Method for preparing high-purity dimethyl diallyl ammonium chloride (DMDAAC) monomer
A dimethyl diallyl ammonium chloride, high-purity technology is applied in the field of preparation of cationic quaternary ammonium salt monomers, and can solve the problems of no two-step method to obtain monomer purity, reports, no pure DMDAAC, etc.
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0054] The preparation method of high-purity DMDAAC monomer, concrete steps are as follows:
[0055] (1) Adding alkali to release amine: under the condition of stirring at room temperature, in the DMDAAC monomer aqueous solution (40wt%) that is placed in the 40g that is placed in the reactor, one-step process makes dripping the sodium hydroxide aqueous solution that massfraction is 1.0%, adjusts And maintain the pH value at 11.0, and then distill under reduced pressure at 40°C to release the ammonium salt until the pH value of the distillate is constant at 7.0.
[0056] (2) Neutralize residual alkali: add 1% hydrochloric acid aqueous solution to the DMDAAC monomer solution after amine-releasing treatment, adjust the pH value to 7.0, neutralize residual alkali, and set aside.
[0057] (3) Monomer dehydration crystallization: add alkali to release amine, add acid to neutralize the DMDAAC monomer solution after vacuum distillation until no water is evaporated, add 32mL water-carr...
Embodiment 2
[0063] The preparation method of high-purity DMDAAC monomer, concrete steps are as follows:
[0064] (1) Adding alkali to release amine: under the condition of stirring at room temperature, in the DMDAAC monomer aqueous solution (50wt%) that is placed in the 50g that is placed in the reactor, two-step method makes dripping the dilute sodium hydroxide aqueous solution that mass fraction is 5%, adjusts And maintain a certain pH value of 11.5, and then distill under reduced pressure at a temperature of 60°C to release the ammonium salt until the pH value of the distillate is constant at 7.3.
[0065] (2) Neutralize residual alkali: add 5% dilute hydrochloric acid aqueous solution to the DMDAAC monomer solution after amine release, adjust the pH value to 7.3, neutralize residual alkali, and set aside.
[0066](3) Monomer dehydration crystallization: add alkali to release amine, add acid to neutralize the DMDAAC monomer solution after vacuum distillation until no water is evaporate...
Embodiment 3
[0073] The preparation method of high-purity DMDAAC monomer, concrete steps are as follows:
[0074] (1) Add alkali to release amine: add dropwise 10% aqueous sodium hydroxide solution to the 50g two-step method DMDAAC monomer aqueous solution (60wt%) placed in the reactor under stirring at room temperature, adjust and maintain a certain pH value of 12.0 , and then distilled under reduced pressure at a temperature of 80°C to release the ammonium salt until the pH value of the distillate is constant at about 7.5.
[0075] (2) Neutralize residual alkali: add a small amount of 10% hydrochloric acid aqueous solution to the DMDAAC monomer solution after amine-releasing treatment, adjust the pH value to 7.5 to neutralize residual alkali, and then set aside.
[0076] (3) Monomer dehydration crystallization: add alkali to release amine, add acid to neutralize the DMDAAC monomer solution after vacuum distillation until no water is evaporated, add 300mL ethanol with water agent, and con...
PUM
![No PUM](https://static-eureka.patsnap.com/ssr/23.2.0/_nuxt/noPUMSmall.5c5f49c7.png)
Abstract
Description
Claims
Application Information
![application no application](https://static-eureka.patsnap.com/ssr/23.2.0/_nuxt/application.06fe782c.png)
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap