Gear oil composition and preparation method thereof

A technology of composition and gear oil, which is applied in the field of lubricating oil, can solve the problems of high solubility of base oil, difficulty in preparing uniform and transparent liquid, and complicated preparation process of friction reducing agent, so as to reduce energy consumption, viscosity and temperature Excellent performance, noise reduction and body temperature reduction effect

Active Publication Date: 2017-05-24
SHANGHAI HITECRUN SPECIAL LUBRICATE SCI & TECH
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  • Abstract
  • Description
  • Claims
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Problems solved by technology

[0003] Patent application document CN101280240A provides a gear oil composition, the additives of which are composed of phosphite and phosphoric acid ester phosphorus-based extreme pressure agent, nitrogen-based anti-corrosion agent, nitrogen-sulfur-based anti-corrosion agent, viscosity index improver, dialkyl di Compositions such as zinc thiophosphate have moderate extreme pressure and anti-wear properties, but cannot improve the anti-wear properties of the product
[0004] Patent application document CN105524682A prepared a wear self-repairing gear oil by adding 5-20% organic molybdenum wear reducer, which has certain oxidation resistance and extreme pressure and anti-wear properties at different temperatures, and can also protect gears The surface can be repaired to a certain extent, but the molybdenum compound has high requirements on the solubility of the base oil, and it is difficult to prepare a uniform and transparent liquid
[0005] Patent application document CN105555929A relates to a gear oil composition containing a base stock and at least 0.01wt% of friction-reducing additives, the friction-reducing additives include glycerin and / or polyglycerol C12-C24 saturated fatty esters, and the friction coefficient can be reduced to 0.66 or so, but the preparation process of the friction reducer is complicated, and there is no commercially produced commodity

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  • Gear oil composition and preparation method thereof
  • Gear oil composition and preparation method thereof

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preparation example Construction

[0046] Specifically, the alkoxy phosphate antiwear agent can be a commercially available product, or it can be prepared by a conventional preparation method. For example, the preparation method of the alkoxy phosphate antiwear agent The method includes: reacting low carbon alcohol with phosphorus oxychloride to obtain alkyl phosphoric acid, and reacting the alkyl phosphoric acid with amine to obtain alkoxy phosphate antiwear agent.

[0047] According to the gear oil composition of the present invention, based on the total weight of the gear oil composition as 100%, the addition of fatty acid is 0.1-3%, preferably 0.3-2%; when the addition of fatty acid is less than 0.1% , cannot promote the sufficient dissolving of hydrophilic fumed silicon dioxide, and when the addition of fatty acid is greater than 3%, its effect of promoting dispersion no longer continues to increase, and the utilization rate of fatty acid of the present invention declines.

[0048] Specifically, the fatty ...

Embodiment 1

[0074] Add 1 part by weight of dodecyltrimethoxysilane (manufacturer: Nanjing Quanxi Chemical Co., Ltd., brand QX-1213, the same below) to 1 part by weight of hydrophilic fumed silica (manufacturer : Evonik Degussa company, trade mark: AEROSIL 300, hereinafter the same) in the heating vessel, be warming up to 80 ℃, fully stir 20min; With the pentaerythritol ester of 60 weight parts (manufacturer: Croda Chemical company, trade mark: Priolube3987, hereinafter the same) and 33.9 parts by weight of polyalphaolefin synthetic oil (manufacturer: Exxonmobil company, trade mark: Synbase Polyolefin40) joins in the reactor, maintains still temperature at 80 ℃, adds the stearic acid of 1 weight part, stirs 7min to uniform transparency; Add the mixture of dodecyltrimethoxysilane and hydrophilic fumed silica in the heating container into the stainless steel mixing kettle, stir for 10 minutes, stop heating, and use cooling water to lower the temperature of the kettle to 50 ° C, and then succe...

Embodiment 2

[0091] Add 0.8 parts by weight of dodecyltrimethoxysilane into a heating container containing 0.5 parts by weight of hydrophilic fumed silica, raise the temperature to 90°C, and stir thoroughly for 10 minutes; add 84.3 parts by weight of mineral oil 150BS (Manufacturer: Sinopec Maoming Petrochemical Company, brand: 150BS) and 10 parts by weight of pentaerythritol ester were added to the reaction kettle, and the temperature of the reaction kettle was maintained at 90 ° C. Added 1 part by weight of dodecyl hydroxystearic acid and stirred for 10 minutes until uniform Transparent; then add the mixture of dodecyltrimethoxysilane and hydrophilic fumed silica in the heating container into the stainless steel mixing kettle, stir for 30 minutes, stop heating, and use cooling water to lower the temperature of the kettle to 50°C. Then sequentially add 0.8 parts by weight of thiadiazole disulfide dimer, 1.5 parts by weight of alkoxy phosphate, 1 part by weight of octylbutyl diphenylamine, ...

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Abstract

The invention provides a gear oil composition and a preparation method thereof. The gear oil composition comprises the following components in percentage by total weight of100%: 78.5-98.39% of base oil, preferably 85-97%, and more preferably 91-95%, 0.1-4% of a sulfur-containing extreme pressure agent, preferably 0.5-2%, 0.1-4% of a phosphorus-containing anti-wear agent, preferably 0.5-2%, 0.1-3% of fatty acid, preferably 0.3-2%, 0.1-1% of alkylsilane, preferably 0.5-1%, 0.3-6% of hydrophilic fumed silica, preferably 0.5-3%, 0.01-0.5% of a metal deactivator, preferably 0.03-0.1%, 0.3-3% of an antioxidant, preferably 0.5-1.5%. The gear oil composition provided by the invention sufficiently utilizes the wear reduction function of the hydrophilic fumed silica and the extreme pressure anti-wear functions of the sulfur-containing extreme pressure agent and the phosphorus-containing anti-wear agent, and is a gear oil composition with integrated functions of wear reduction, wear resistance, extreme pressure resistance, oxidation resistance and corrosion resistance.

Description

technical field [0001] The invention relates to a gear oil composition and a preparation method thereof, belonging to the field of lubricating oil. Background technique [0002] Gear oil is one of the three major varieties of lubricating oil, which plays a vital role in the power transmission of various equipment. Due to the heavy load of gears during work, good extreme pressure and anti-wear properties are one of the most important characteristics of gear oils. Especially with the development of machinery towards high-load, high-temperature, and high-pressure operations, it is very important for industrial The load-bearing capacity and anti-friction and anti-wear properties of gear oil are increasingly required to prevent tooth surface wear, abrasion, sintering, etc., thereby prolonging its service life and improving power transmission efficiency. [0003] Patent application document CN101280240A provides a gear oil composition, the additives of which are composed of phosp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10N30/02C10N30/06C10N30/10C10N30/12C10N40/04
CPCC10M169/045C10M2201/10C10M2203/1025C10M2205/0285C10M2207/126C10M2207/128C10M2207/2835C10M2215/064C10M2215/223C10M2219/022C10M2219/106C10M2223/041C10M2223/08C10M2227/04C10N2030/02C10N2030/06C10N2030/10C10N2030/12C10N2030/72C10N2030/76C10N2040/04
Inventor 范海粉王瑞兴
Owner SHANGHAI HITECRUN SPECIAL LUBRICATE SCI & TECH
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