Polytrimethylene terephthalate toughened color master batch and preparing method thereof

A polytrimethylene terephthalate and color masterbatch technology, which is applied in the polymer field, can solve problems such as hindering the development of polytrimethylene terephthalate color masterbatch, poor heat resistance and discoloration of PTT resin, and achieves Excellent impact resistance, improved physical properties, strong coloring effect

Inactive Publication Date: 2017-04-26
CHUZHOU MADIL PLASTIC
View PDF4 Cites 2 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Masterbatch coloring has the advantages of good dispersibility, no pollution and convenient use, and overcomes the problems of color points, color difference and production environment pollution that exist in direct coloring with toner. However, polytrimethylene terephthalate masterbatches are more With PTT resin as the carrier, PTT resin has poor heat resistance, and it will change color after many times of heat history, which hinders the development of polytrimethylene terephthalate masterbatch

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

specific Embodiment 1

[0022] A kind of polytrimethylene terephthalate toughening masterbatch described in this embodiment, its component ratio by mass percentage is: PTT resin 20%, pigment 15%, ACR 10%, nanometer barium sulfate 5%, 2% cold-resistant toughening agent, 2% reinforcing modifier, 2% coupling agent, 2% heat stabilizer, 1% antioxidant, and 1% dispersant.

[0023] Specifically, the toner is a mixture of titanium dioxide, phthalocyanine green, phthalocyanine blue and carbon black in a weight ratio of 8:20:3:1; the titanium dioxide is composed of rutile titanium dioxide and anatase titanium A mixture of white powder with a weight ratio of 1:1.5; the coupling agent is isopropyl triisostearyl titanate.

[0024] Specifically, the cold-resistant toughening agent is a mixture of amide-based β-crystal nucleating agents and dicarboxylate-based β-crystal nucleating agents at a weight ratio of 1:1.2; the reinforcing modifier is nanocarbonic acid One or more mixtures of calcium, nano-silicon and nano...

specific Embodiment 2

[0036] A polytrimethylene terephthalate toughening color masterbatch described in this embodiment, its components are proportioned by mass percentage: PTT resin 35%, pigment 27.5%, ACR 17.5%, nano barium sulfate 17.5%, 3% cold-resistant toughening agent, 3% reinforcing modifier, 3% coupling agent, 5% heat stabilizer, 2% antioxidant, and 2% dispersant.

[0037] Specifically, the toner is a mixture of titanium dioxide, phthalocyanine green, phthalocyanine blue and carbon black at a weight ratio of 10:25:5:2.5; the titanium dioxide is composed of rutile titanium dioxide and anatase titanium White powder is a mixture with a weight ratio of 1:2; the coupling agent is isopropyl triisostearyl titanate.

[0038] Specifically, the cold-resistant toughening agent is a mixture of amide-based β-crystal nucleating agents and dicarboxylate-based β-crystal nucleating agents at a weight ratio of 1:1.5; the reinforcing modifier is nanocarbonic acid One or more mixtures of calcium, nano-silico...

specific Embodiment 3

[0050] A polytrimethylene terephthalate toughening color masterbatch described in this embodiment, its components are proportioned by mass percentage: PTT resin 50%, pigment 40%, ACR 25%, nano barium sulfate 30%, 4% cold-resistant toughening agent, 4% reinforcing modifier, 4% coupling agent, 8% heat stabilizer, 3% antioxidant, and 3% dispersant.

[0051] Specifically, the toner is a mixture of titanium dioxide, phthalocyanine green, phthalocyanine blue and carbon black in a weight ratio of 12:30:7:4; the titanium dioxide is composed of rutile titanium dioxide and anatase titanium A mixture of white powder with a weight ratio of 1:2.5; the coupling agent is isopropyl triisostearyl titanate.

[0052] Specifically, the cold-resistant toughening agent is a mixture of amide-based β-crystal nucleating agents and dicarboxylate-based β-crystal nucleating agents at a weight ratio of 1:1.8; the reinforcing modifier is nanocarbonic acid One or more mixtures of calcium, nano-silicon and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a polytrimethylene terephthalate toughened color master batch. The polytrimethylene terephthalate toughened color master batch comprises, by mass percent, 20%-50% of PPT resin, 15%-40% of pigment, 10%-25% of ACR, 5%-30% of nano barium sulfate, 2%-4% of a cold-resistant toughening agent, 2%-4% of an enhanced modifying agent, 2%-4% of a coupling agent, 2%-8% of a heat stabilizer, 1%-3% of antioxidant and 1%-3% of a dispersing agent. According to the polytrimethylene terephthalate toughened color master batch, the technology process is improved, the polytrimethylene terephthalate toughened color master batch has the beneficial effects of being environment-friendly, free of pollution, high in dispersibility, good in heat stability, high in dyeing property, good in impact resistance and the like, and the actual using requirement is met.

Description

technical field [0001] The invention relates to a poly(trimethylene terephthalate) toughened color masterbatch and a preparation method thereof, belonging to the technical field of macromolecules. Background technique [0002] Plastic is mainly composed of carbon, oxygen, hydrogen and nitrogen and other organic or inorganic elements, and can be formed into plastic products of various shapes and colors. It has been widely used in every field of modern life; such as household appliances, instruments Apparatus, wire and cable, construction equipment, communication electronics, automobile industry, aerospace, daily hardware, etc. There are three kinds of coloring methods for producing plastic products in the prior art: toner coloring, dyeing and pulling grain coloring and masterbatch coloring. When directly using toner for coloring, the coloring is very simple, but it has the disadvantages of easy to produce color spots, difficult to control color difference, and great environm...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/02C08L33/04C08K13/02C08K3/30C08K3/26C08K3/22C08K3/04C08K5/10C08K5/20C08K5/098
CPCC08L67/02C08K2201/011C08K2201/014C08L2201/08C08L2310/00C08L33/04C08K13/02C08K2003/3045C08K2003/265C08K2003/2241C08K3/04C08K5/10C08K5/20C08K5/098
Inventor 涂前峰
Owner CHUZHOU MADIL PLASTIC
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap