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Surface treatment process of molybdenum foil for spaceflight interconnection piece

A technology of surface treatment and interconnection sheet, applied in metal material coating process, ion implantation plating, coating and other directions, can solve the problems of easy interface cracking, poor bonding force of molybdenum foil, mismatch of thermal expansion coefficient, etc., to avoid Secondary oxidation, low cost, enhanced binding effect

Inactive Publication Date: 2016-10-26
鹰普航空科技(南通)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, molybdenum foil is mainly used for aerospace interconnection sheets, but because spacecraft are often affected by various complex environmental factors such as high-altitude radiation, meteorites, ultra-high temperature, and ultra-low temperature during orbital flight, in order to enhance the conductivity of molybdenum foil and wide-range To improve its damage resistance, the molybdenum foil material must be surface treated, that is, coated with a layer of protective metal silver. However, the bonding force between the silver plating layer and the molybdenum foil as the substrate is very poor, and there is a problem of thermal expansion coefficient mismatch. , the interface is easy to crack, thus failing

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The surface treatment process of molybdenum foil for aerospace interconnection sheet includes the following steps:

[0018] (1) Degreasing: Soak the molybdenum foil workpiece in acetone solution for 35 minutes, methanol solution for 10 minutes, isopropanol solution for 10 minutes, and blow dry with high pressure nitrogen;

[0019] (2) Pickling: Sulfuric acid and deionized water are prepared into an acid solution in a mass ratio of 1:5, and the degreasing treated molybdenum foil workpiece is immersed in the acid solution for 30 minutes to completely eliminate the surface oxide layer. Ionized water for 10min;

[0020] (3) Alkaline washing: Soak the pickled molybdenum foil workpiece in 50% NaOH solution at 75℃ for 60min, then transfer it to acetone solution for soaking within 5s, observe by atomic force microscope, the surface roughness is less than 100nm;

[0021] (4) Nickel-chromium alloy: at 10 -7 Under the vacuum degree of Torr, the molybdenum foil workpiece after a...

Embodiment 2

[0025] The surface treatment process of molybdenum foil for aerospace interconnection sheet includes the following steps:

[0026] (1) Degreasing: Soak the molybdenum foil workpiece in acetone solution for 40 minutes, methanol solution for 12 minutes, isopropanol solution for 12 minutes, and blow dry with high pressure nitrogen;

[0027] (2) Pickling: Sulfuric acid and deionized water are prepared into an acid solution in a mass ratio of 1:5, and the degreasing treated molybdenum foil workpiece is immersed in the acid solution for 30 minutes to completely eliminate the surface oxide layer. Ionized water cleaning for 12min;

[0028] (3) Alkaline washing: soak the pickled molybdenum foil workpiece in 50% NaOH solution at 80°C for 65min, then transfer it to acetone solution for soaking within 5s, observe by atomic force microscope, the surface roughness is less than 100nm;

[0029] (4) Nickel-chromium alloy: at 10 -7 Under the vacuum degree of Torr, the molybdenum foil workpiec...

Embodiment 3

[0033] The surface treatment process of molybdenum foil for aerospace interconnection sheet includes the following steps:

[0034] (1) Degreasing: soak the molybdenum foil workpiece in acetone solution for 45 minutes, methanol solution for 15 minutes, isopropanol solution for 15 minutes, and blow dry with high pressure nitrogen;

[0035] (2) Pickling: Sulfuric acid and deionized water are prepared into an acid solution in a mass ratio of 1:5, and the degreasing treated molybdenum foil workpiece is immersed in the acid solution for 35 minutes to completely eliminate the surface oxide layer. Ionized water for 15min;

[0036] (3) Alkaline washing: soak the pickled molybdenum foil workpiece in 50% NaOH solution at 85°C for 70min, then transfer it to acetone solution for soaking within 5s, observe by atomic force microscope, the surface roughness is less than 100nm;

[0037] (4) Nickel-chromium alloy: at 10 -6 Under the vacuum of Torr, the molybdenum foil workpiece after alkali ...

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Abstract

The invention provides a surface treatment process of molybdenum foil for a spaceflight interconnection piece. The process comprises the steps of degreasing, acid pickling, alkali washing, nickel-chromium alloy plating, silver plating, packaging and the like. The surface treatment process adopts the reasonable pretreatment step so as to effectively remove oil grease and an oxide layer on the surface of the molybdenum foil; a highly-vacuum electron beam evaporation coating technology is adopted so that secondary oxidation of the molybdenum foil can be effectively avoided and the thickness of a coating film can be controlled accurately; a nickel-chromium alloy layer is adopted as a buffering layer so that the mechanical performance and thermal performance of workpieces can be effectively improved; bonding force between the nickel-chromium alloy layer and the molybdenum foil can be effectively enhanced through highly-vacuum annealing treatment of the nickel-chromium alloy layer; and meanwhile, the process is simple in operation, low in cost and capable of meeting the requirements for mass treatment of products.

Description

technical field [0001] The invention belongs to the technical field of material surface treatment, in particular to a surface treatment process of molybdenum foil for aerospace interconnection sheets. Background technique [0002] Most spacecraft use solar-battery batteries as the power system, and during light periods, the solar array converts solar energy into electrical energy to provide electrical energy for the spacecraft's electrical loads while charging the battery pack. The solar cell array is actually composed of a certain number of solar cells connected in series and parallel, and these cells are assembled on the battery board in an orderly manner to generate electricity by the photoelectric effect. Because the panels need to be stretched and angled, the interconnects between them and the spacecraft must have a series of excellent electrical, mechanical, thermal, and corrosion resistance properties. At present, the aerospace interconnection sheet mainly uses molyb...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C14/16C23C14/30C23C14/58C23C14/02
CPCC23C14/16C23C14/021C23C14/025C23C14/30C23C14/5806
Inventor 修发贤
Owner 鹰普航空科技(南通)有限公司
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