Non-aqueous solvent cold pad batch dyeing method of reactive dye

Abstract

The invention provides a non-aqueous solvent cold pad batch dyeing method of reactive dye. The method comprises the steps of curing and drying the pad batch alkali liquor of the textile; pad dyeing the textile; yarding the pad dyed textile products in the saturated vapor atmosphere of reactive dye poor solvent; curing and drying the yarded textile products, and finishing the non-aqueous solvent cold pad batch dyeing of the reactive dye; or, conducting cationicm odification to the textile; curing and drying the pad batch alkali liquor of the textile; pad dyeing the textile; yarding the pad dyed textile products; curing and drying the yarded textile products; and finishing the non-aqueous solvent cold pad batch dyeing of the reactive dye. The method can achieve the salt free shade dyeing for the reactive dye, the dyeing fixation rate is high, the use amount of the organic solvent and water is low, the energy consumption is low, and the amount of discharged waste water is less.

Description

technical field [0001] The invention relates to a dyeing method of reactive dyes, in particular to a non-aqueous solvent cold pad-batch dyeing method of reactive dyes, belonging to the technical field of textile dyeing and finishing. Background technique [0002] At present, reactive dyes are mostly used in the dyeing of reactive fibers. During the dyeing process, due to the hydrolysis of the active groups in the water medium, not only a large amount of reactive dyes are wasted, but also a large amount of water is consumed during the dyeing process and a large amount of high Chroma sewage, which is also an insurmountable bottleneck for reactive dyes. [0003] In order to avoid the hydrolysis reaction of reactive dyes and improve the utilization rate of reactive dyes, scientists have paid attention to and studied the dyeing of reactive dyes in non-aqueous media very early. The advantage of using non-aqueous medium dyeing is that reactive dyes will not be hydrolyzed during th...

AI Technical Summary

Problems solved by technology

However, the reverse micellar dyeing process has the following problems: 1. The amount of surfactant and co-surfactant in the system is relatively large, and the amount of a large amount of surfactant and auxiliary agent will cause a large amount of surface adsorption on the cloth sample during the dyeing process. Active agents and additives will also cause post-processing difficulties, high COD value of soaping wastewater, environmental pollution and waste of resources

2. Due to the high affinity of the high-concentration dye aqueous solution dispersed in the solvent system to the fiber, the dyeing speed is fast, it is not easy to control, and it is easy to dye flowers.

3. When dyeing, the fiber first needs to be padded with a certain concentration of sodium carbonate aqueous solution, and dyed with a certain liquid rate. The water in the system will also cause the hydrolysis of the dye, so its color fixation rate is low.

However, this method requires a bath ratio of 1: (15-50) (the bath ratio is the mass g of the fiber: the volume mL of the solvent), and it needs to be incubated at 90-130°C for 1-3h to fix the color, and the total solvent usage is relatively large. Large, large energy consumption in the production process, resulting in high economic costs