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Positive silver slurry for crystalline silicon solar cell and preparation method thereof

A technology for solar cells and crystalline silicon, which is applied in the field of front-side silver paste for crystalline silicon solar cells and its preparation, can solve problems such as the influence of aspect ratio, and achieve improved gate line aspect ratio, reduced widening phenomenon, and increased aspect ratio than the effect

Inactive Publication Date: 2017-01-04
北京市合众创能光电技术有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the problems encountered by domestic enterprises in front silver paste are mainly in the aspect of product efficiency, and the gap between printing applicability and foreign manufacturers is obvious, so the main problem in the application of silver paste is the aspect ratio. At present, the front surface of solar cells The obvious sintering widening phenomenon of the fine grid has a great influence on the aspect ratio

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The composition and weight percentage of the front silver conductive paste in this example are: 70% silver powder, 8% glass powder, 5% organic vehicle, 1% polydimethylsiloxane, 0.2% BYK110, and the rest is solvent. Among them, the particle size of the silver powder is 0.5-3 microns, and the tap density is 4.5-6g / m 3 The spherical silver powder; the glass powder is PbO-TeO 2 A series of glass powders with a particle size of 0.5-3 microns.

[0027] Preparation of organic vehicle: rosin 2%, ethyl cellulose 1%, epoxy resin 5%, butyl carbitol 50%, butyl carbitol acetate 40%, dissolved at 80°C for 2 hours to obtain a uniform organic carrier;

[0028] Weigh 70% of silver powder, 8% of glass powder, 5% of organic carrier, 1% of polydimethylsiloxane, 0.2% of BYK1100.2% according to the proportion of the above formula, and mix them evenly in a planetary mixer or other mixer. Then disperse it on a three-roll machine to a thickness below 10 μm to make a front silver paste for cr...

Embodiment 2

[0031] The composition and weight percentage of the front silver conductive paste in this example are: 85% silver powder, 5% glass powder, 8% organic vehicle, 1.2% polyaminosiloxane, and 0.2% BYK110. Among them, the particle size of the silver powder is 0.5-3 microns, and the tap density is 4.5-6g / m 3 The spherical silver powder; the glass powder is PbO-TeO 2 A series of glass powders with a particle size of 0.5-3 microns.

[0032] Preparation of organic vehicle: 3% ethyl cellulose, 2% epoxy resin, 3% cellulose acetate, 50% terpineol, and 40% DBE were dissolved at 80°C for 2 hours to obtain a uniform organic vehicle;

[0033] Weigh 85% of silver powder, 5% of glass powder, 8% of organic carrier, 1% of polyaminosiloxane, 0.5% of BYK110 according to the proportion of the formula, and mix them evenly in a planetary mixer or other mixer, and then mix them in a three-roller On-machine dispersion to less than 10μm can be used to make front silver paste for crystalline silicon sola...

Embodiment 3

[0036] The composition and weight percentage of the front silver conductive paste in this example are: 82% silver powder, 2.5% glass powder, 10% organic vehicle, 2% polyhydroxysiloxane, and 0.3% BYK110. Among them, the particle size of the silver powder is 0.5-3 microns, and the tap density is 4.5-6g / m 3 The spherical silver powder; the glass powder is PbO-TeO 2 A series of glass powders with a particle size of 0.5-3 microns.

[0037] Preparation of organic vehicle: 3% of acrylic resin, 5% of polyethylene resin, 3% of polyethylene resin, 50% of propylene glycol butyl ether, and 40% of terpineol were dissolved at 80°C for 2 hours to obtain a uniform organic vehicle;

[0038] Weigh 82% of silver powder, 2.5% of glass powder, 10% of organic vehicle, 2% of polyhydroxysiloxane, 0.3% of BYK110 according to the proportion of the formula, and mix them evenly in a planetary mixer or other mixer, and then mix them in a three-roller On-machine dispersion to less than 10μm can be used t...

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Abstract

The invention relates to the technical field of electronic materials, and specifically relates to positive silver slurry for a crystalline silicon solar cell. The slurry comprises components by mass percentage content: 0.1-6% of polysiloxane product, 1-90% of silver powder, 5-15% of organic carrier, 1-8% of glass powder, and 0-3% of auxiliary agent, the sum of content of the components is 100%, the polysiloxane product can be straight-chain or branched polysiloxane, a hydrogen group of which is substituted by amino, ethyl, phenyl, chlorphenyl, trifluoropropyl, nitro, and hydroxy etc., and the content is preferably 0.1-6%. According to the slurry, the polysiloxane is added, the expansion phenomenon generated in a sintering process of the silver slurry is reduced, the grid aspect ratio of the slurry is increased, and the slurry can maintain an excellent grid shape in the sintering process.

Description

technical field [0001] The invention relates to the technical field of electronic materials, in particular to a front silver paste for crystalline silicon solar cells and a preparation method thereof. Background technique [0002] Solar energy is an inexhaustible renewable energy source for human beings, and it is also a clean energy source that does not produce any environmental pollution. Among the effective utilization of solar energy, solar photoelectric conversion utilization is the fastest growing and most dynamic research field in recent years. [0003] Solar cell silver paste is one of the main raw materials for manufacturing solar cells, and the preparation technology of solar cell silver paste is a key technology for high-efficiency and low-cost solar cells. Solar cell silver paste is an important raw material for manufacturing solar cells. According to estimates, the cost of paste accounts for about 15-20% of the cost of solar cells. Solar cell silver paste manuf...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01B1/22H01B1/12H01B1/02H01L31/0224
CPCH01B1/02H01B1/12H01B1/22H01L31/022425Y02E10/50
Inventor 赵德平任中伟丁兴隆
Owner 北京市合众创能光电技术有限公司