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Polyolefin communication cable material used in rail transportation, and preparation method thereof

A rail transit and polyolefin technology, which is applied in the field of material chemistry, can solve the problems of insufficient water resistance, barrier resistance, scratch resistance and flexibility, complex preparation process, and inability to recycle, and achieve excellent physical and mechanical properties, good processing fluidity, The effect of excellent wear resistance

Inactive Publication Date: 2017-03-22
WUXI JAKE PLASTIC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In the prior art, heat-resistant rail transit wires generally use expensive engineering plastics polyphenylene ether or polyphenylene sulfide or thermosetting materials with complex preparation processes and cannot be recycled, such as nitrile rubber, cross-linked polyethylene, etc.
Although there have been many reports on the preparation technology of thermoplastic halogen-free flame-retardant polyolefin cable materials in recent years, such materials are not resistant to high temperature, water barrier, scratch resistance and flexural resistance.

Method used

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  • Polyolefin communication cable material used in rail transportation, and preparation method thereof
  • Polyolefin communication cable material used in rail transportation, and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A polyolefin communication cable material for rail transit, which is composed of the following components in proportion by weight: 40 parts of ethylene-vinyl acetate copolymer, 50 parts of propylene-ethylene block copolymer, 10 parts of interface compatibilizer, 160 parts of flame retardant, 2 parts of composite antioxidant, 5 parts of anti-wear agent, 1 part of ultraviolet absorber, 2 parts of lubricant, 2 parts of water blocking agent, and 1 part of metal deactivator.

[0024] The ethylene-vinyl acetate copolymer is two kinds of ethylene-vinyl acetate copolymers whose vinyl acetate monomer dosages are 28wt% and 40wt%, mixed at 1:1, and the melt flow rate is 3g / 10min; the propylene -The molar content of ethylene in the ethylene block copolymer is 12%, and the melt flow rate is 2.5g / 10min; the interface compatibilizer is polypropylene polar monomer graft, and the polar monomer is maleic acid Acid anhydride, the graft content is 1.0wt%.

[0025] The flame retardant is m...

Embodiment 2

[0037] A polyolefin communication cable material for rail transit, which is composed of the following components in proportion by weight: 45 parts of ethylene-vinyl acetate copolymer, 40 parts of propylene-ethylene block copolymer, 15 parts of interface compatibilizer, 170 parts of flame retardant, 2 parts of composite antioxidant, 5 parts of antiwear agent, 1 part of ultraviolet absorber, 2 parts of lubricant, 2 parts of water blocking agent, and 1 part of metal deactivator.

[0038] The ethylene-vinyl acetate copolymer is two kinds of ethylene-vinyl acetate copolymers whose vinyl acetate monomer dosages are 28wt% and 40wt%, mixed at 1:1, and the melt flow rate is 3g / 10min; the propylene -The molar content of ethylene in the ethylene block copolymer is 10%, and the melt flow rate is 2.5g / 10min; the interface compatibilizer is polypropylene polar monomer graft, and the polar monomer is maleic acid Acid anhydride, the graft content is 1.0wt%.

[0039] The flame retardant is mi...

Embodiment 3

[0051] A polyolefin communication cable material for rail transit, which is composed of the following components in proportion by weight: 50 parts of ethylene-vinyl acetate copolymer, 40 parts of propylene-ethylene block copolymer, 10 parts of interface compatibilizer, 180 parts of flame retardant, 2 parts of composite antioxidant, 5 parts of anti-wear agent, 1 part of ultraviolet absorber, 2 parts of lubricant, 2 parts of water blocking agent, and 1 part of metal deactivator.

[0052] The ethylene-vinyl acetate copolymer is two kinds of ethylene-vinyl acetate copolymers whose vinyl acetate monomer dosages are 28wt% and 40wt%, mixed at 1:1, and the melt flow rate is 3g / 10min; the propylene -The molar content of ethylene in the ethylene block copolymer is 8%, and the melt flow rate is 2.0g / 10min; the interface compatibilizer is polypropylene polar monomer graft, and the polar monomer is maleic acid Acid anhydride, the graft content is 1.0wt%.

[0053] The flame retardant is mi...

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Abstract

The invention discloses a polyolefin communication cable material used in rail transportation, and a preparation method thereof. The polyolefin communication cable material is composed of, by weight, 40 to 60 parts of ethylene-vinyl acetate copolymer, 40 to 60 parts of propylene-ethylene block copolymer, 10 to 20 parts of an interface compatilizer, 140 to 180 parts of a fire retardant, 1 to 2 parts of a composite antioxidant, 5 to 10 parts of an antiwear additive, 1 to 2 parts of an ultraviolet light absorber, 2 to 4 parts of a lubricating agent, 2 to 3 parts of a water resistance agent, and 1 to 2 parts of a metal deactivator. The polyolefin communication cable material is high in strength, and excellent in wear resistance; possesses petroleum butter resistance, environmental stress crack resistance, hydrophobicity performance, watertightness, weatherability, excellent physical and mechanical properties, electrical performance, and excellent extrusion processability; and is capable of resisting a temperature as high as 105 DEG C; the preparation method and formula are simple; no toxic substance or waste gas is generated in production process; the compatibility of the above ingredients is excellent, and processing fluidity is excellent; the flame resistance is capable of satisfying requirements in UL-94 V-0 vertical flame test; and oxygen index value is equal to or larger than 38%.

Description

technical field [0001] The invention belongs to the field of material chemistry and relates to a composite material, in particular to a polyolefin communication cable material for rail transit and a preparation method thereof. Background technique [0002] Electric wires for rail transit are used in a non-sealed environment with high vibration, high temperature and serious oil pollution, and are often pulled and slid, so the insulating sheath material needs to have good flame retardancy, heat resistance, weather resistance, oil resistance, water resistance, and scratch resistance and other performance. [0003] Polyolefins are inherently flammable substances, however, flame retardancy is required in many applications such as cables and wires used in the electronics or electrical industries. In order to obtain polyolefin compounds with good flame retardancy, some additives are often added to them, such as: halogen-based chemicals, phosphate-based chemicals or inorganic hydro...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L53/00C08L23/08C08L51/06C08L23/12C08K13/06C08K9/06C08K3/22C08K5/25B29C47/92H01B3/44B29C48/92
CPCC08L53/00B29C48/92B29C2948/92704C08L2201/08C08L2203/202C08L2205/025C08L2205/035H01B3/441C08L23/0853C08L51/06C08L23/12C08K13/06C08K9/06C08K2003/2224C08K5/25
Inventor 张建耀游泳祁建强
Owner WUXI JAKE PLASTIC
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