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Modified carbon fiber containing Ni-P-SiC (titanium diboride) composite plating layer and preparation and application thereof

A composite coating and carbon fiber technology, applied in the direction of liquid chemical plating, coating, metal material coating technology, etc., can solve the problems of poor wettability and dispersibility, short service life, etc.

Active Publication Date: 2017-03-29
CENT SOUTH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Aiming at the problems of short service life of carbon fiber at high temperature and poor wettability and dispersibility of carbon fiber and metal matrix in the prior art, the purpose of the present invention is to provide a compound with Ni-P-SiC, Ni-P- TiB 2 or Ni-P-SiC-TiB 2 Modified carbon fiber with composite coating, the composite coating of the modified carbon fiber is dense and uniform, and the composite coating has strong bonding force with carbon fiber, which can well improve the oxidation resistance, electrical conductivity and compatibility with the metal matrix of carbon fiber, and improve carbon fiber Dispersion properties in metal matrix

Method used

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  • Modified carbon fiber containing Ni-P-SiC (titanium diboride) composite plating layer and preparation and application thereof
  • Modified carbon fiber containing Ni-P-SiC (titanium diboride) composite plating layer and preparation and application thereof
  • Modified carbon fiber containing Ni-P-SiC (titanium diboride) composite plating layer and preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0060] Step 1: Carbon Fiber Pretreatment

[0061] (1) Degumming: Put the carbon fiber in a muffle furnace and heat it at 400°C for 1 hour. After degumming, soak in absolute ethanol for 5 minutes to remove oil, and then rinse with deionized water.

[0062] (2) Roughening: Treat with potassium dichromate (20 g / L) and sulfuric acid (100 mL / L) at room temperature for 10 minutes. The degummed carbon fiber has fewer surface active functional groups, and roughening can change the state of the functional groups and increase the specific surface area of ​​the carbon fiber. Take out the roughened carbon fibers, and then use distilled water to wash the acidified carbon fibers with the aid of ultrasonic waves until the washed liquid is neutral.

[0063] (3) Neutralization: The acid remaining in the roughening process is neutralized with sodium hydroxide.

[0064] (4) Sensitization: Sensitization was treated with stannous chloride (14 g / L) and hydrochloric acid (40 mL / L) at room tempera...

Embodiment 2

[0072] The surface and cross-sectional morphology of the carbon fiber Ni-P-nano-SiC composite coating are as attached. image 3 and Figure 4 shown.

[0073] Step 1: Carbon Fiber Pretreatment

[0074] (1) Degumming: Put the carbon fiber in a muffle furnace and heat it at 430°C for 0.8h. After degumming, soak in absolute ethanol for 5 minutes to remove oil, and then rinse with deionized water.

[0075] (2) Roughening: Treat with potassium dichromate (24 g / L) and sulfuric acid (100 mL / L) at room temperature for 10 minutes. The degummed carbon fiber has fewer surface active functional groups, and roughening can change the state of the functional groups and increase the specific surface area of ​​the carbon fiber. The roughened carbon fibers were taken out, and then the acidified carbon fibers were washed with distilled water with the aid of ultrasonic waves until the washed liquid was neutral.

[0076] (3) Neutralization: The acid remaining in the roughening process is neutr...

Embodiment 3

[0085] Step 1: Carbon Fiber Pretreatment

[0086] (1) Degumming: Put the carbon fiber in a muffle furnace and heat it at 400°C for 1 hour. After degumming, soak in absolute ethanol for 5 minutes to remove oil, and then rinse with deionized water.

[0087] (2) Roughening: Treat with potassium dichromate (20 g / L) and sulfuric acid (100 mL / L) at room temperature for 10 minutes. The degummed carbon fiber has fewer surface active functional groups, and roughening can change the state of the functional groups and increase the specific surface area of ​​the carbon fiber. The roughened carbon fibers were taken out, and then the acidified carbon fibers were washed with distilled water with the aid of ultrasonic waves until the washed liquid was neutral.

[0088] (3) Neutralization: The acid remaining in the roughening process is neutralized with sodium hydroxide.

[0089] (4) Sensitization: Sensitization was treated with stannous chloride (14 g / L) and hydrochloric acid (40 mL / L) at ...

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Abstract

The invention discloses a modified carbon fiber containing a Ni-P-SiC (titanium diboride) composite plating layer and a preparation method and application thereof. The modified carbon fiber consists of a carbon fiber and a Ni-P-SiC composite plating layer, a Ni-P-TiB2 composite plating layer or a Ni-P-SiC-TiB2 composite plating layer on the surface thereof. The preparation method comprises the following steps: the surface of the carbon fiber is put in chemical plating liquid for chemically plating the Ni-P-SiC, Ni-P-TiB2 or Ni-P-SiC-TiB2 composite layer to obtain the compact and uniform composite plating layer after pretreatment of degumming, roughening, neutralization, sensitization, activation, reduction and peptization; the bonding force of the composite plating layer and the carbon fiber is high; the compatibility of the modified carbon fiber and a metal matrix is excellent; the dispersibility in the metal matrix is excellent; a carbon fiber reinforced metal base composite material with good mechanical performance, stable performance and good reliability can be prepared; and the preparation method of the modified carbon fiber is simple and low in cost, and facilitates industrial production.

Description

technical field [0001] The invention relates to a modified carbon fiber and a preparation method thereof, in particular to a modified carbon fiber containing Ni-P-SiC and Ni-P-TiB 2 or Ni-P-SiC-TiB 2 The invention relates to a modified carbon fiber of a composite coating and a preparation method thereof, belonging to the technical field of preparation of modified carbon fiber materials. Background technique [0002] Carbon fiber has a series of excellent properties such as low density, high specific strength, high specific modulus, and high temperature resistance. One of its important applications is load bearing as a reinforcement for composite materials. For example, carbon fiber can be combined with metal aluminum to prepare aluminum matrix composites with high modulus and high strength. Thermal oxidation leads to a decrease in mechanical properties. [0003] In response to these problems, researchers have proposed some methods to solve them. Among them, the most repo...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C18/50C23C18/18
CPCC23C18/1639C23C18/1893C23C18/50
Inventor 李国栋杨娟刘阳陈鑫张军孙晔华
Owner CENT SOUTH UNIV
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