Fiber-reinforced biological resin adhesive composite material and preparation method thereof

A bio-resin and composite material technology, which is applied in the field of fiber-reinforced bio-resin adhesive composite materials and its preparation, can solve the problems of high brittleness, poor impact resistance, and aging resistance of epoxy resin, and achieve good weather resistance and reduce costs , The effect of simple production process

Active Publication Date: 2017-02-15
四川景文材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Epoxy resin has the characteristics of excellent physical, mechanical and electrical insulation properties, corrosion resistance, chemical stability, bonding performance with various materials, and the flexibility of its use process, etc., and is widely used in the preparat...

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] A kind of fiber-reinforced bioresin glue composite material described in the present embodiment, its preparation method is:

[0028] (1) Preparation of bioresin glue: in parts by weight, take 100 parts of biomass oil modified E44 epoxy resin, 15 parts of ethylene glycol, 2 parts of polyoxyethylene oxypropylene oleate, 3 parts of calcium stearate , 1 part of silane coupling agent KH550, 10 parts of heavy calcium carbonate, 2 parts of iron oxide red, and 15 parts of triethanolamine. Add the above raw materials into the stirring tank in turn, and stir for 10-20 minutes to get the biological resin glue;

[0029] (2) 30 parts of bioresin glues are injected into the dipping device to infiltrate 50 parts of glass fiber untwisted yarns to form infiltrated fibers;

[0030] (3) the impregnated fiber is blended together with 20 parts of glass fiber untwisted yarns again, and is evenly distributed;

[0031] (4) After uniform distribution, pass through a high-temperature mold toge...

Embodiment 2

[0041] A kind of fiber-reinforced bioresin glue composite material described in the present embodiment, its preparation method is:

[0042] (1) Preparation of bioresin glue: in parts by weight, get 90 parts of biomass oil modified F51 epoxy resin, 12 parts of ethanol, 2.5 parts of diethylene glycol fatty acid ester, 2 parts of dimethyl silicone oil, silane dimethicone 1 part of joint agent KH560, 20 parts of montmorillonite, 2 parts of carbon black, 18 parts of pyridine. Add the above raw materials into the stirring tank in turn, and stir for 10-20 minutes to get the biological resin glue;

[0043] (2) 38 parts of the bioresin glue are injected into the dipping device to infiltrate 52 parts of glass fiber cloth to form infiltrated fibers;

[0044] (3) The infiltrated fiber is stacked with 10 parts of basalt fiber cloth and distributed evenly;

[0045] (4) After uniform distribution, pass through a high-temperature mold together, and undergo a molding process to obtain a fibe...

Embodiment 3

[0055] A kind of fiber-reinforced bioresin glue composite material described in the present embodiment, its preparation method is:

[0056] (1) Preparation of biological resin glue: in parts by weight, get 85 parts of biomass oil modified F44 epoxy resin, 17 parts of glycerol, 1 part of sorbitan monostearate, polyoxyethylene oxypropylene 2 parts of oleic acid ester, 3 parts of zinc stearate, 1.5 parts of silane coupling agent KH550, 10 parts of heavy calcium carbonate, 10 parts of montmorillonite, 2 parts of red iron oxide, 16 parts of N-diglycidyl aniline. Add the above raw materials into the stirring tank in turn, and stir for 10-20 minutes to get the biological resin glue;

[0057] (2) Inject 25 parts of the bioresin glue into the dipping device to infiltrate 40 parts of basalt fiber untwisted yarns to form infiltrated fibers;

[0058] (3) The impregnated fiber is stacked with 35 parts of basalt fiber untwisted yarns and evenly distributed;

[0059] (4) After uniform dist...

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Abstract

The invention discloses a fiber-reinforced biological resin adhesive composite material and a preparation method thereof. The composite material is prepared from 10-50 parts by weight of a biological resin adhesive and 50-100 parts by weight of fibers. The biological resin adhesive is prepared from 20-100 parts by weight of biomass oil-modified epoxy resin, 2-20 parts by weight of a diluent, 1-4 parts by weight of an emulsifier, 1-3 parts by weight of a coupling agent, 1-5 parts by weight of a release agent, 5-20 parts by weight of a filler, 1-4 parts by weight of a pigment and 10-20 parts by weight of a curing accelerator. The biological resin adhesive is prepared from the biomass oil-modified epoxy resin, then infiltrates fibers and then is cured so that the fiber-reinforced biological resin adhesive composite material with better toughness, better weather resistance and excellent mechanical properties is obtained. The method is used to prepare the composite material, utilizes easily accessible and cheap raw materials, has simple and mature processes and reduces a composite material cost.

Description

technical field [0001] The invention relates to the technical field of composite materials and production thereof, in particular to a fiber-reinforced biological resin glue composite material and a preparation method thereof. Background technique [0002] Fiber-reinforced composite materials are composite materials formed by reinforcing fiber materials and matrix materials through hand lay-up, winding, molding or pultrusion. According to different reinforcing materials, common fiber reinforced composites are divided into glass fiber reinforced composites, basalt fiber reinforced composites, carbon fiber reinforced composites and aramid fiber reinforced composites. Fiber-reinforced composite materials have the following characteristics: (1) high specific strength and large specific modulus; (2) material properties can be designed; (3) good corrosion resistance and durability; (4) thermal expansion coefficient is similar to that of concrete . These characteristics make fiber...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08K13/04C08K7/14C08K7/10C08K5/053C08K5/098C08K3/26C08K3/34C08J5/04
CPCC08J5/043C08J2363/00C08K7/10C08K13/04C08L63/00C08L2201/08C08J5/0405C08L71/02C08K7/14C08K5/053C08K5/098C08K2003/265C08L83/04C08K5/05C08K3/34
Inventor 曹海波王兴财王维平
Owner 四川景文材料科技有限公司
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