Catalyst for processing shale oil, preparation method thereof, shale oil processing system and processing method thereof
A catalyst and shale oil technology, applied in chemical instruments and methods, chemical elements of heterogeneous catalysts, physical/chemical process catalysts, etc., can solve the problems of large environmental pollution of solvents and wastewater, consumption of catalysts easily poisoned, high energy consumption, etc. question
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[0085] The preparation method of described catalyst, described method comprises the following steps:
[0086] (1) mixing a part of pseudo-boehmite and an adsorption auxiliary agent to make slurry, so that the solid content of the slurry is 30-50 wt%, and adjusting the pH of the slurry to 3-5 to obtain slurry I;
[0087] (2) mixing another part of pseudo-boehmite and clay to make pulp, so that the solid content of the slurry is 30-50 wt%, and adjusting the pH of the slurry to 1-3 to obtain slurry II;
[0088] (3) Mix the obtained slurry I and slurry II, add a binder, make the solid content of the slurry 20-50wt%, and adjust the pH of the slurry to 3-5, and then spray dry and form;
[0089] (4) Calcining the material obtained by spray drying in step (3) to obtain the catalyst.
[0090] like figure 1As shown, the shale oil processing system includes: heating furnace 1, fluidized bed reactor 2, separation system 3, gas stripping system 4, regeneration device 5 and fractionation ...
Embodiment 1
[0102] The present embodiment provides a kind of preparation method of catalyst and the prepared catalyst, described method is:
[0103] (1) Mix 1.4kg of pseudo-boehmite to 0.1-5 μm and 0.9kg of CaO, add deionized water for beating, make the slurry solid content 40wt%, adjust the pH=3.4 of the slurry with hydrochloric acid, stir for 30min, and obtain Serum I;
[0104] (2) Grind 0.3 kg of kaolin and 3.2 kg of pseudo-boehmite to 0.1-5 μm, add deionized water for beating, make the slurry solid content 40 wt%, adjust the pH of the slurry to 2.5 with hydrochloric acid, and stir for 15 minutes to obtain slurry II ;
[0105] (3) Mix the obtained slurry I and slurry II, add 0.5kg of aluminum sol to make the solid content of the slurry 30-40wt%, and adjust the pH of the slurry to 3.6 with hydrochloric acid, stir for 50min, and then spray dry and form;
[0106] (4) Calcining the material obtained by spray drying in step (3) at 600° C. for 4 hours to prepare the catalyst.
[0107] The...
Embodiment 2
[0109] The present embodiment provides a kind of preparation method of catalyst and the prepared catalyst, described method is:
[0110] (1) 1.8kg pseudo-boehmite is ground to 0.1~5 μ m and 0.3kg of dolomite and 0.3kg of limestone are mixed, add deionized water and beating, make the slurry solid content be 30wt%, regulate the pH= of slurry with hydrochloric acid 3.5, stirred for 10 minutes to obtain slurry I;
[0111] (2) Grind 1.0 kg of montmorillonite and 3.4 kg of pseudoboehmite to 0.1-5 μm, add deionized water for beating to make the slurry solid content 30 wt%, adjust the pH of the slurry to 2.7 with hydrochloric acid, and stir for 15 minutes to obtain the slurry II;
[0112] (3) Mix the obtained slurry I and slurry II, add 1.2kg of silica sol to make the solid content of the slurry 20-30wt%, and adjust the pH of the slurry to 3.2 with hydrochloric acid, stir for 60min, and then spray dry and form;
[0113] (4) Calcining the material obtained by spray drying in step (3)...
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