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Preparation method of environmental-friendly type pressure-sensitive oil for carbonless copying paper

A carbonless copy paper, environmentally friendly technology, used in paper, papermaking, paper coatings, etc., can solve the problems of large VOCs emissions, non-compliance with environmental protection, unfavorable to human health, etc., achieving excellent compatibility and synergy, easy to micro Encapsulated, safe to use effect

Active Publication Date: 2017-02-15
SUZHOU FENGBEI BIOTECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] 1. It has a stimulating effect, damages the heart, liver and kidney, has certain toxicity to the nervous system and digestive system, is not conducive to human health, and does not meet the national requirements for environmental protection;
[0005] 2. It is harmful to the environment and can cause pollution to the atmosphere;
[0006] 3. The emission of VOCs (>100mg / g) is large, and the cost of environmental protection is high;
[0007] 4. Low flash point, there is a danger of burning when heated

Method used

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  • Preparation method of environmental-friendly type pressure-sensitive oil for carbonless copying paper

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preparation example Construction

[0034] A preparation method of an environment-friendly carbonless copy paper pressure-sensitive oil, the preparation method comprising the following steps:

[0035] 1) Pretreatment: Heat the solvent oil compound to 60-70°C and stir evenly;

[0036] 2) Dissolving: under the condition of temperature 110°C-130°C, heat and dissolve 2-6 parts by weight of leuco dye and 20-40 parts by weight of solvent oil to obtain a chromogenic agent; wherein, the colorless dye is phenolic, phenothione One or more of azine series and fluorane series, phenol series can be crystal violet lactone (CVL), malachite green lactone (MGL), phenothiazine series can be benzomethylene blue (BLMB), fluoran series It can be fluorane black; solvent oil is prepared from the following components in terms of mass percentage: 0-40% of component A; 40-100% of component B, 0-20% of chloromethyl ester; Divided into vegetable oil or vegetable oil methyl ester, the B component is epoxidized vegetable oil or epoxy methyl...

Embodiment 1

[0043] A preparation method of an environment-friendly carbonless copy paper pressure-sensitive oil, the preparation method comprising the following steps:

[0044]1) Pretreatment: heat the solvent oil compound to 60°C, and stir evenly; the solvent oil is prepared from the following components in mass percentage: 60% epoxy soybean oil; 20% chloromethyl ester, castor oil 20%;

[0045] 2) Dissolving: at a temperature of 110°C, 2 parts by weight of CVL and 30 parts by weight of solvent oil were heated and dissolved to obtain a color developing agent;

[0046] 3) Pre-emulsification: Add 5 parts by weight of emulsifier, 20 parts by weight of urea-formaldehyde resin and 43 parts by weight of deionized water to the chromogenic agent obtained in step 2) and mix, then stir at a stirring speed of 800r / min; Among them, the emulsifier is composed of calcium dodecylbenzenesulfonate and styrylphenyl polyoxyethylene ether in a mass ratio of 6:4;

[0047] 4) Emulsification: Carry out high-s...

Embodiment 2

[0052] A preparation method of an environment-friendly carbonless copy paper pressure-sensitive oil, the preparation method comprising the following steps:

[0053] 1) Pretreatment: Heat the solvent oil compound to 63°C and stir evenly; the solvent oil is prepared from the following components in mass percentage: epoxy soybean oil 65%; chloromethyl ester 15%, palm oil 20%;

[0054] 2) Dissolving: at a temperature of 120°C, 2 parts by weight of MGL and 30 parts by weight of solvent oil were heated and dissolved to obtain a chromogenic agent;

[0055] 3) pre-emulsification: in step 2) in the chromogenic agent that obtains, add the polyacrylamide of 5 weight parts, the chitosan of 20 weight parts and the deionized water of 43 weight parts and mix, then stir, stirring speed is 900r / min;

[0056] 4) Emulsification: Carry out high-speed shear emulsification to the required particle size of the capsule, the shear speed is 8000r / min, and the shear time is 5min to obtain the emulsio...

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Abstract

The invention discloses a preparation method of environmental-friendly type pressure-sensitive oil for carbonless copying paper. The preparation method comprises the following steps: 1) pretreatment: compounding and heating solvent oil, and stirring uniformly; 2) dissolution: heating and dissolving colorless dye and the solvent oil to obtain a color forming agent; 3) pre-emulsification: adding and mixing an emulsifying agent, a wall material and deionized water into the color forming agent in the step 2) to obtain emulsified liquid; 4) emulsification: shearing and emulsifying at a high speed to the particle diameter needed by capsules, so as obtain emulsified liquid; 5) curing: carrying out curing on the emulsified liquid in the step 4) to form microcapsules; 6) hardening: carrying out water-bath insulation on the microcapsules in the step 5); 7) oil formation: adding an adhesive and an isolating agent into the microcapsules in the step 6) to obtain the pressure-sensitive oil. The environmental-friendly type pressure-sensitive oil for the carbonless copying paper, prepared by the preparation method, is non-toxic and non-irritating, is good in safety and wide in application range and is environmental-friendly and pollution-free.

Description

technical field [0001] The invention relates to a preparation method of carbon paper pressure-sensitive oil, in particular to an environment-friendly preparation method of carbon-free carbon paper pressure-sensitive oil. Background technique [0002] Carbon-free copy paper is mainly used for multi-part forms, bills, continuous financial notes, general business financial notes, etc. It has been widely used in people's work and life. The principle is to make the force-sensitive pigment in the microcapsules And the oil solution overflows, and after contacting with the color developer, a dyeing reaction occurs, thus playing the role of copying. [0003] With the continuous development of carbonless copy paper technology, people have higher and higher requirements for carbonless paper pressure-sensitive oil, not only require better performance, but also have requirements in terms of environmental protection, especially in Japan, Europe and the United States and other markets, peo...

Claims

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Application Information

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IPC IPC(8): D21H21/28D21H21/14D21H21/54D21H19/14
CPCD21H19/14D21H21/14D21H21/28D21H21/54
Inventor 周孟龙马敏任鹏平原陈杰
Owner SUZHOU FENGBEI BIOTECH CO LTD
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