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Low-foam glufosinate-ammonium synergist and preparation method thereof

A synergist, glufosinate-ammonium technology, applied in the field of pesticides, can solve the problems of short duration of efficacy, long wetting time, difficult to achieve, etc., and achieves long duration of efficacy, easy production and feeding, and simple production method. Effect

Inactive Publication Date: 2017-05-24
江苏凯元科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] And prior art glufosinate-ammonium aqueous preparation adopts fatty alcohol polyoxyethylene ether sodium sulfate as main synergist preparation, and its shortcoming is:
[0005] (1) Excessive viscosity: Fatty alcohol polyoxyethylene ether sodium sulfate has too high viscosity, similar to a paste-like substance, and it is extremely difficult to add materials in production, especially in winter, which affects processing and production efficiency
[0006] (2) High foaming properties: Compounds with sodium sulfate groups have large foaming properties and are difficult to eliminate. It is difficult to meet the national requirement of 20 times diluted foam height of FAO, and the use effect is not ideal.
[0007] (3) The synergistic effect is not significant: the existing technology uses fatty alcohol polyoxyethylene ether sodium sulfate and sodium sarcosinate as synergists, and the wetting time of the prepared glufosinate-ammonium aqueous solution is generally 90~180s. Too long; the herbicidal effect lasts for 3 weeks, and the duration of the drug effect is shorter
[0008] (4) The dilution stability of the compounding pharmaceutical industry is poor, and flocculation and precipitation are prone to occur, which affects the stability of product quality
[0009] (5) The adjuvants have poor versatility for glufosinate-ammonium technical materials, and can be used for the technical powder of the original drug, but it is easy to turbid the preparation of the original drug of the mother liquor; the problem of poor compatibility with the original drugs of different manufacturers also occurs

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] The following weights were taken: dodecyldimethyl betaine 30g; sodium dodecylbenzenesulfonate 30g; KY-555 10g; KY-R01 16g; AEO-5 10g; citric acid 4g. Add 30g of dodecyldimethyl betaine and 30g of sodium dodecylbenzenesulfonate into a four-necked flask, stir and heat to 80°C; then add 10g of KY-555; 16g of KY-R01; AEO- 510g; Stir evenly, finally add 4g of citric acid as a pH regulator, stir to neutralize, cool and discharge to prepare low-foaming glufosinate-ammonium synergist.

[0032] The low-foam type glufosinate-ammonium synergist of preparation is carried out pH value measurement:

[0033] Weigh 1.0g of the glufosinate-ammonium synergist product into a beaker, add deionized water to 100g, stir well, measure the pH value with a pH meter, and measure the pH value of the low-foaming glufosinate-ammonium synergist as 5.0.

[0034] Viscosity determination:

[0035] Instrument: NDJ-1 rotary viscometer (Shanghai Hengping Instrument Factory);

[0036] Test temperature: 2...

Embodiment 2

[0045] The following weights of material were taken: tetradecyl dimethyl betaine 30 g; sodium lauryl sulfate 30 g; KY-555 10 g; KY-R01 16 g; AEO-5 10 g; citric acid 4 g. Add 30g tetradecyldimethyl betaine and 30g sodium lauryl sulfate into a four-necked flask, stir and heat to 80°C; then add 10g of KY-555; 16g of KY-R01; 10g of AEO-5 Stir evenly, finally add 4 g of citric acid as a pH regulator, stir to neutralize, and cool and discharge to prepare a low-foaming glufosinate-ammonium synergist.

[0046] According to the test method of Example 1, the low-foaming glufosinate-ammonium synergist prepared by this formula has a pH value of 4.8, a viscosity of 160 mPa.s, and a surface tension of 11 mN / m.

Embodiment 3

[0048] Take the following weights of material: Lauryl dimethyl betaine 30g; Sodium lauryl sulfate 20g; KY-555 15g; KY-R01 17g; AEO-5 15g; Citric acid 3g. Add 30g of dodecyl dimethyl betaine and 25g of sodium lauryl sulfate into a four-neck flask, stir and heat to 80°C; then add 15g of KY-555; 17g of KY-R01; 15g of AEO-5 Stir evenly, finally add 3 g of citric acid as a pH regulator, stir to neutralize, cool and discharge, and obtain a low-foaming glufosinate-ammonium synergist.

[0049] According to the test method of Example 1, the pH value of the low-foaming glufosinate-ammonium synergist prepared by this formula is 4.5, the viscosity is 130mPa.s, and the surface tension is 15mN / m.

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Abstract

The invention relates to a low-foam glufosinate-ammonium synergist and a preparation method thereof. The low-foam glufosinate-ammonium synergist provided by the invention is prepared from the following substances in parts by mass: 10 to 30 parts of glycine betaine substance, 10 to 30 parts of surface active agent, 0.1 to 20 parts of dispersing agent, 0.1 to 20 parts of wetting agent, 0.1 to 10 parts of penetrating agent, and 0.1 to 10 parts of pH (Potential Of Hydrogen) regulator. The preparation method comprises the steps of adding the glycine betaine and the surface active agent into a reaction vessel, and stirring and heating to 80 DEG C; adding the dispersing agent, the wetting agent and the penetrating agent into a product, and uniformly stirring; then adding metered pH regulator, carrying out neutral reaction completely, and cooling for discharging materials. The low-foam glufosinate-ammonium synergist provided by the invention has the advantages of simple production method, easiness in preparation, low foamability and excellent wettability; a glufosinate-ammonium aqueous solution pesticide prepared by the synergist provided by the invention has a good weeding effect and slow reviving speed; the prepared synergist is safe to use without environment pollution.

Description

technical field [0001] The invention belongs to the field of pesticides, and in particular relates to a low-foaming glufosinate-ammonium synergist and a preparation method thereof. Background technique [0002] Glufosinate-ammonium is a new type of herbicide developed in the 1980s by Hearst Corporation (currently a subsidiary of Bayer Corporation). In addition to its herbicidal activity, it also has insecticidal and fungicidal activity. It can be mixed with insecticides to achieve The effect of prevention at the same time. The herbicide has the characteristics of high efficiency, low toxicity, and easy degradation. Water is the base agent, and it is safe and convenient to use. As an excellent herbicide, glufosinate-ammonium is very suitable as a resistance gene. With glufosinate-ammonium as the target, Hearst has successfully introduced glufosinate-ammonium resistance genes into more than 20 crops such as rice, wheat, and corn through resistance gene transfer and breeding ...

Claims

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Application Information

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IPC IPC(8): A01N25/30A01N25/02A01N57/20A01P13/00
CPCA01N25/02A01N25/30A01N57/20A01N2300/00
Inventor 何华雄朱极刘阳生展红明
Owner 江苏凯元科技有限公司
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