The invention discloses a preparation method of 
smoothing, stiffening and color deepening 
silicone oil. The method comprises steps as follows: (1) synthesis of the 
smoothing, stiffening and color deepening 
silicone oil: the 
smoothing, stiffening and color deepening 
silicone oil is prepared from certain amounts of 
octamethylcyclotetrasiloxane, dodecyl methyldimethoxysilane and gamma-piperazinylpropylmethyldimethoxysilane under the 
catalysis of a certain quantity of catalysts at certain 
polymerization temperature for a certain time; (2) emulsification of the smoothing, stiffening and color deepening 
silicone oil: 10% of 2-
phenoxyethanol as a special emulsifier is added to a 
silicone oil emulsifier to emulsify the smoothing, stiffening and color deepening 
silicone oil, and milky-white smoothing, stiffening and color deepening silicone 
oil emulsion which has the content of 40% and has slight 
blue light is obtained. The smoothing, stiffening and color deepening silicone 
oil emulsion realizes the color deepening effect by reducing the surface 
refractive index of fabric and is an 
organosilicon finishing agent, and the hand feel finishing and color deepening of the fabric are performed simultaneously, so that 
energy conservation, 
environmental protection, color deepening, dye saving and cost reduction are realized.