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Preparation method for carbon nanofiber electrode

A carbon nanofiber and electrode technology, applied in the field of carbon nanofiber electrode preparation, can solve the problems of uneven distribution on the surface of the current collector, obliteration of the advantages of carbon nanofibers, and inability to fully utilize them, so as to facilitate the transmission of ions and solve the preparation efficiency The effect of low and high specific capacitance

Inactive Publication Date: 2017-05-10
XIAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The advantage of this preparation method is that the damaged film can be made into an electrode sheet, but the operation is relatively complicated, and it may be unevenly distributed on the surface of the current collector; the other is to directly sandwich the carbon nanofiber film between two current collectors at a certain compression molding under pressure
This preparation method is simple to operate and does not require the use of conductive carbon black and binders, but the disadvantage is that it cannot make full use of the radially rich pore structure of carbon nanofibers, obliterating the unique advantages of carbon nanofibers

Method used

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  • Preparation method for carbon nanofiber electrode
  • Preparation method for carbon nanofiber electrode
  • Preparation method for carbon nanofiber electrode

Examples

Experimental program
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Embodiment 1

[0028] This embodiment includes the following steps:

[0029] Step 1. Preparation of carbon nanofibers: Add polyacrylonitrile powder, polymethyl methacrylate powder and graphene to N, N-dimethylformamide, and stir evenly with a magnetic stirrer to obtain homogeneously dispersed The transparent spinning solution is then spun with an electrospinning device at a temperature of 35°C to obtain a fiber film. The electrospun carbon nanofiber film is a network structure composed of fibers of about 150nm to 400nm , then spread the fiber film on a high-temperature-resistant quartz plate, put it into a tube furnace for pre-oxidation treatment, and finally obtain a carbon nanofiber film; the polyacrylonitrile powder, polymethyl methacrylate powder and The mass ratio of N,N-dimethylformamide is 2:1:30; the added amount of the graphene is 0.3% of the total mass of the polyacrylonitrile powder and polymethyl methacrylate powder;

[0030] The electrospinning device is produced by Beijing Fuy...

Embodiment 2

[0037] This embodiment includes the following steps:

[0038] Step 1. Preparation of carbon nanofibers: Add polyacrylonitrile powder and polymethyl methacrylate powder to N, N-dimethylformamide, and stir evenly with a magnetic stirrer to obtain homogeneously dispersed transparent spinning liquid, and then use an electrospinning device to spin at a temperature of 33°C to obtain a fiber film, then spread the fiber film on a high-temperature resistant quartz plate, and then put it into a tube furnace for pre-oxidation treatment , to finally obtain a carbon nanofiber film; the mass ratio of the polyacrylonitrile powder, polymethyl methacrylate powder and N,N-dimethylformamide is 2:1:30;

[0039] The electrospinning device is produced by Beijing Fuyouma Technology Co., Ltd., and the model is 1206. The process parameters of the electrospinning are: the voltage of the high-voltage power supply is 25kV, the distance from the needle tip to the drum receiver is 18cm, and the spinning S...

Embodiment 3

[0045] This embodiment includes the following steps:

[0046] Step 1. Preparation of carbon nanofibers: Add polyacrylonitrile powder to N,N-dimethylformamide, stir evenly with a magnetic stirrer to obtain a homogeneously dispersed transparent spinning solution, and then use an electrospinning device Spinning at a temperature of 30°C to obtain a fiber film, then spread the fiber film on a high-temperature-resistant quartz plate, and then put it into a tube furnace for pre-oxidation treatment, and finally obtain a carbon nanofiber film; The mass ratio of the polyacrylonitrile powder to N,N-dimethylformamide is 1:10;

[0047] The electrospinning device is produced by Beijing Fuyouma Technology Co., Ltd., and the model is 1206. The process parameters of the electrospinning are: the voltage of the high-voltage power supply is 25kV, the distance from the needle tip to the drum receiver is 18cm, and the spinning Silk flow rate is 2mL / h;

[0048] The specific process of the pre-oxid...

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Abstract

The invention discloses a preparation method for a carbon nanofiber electrode. The method comprises the steps of 1, adding polymer powder to N,N-dimethylformamide, performing stirring to obtain a homogenous and dispersed transparent spinning solution, performing spinning by using an electrostatic spinning apparatus to obtain a fiber membrane, then flatly laying the fiber membrane on a high-temperature-resistant quartz plate, putting the quartz plate into a tubular furnace for performing pre-oxidization treatment, and finally obtaining a carbon nanofiber membrane; and 2, cutting the carbon nanofiber membrane into a plurality of thin strip-shaped carbon nanofiber membranes, upwards and vertically putting cuts of all the thin strip-shaped carbon nanofiber membranes between two foam nickel sheets, then putting lead wires between the cuts of the thin strip-shaped carbon nanofiber membranes and the foam nickel sheets, and finally performing pressing to obtain the carbon nanofiber electrode. The preparation method is simple in operation; and as a supercapacitor electrode material, rich hole structures in the carbon nanofiber membrane can be fully utilized, thereby facilitating quick transmission of ions.

Description

technical field [0001] The invention belongs to the technical field of electrode preparation, and in particular relates to a method for preparing a carbon nanofiber electrode. Background technique [0002] Carbon nanofibers (CNFs), as a new type of nanocarbon material with a quasi-one-dimensional structure, have many advantages such as easy processing and molding, controllable microstructure, excellent mechanical properties, large specific surface area, and good electrical conductivity. It has broad application prospects in the field of supercapacitors, and has attracted much attention in scientific research and industry in recent years. [0003] Electrodes are the key components of supercapacitors, and their preparation methods greatly affect the electrochemical performance of supercapacitors. At present, there are two main methods for the preparation of carbon nanofiber electrodes: one is to grind the carbon nanofiber film into powder, then mix it with conductive carbon b...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/86H01G11/36
CPCH01G11/36H01G11/86Y02E60/13
Inventor 张亚婷付世启张婧蔡江涛李可可任绍昭陈晨周安宁邱介山
Owner XIAN UNIV OF SCI & TECH
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