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Environment-friendly efficient and microporous-starch-containing monocrystalline silicon solar cell piece surface texture liquid and preparation method therefor

A technology of solar cells and microporous starch, applied in the field of solar cells, can solve the problems of high price of isopropanol, poor reaction uniformity, fast volatilization speed, etc., and achieve the effects of small particles, fast reaction speed and reduction of impurities

Inactive Publication Date: 2016-11-16
CHINALAND SOLAR ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, chemical etching is the most commonly used method for surface texture of single crystal silicon, and the commonly used texturing liquid is NaOH / isopropanol system, but isopropanol is expensive, volatilizes quickly, costs high and is not conducive to environmental protection
Patent 201010161287.8 discloses a monocrystalline silicon additive texturing solution, which is composed of alkaline corrosion solution, surfactant and organic acid or salt, does not contain isopropanol and is fast and efficient, but it has the problem of poor uniformity of reaction, which is easy to cause After texture, the pyramids on the silicon surface are too large and local over-corrosion, etc., the quality of the silicon wafers needs to be further improved

Method used

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Embodiment Construction

[0014] An environment-friendly and high-efficiency monocrystalline silicon solar cell surface texturing solution containing microporous starch, which is prepared from the following component raw materials in weight (kg):

[0015] Microporous starch 0.1, polyaspartic acid 0.05, styrene 1.5, 5% ammonium persulfate solution 1, sodium lauryl sulfate 0.1, soapberry soap emulsion 0.05, dodecafluoroheptylpropyltrimethoxysilane 0.1, sodium hydroxide 3, citric acid 0.3, edetate disodium 0.03, water 100.

[0016] A method for preparing an environment-friendly and high-efficiency monocrystalline silicon solar cell surface texture liquid containing microporous starch, comprising the following steps:

[0017] (1) Weigh raw materials by weight, first add sodium lauryl sulfate to 1 / 3 weight of water and stir evenly, then slowly add the mixture of styrene and dodecafluoroheptylpropyltrimethoxysilane and stir for 0.5h , and finally slowly add ammonium persulfate solution dropwise and stir at ...

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Abstract

The invention discloses an environment-friendly efficient and microporous-starch-containing monocrystalline silicon solar cell piece surface texture liquid. The monocrystalline silicon solar cell piece surface texture liquid is prepared from the following raw materials in parts by weight: 0.1-0.15 parts of microporous starch, 0.05-0.1 parts of polyaspartic acid, 1.5-2.5 parts of styrene, 1-2 parts of 5-10% of ammonium persulfate solution, 0.1-0.2 parts of lauryl sodium sulfate, 0.05-0.1 parts of soapnut saponin emulsion, 0.1-0.15 parts of dodecafluoroheptyl-propyl-trimethoxysilane, 3-5 parts of sodium hydroxide, 0.3-0.5 parts of citric acid, 0.03-0.05 parts of ethylene diamine tetraacetic acid and 100-120 parts of water. The silicon wafer texture liquid provided by the invention has relatively high reaction speed, moderate corrosion, low thinning amount and high repeating utilization factor; the impurities generated in the reaction can be effectively reduced; the service life can be prolonged; the prepared textured pyramid has a uniform size and relatively small granules; in addition, a green and environmental protection effect, and high photoelectric conversion efficiency are achieved.

Description

technical field [0001] The invention relates to the technical field of solar cells, in particular to an environment-friendly and high-efficiency monocrystalline silicon solar cell surface texture liquid containing microporous starch and a preparation method thereof. Background technique [0002] As the world's energy crisis becomes more serious, solar energy has become the most potential alternative energy source, and a solar cell is an electronic component that directly converts solar energy into electrical energy. The main problem hindering the development of solar cell technology is its high manufacturing cost. At present, in order to reduce the cost of monocrystalline silicon solar cells and improve the photoelectric conversion efficiency, silicon surface texturing is the easiest and most efficient method. Texture, also known as velvet, uses the principle of light trapping to make the incident light reflect multiple times to prolong its propagation path on the surface o...

Claims

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Application Information

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IPC IPC(8): H01L31/0236H01L21/306
CPCY02E10/50H01L31/02363H01L21/30608
Inventor 程晓民李尚荣王可胜孟祥法郭万东袁艺琴
Owner CHINALAND SOLAR ENERGY