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A kind of microcapsule foamed melamine foam material and preparation method thereof

A technology of microcapsule foaming and foam materials, which is applied in the field of foam materials, can solve the problems of low compressive strength, uneven performance, and good thermal conductivity of foam, and achieve good flame retardancy, good heat preservation effect, and good mechanical properties.

Active Publication Date: 2019-04-30
HEFEI UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But use mechanical foaming method, or use the melamine foam prepared by traditional physical blowing agent, chemical blowing agent to have various performance defects, such as the inhomogeneous cell structure of each part of the foam material, thus The performance of each part is not uniform; its opening rate is high, which leads to good thermal conductivity of the foam and poor thermal insulation performance; its cell distribution is uneven, and it is easy to generate stress concentration points, making the compressive strength smaller; the foam cells are larger, It is difficult to form a dense protective carbon layer during combustion, and its oxygen index (OI) is generally below 32%.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:

[0029] (1) Preparation of microcapsule foaming agent

[0030] Weigh 260g of deionized water into a 500ml four-neck flask, add 30g of sodium lauryl sulfate, stir, and ultrasonically treat to obtain the aqueous phase.

[0031] Weigh 60g of hydroxyethyl methacrylate, 22g of a saturated aqueous solution of sodium bicarbonate, 1.8g of azobisisobutyronitrile, and 0.27g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.

[0032] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, blow nitrogen into the four-neck flask for 30 minutes, polymerize at 65°C for 3 hours, and polymerize at 70°C for 12 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.

[0033] (2...

Embodiment 2

[0038] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:

[0039] (1) Preparation of microcapsule foaming agent

[0040] Weigh 285g of deionized water into a 500ml four-neck flask, add 15g of sodium lauryl sulfate and 20g of Span-60, stir and ultrasonically treat to obtain the aqueous phase.

[0041] Weigh 50g of hydroxypropyl methacrylate, 15g of cyclohexane, 1.3g of azobisisobutyronitrile, and 0.21g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.

[0042] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, pass nitrogen gas into the four-neck flask for 30 minutes, polymerize at 60°C for 10 hours, and polymerize at 65°C for 5 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.

[0043] (2) Preparation of...

Embodiment 3

[0048] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:

[0049] (1) Preparation of microcapsule foaming agent

[0050] Weigh 300g of deionized water into a 500ml four-neck flask, add 28g of sodium dodecylbenzenesulfonate, stir and ultrasonically treat to obtain the aqueous phase.

[0051] Weigh 20g of hydroxyethyl methacrylate, 55g of hydroxypropyl methacrylate, 25g of heptane, 2.3g of azobisisobutyronitrile, and 0.32g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.

[0052] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, blow nitrogen into the four-neck flask for 30 minutes, polymerize at 65°C for 3 hours, and polymerize at 75°C for 10 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.

[0053] (2) ...

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PUM

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Abstract

The invention relates to microcapsule-foaming melamine foam, which is prepared from a melamine resin prepolymer through microcapsule foaming. A used microcapsule foaming agent is a microcapsule foaming agent with a hydroxy on a wall material; the closed pore rate of the melamine foam is higher, and achieves than 96 percent or more; the heat preservation effect is better, and the heat conductivity coefficient is lower than 0.028W / m.K; the mechanical property is better, and the compression strength achieves 180KPa or more; better flame retardant property is realized, and the oxygen index achieves 37 percent or more. Used foaming liquid has only three components, and no emulsifying agent or foam stabilizer needs to be added in the melamine resin prepolymer, so that the process flow is simple, and the production cost is lower; the prepared microcapsule foaming agent with the hydroxy on the wall material can be applicable to various melamine resin prepolymers with different kinds and different viscosity, the foaming temperature is lower, and the foaming time is shorter.

Description

technical field [0001] The invention belongs to the technical field of foam materials, and in particular relates to a microcapsule foamed melamine foam material and a preparation method thereof. Background technique [0002] Melamine foam is a kind of thermosetting polymer material, which has good heat resistance, solvent resistance, electrical properties and mechanical strength, and has excellent flame retardant properties such as self-extinguishing after leaving the fire, and no molten droplets dripping when burning. . These excellent properties of melamine foam make it widely used in various industries and fields, gradually replacing other existing foam materials. But use mechanical foaming method, or use the melamine foam prepared by traditional physical blowing agent, chemical blowing agent to have various performance defects, such as the inhomogeneous cell structure of each part of the foam material, thus The performance of each part is not uniform; its opening rate ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08F222/14C08J9/32C08L61/28B01J13/14C08F220/28
CPCB01J13/14C08F220/28C08F220/281C08J9/32C08J2203/22C08J2361/28C08F222/102
Inventor 马海红王雪帆宋聪强周淑千徐卫兵周正发任凤梅杨子征
Owner HEFEI UNIV OF TECH
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