment 3

[0042] The carbon cloth loaded with manganese dioxide is used as poly fluid, polyvinyl alcohol is used as binder, and purified water is used as solvent of binder. The main component of filling is graphene oxide, and the composition ratio is graphene oxide: polyvinyl alcohol: =1:0.25, the electrode is dried at 180°C after coating and rolling.

[0043] The electrode obtained in this embodiment is used as an electrode of a supercapacitor, and is tested after assembly, and the capacitance energy density is 0.53mAh / cm2 at a scan rate of 0.1v / s 2 ; The capacity ratio is 99.1% when the electrode is bent at 90°.

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Abstract

The invention discloses a flexible wearable electrode and a preparation method therefor. The preparation method comprises the steps of taking carbon cloth, or oxidized carbon cloth processed by a chemical method, or carbon cloth loaded with metal oxide as a current collector; and filling the gap of the current collector with graphene, or graphene oxide or graphene loaded with the metal oxide through a binder so as to improve the energy density of the flexible wearable electrode. The carbon cloth and graphene both have high flexibility and can be used as the material of a flexible wearable energy storage apparatus; however, the specific surface area of the carbon cloth is relatively small; the resistance of the laminated layers of the laminated graphene is relatively high; when the carbon cloth and graphene are combined together, relatively high energy density can be obtained; and meanwhile, the prepared electrode can obtain relatively low internal resistance, and a thermal effect in a rapid charging-discharging process can be reduced as well.

Description

technical field [0001] The invention relates to the field of electrodes, and more specifically, to a flexible and wearable electrode and a preparation method thereof. Background technique [0002] In the life of modern people, electronic products can bring great convenience to people's life, whether it is traveling or living at home, from smart phones to iwatches to the current emerging concept products - flexible mobile phones, electronic products It has become one of the essential elements in people's life. In addition to a higher degree of intelligent integration, the development of electronic products must also meet people's needs for portability. Therefore, in addition to meeting the characteristics of small, light, and thin, electronic products must also be bendable or foldable. That is, a new industry field that has emerged: flexible smart wearable devices. Every part of a flexible smart wearable device must have a bendable function. Naturally, the power supply that...

Claims

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Application Information

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IPC IPC(8): H01M4/04H01G11/86H01M4/133H01M4/66H01G11/68H01G11/32
CPCH01G11/32H01G11/68H01G11/86H01M4/0404H01M4/133H01M4/663Y02E60/10
Inventor 邓惠贤
Owner GUANGZHOU TINGYU ENERGY TECH CO LTD
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