Novel carbon-based material supporting spinel catalyst and preparation method thereof

A technology of carbon-based materials and catalysts, which is applied in the field of new-type carbon-based material-loaded spinel catalysts and its preparation, which can solve the problems of low efficiency and achieve uniform particle size, high purity, and good dispersion

Inactive Publication Date: 2017-04-26
SHANDONG UNIV
View PDF4 Cites 10 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In recent years, more research tends to study carbon-based material-supported metal oxide catalysts. These catalysts are generally concentrated in the treatment of air pollution and water pollution, and their preparation pro...

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Novel carbon-based material supporting spinel catalyst and preparation method thereof
  • Novel carbon-based material supporting spinel catalyst and preparation method thereof
  • Novel carbon-based material supporting spinel catalyst and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0077] After acidifying 5g of activated coke with 3mol / L nitric acid at 75°C for 2h, immerse in 15mL of a mixed solution of 0.02mol / L ferric nitrate and 0.01mol / L nickel nitrate for 24h, and add 15mL of 0.1mol / L ammonia water, adjust the pH to 10, continue magnetic stirring for 2 hours, add to a hydrothermal kettle, react at 180°C for 24 hours, filter and dry, and calcinate at 500°C for 4 hours in a nitrogen atmosphere to prepare NiFe 2 o 4 / ASC catalyst, malachite green as water pollutant (100mg / L), 800W microwave catalytic removal rate see figure 1 .

Embodiment 2

[0079] After acidifying 5g of activated coke with 3mol / L nitric acid at 80°C for 2h, immerse in 15mL of a mixed solution of 0.02mol / L ferric nitrate and 0.01mol / L cobalt nitrate for 24h, and add 15mL of 0.1mol / L ammonia water, adjust the pH to 10, continue magnetic stirring for 2 hours, add to a hydrothermal kettle, react at 180°C for 24 hours, filter and dry, and calcinate at 500°C for 4 hours in a nitrogen atmosphere to prepare CoFe 2 o 4 / ASC catalyst, the catalyst is characterized by XRD as image 3 shown, indicating that the spinel CoFe 2 o 4 Loaded on the surface of active coke, the toluene C 7 h 8 (Tar mold compound) as a gas pollutant (1000ppm), 800W microwave catalytic removal rate see figure 2 .

Embodiment 3

[0081] Put 5g of activated carbon into air with an oxygen volume concentration of 8vol.%, and after oxygen etching treatment at 300°C for 0.5h, immerse in 15mL of a mixed solution of 0.02mol / L cobalt nitrate and 0.01mol / L ferric nitrate for 24h , in the state of magnetic stirring, add 15mL sodium hydroxide solution, adjust the pH to 10, continue magnetic stirring for 2h, add a hydrothermal kettle, react at 180°C for 24h, filter and dry, calcinate at 500°C for 4h in a nitrogen atmosphere, and prepare FeCo 2 o 4 / AC Catalyst.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a novel carbon-based material supporting spinel catalyst and a preparation method thereof, wherein a carbon-based substance serves as a supporter and transition metal elements, in a spinel or an inverse spinel structure, are supported on the supporter through the steps of stepwise impregnation, alkali treatment, high-pressure hydrolysis and the like. According to the method, the spinel can be supported on the carbon-based material, thus producing the carbon-based material supporting spinel catalyst.

Description

technical field [0001] The invention belongs to the field of material preparation and pollution treatment, and in particular relates to a novel carbon-based material-loaded spinel catalyst and its preparation method and application. Background technique [0002] Since the beginning of the 21st century, with the rapid development of China's industry, pollution problems have become increasingly serious. Faced with increasingly stringent national regulations and people's growing awareness of environmental protection, pollution treatment is imminent. The transition metal spinel structure, because of its high ability to transfer electrons, can better promote the oxidation or reduction of pollutants in pollutant treatment, so it is widely used in water pollution or air pollution treatment, but spinel The preparation of stone structure generally adopts the method of solid solution, which consumes a lot of energy, and the purity of the prepared material is not high, and the phase is...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): B01J23/755B01J23/745B01J23/75B01J23/889C02F1/30C02F1/72B01D53/86B01J20/20
CPCB01D53/86B01D2258/0283B01J20/20B01J23/005B01J23/745B01J23/75B01J23/755B01J23/8892C02F1/302C02F1/725Y02C20/30
Inventor 周玉立王文龙宋占龙孙静毛岩鹏赵希强
Owner SHANDONG UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap