A kind of microcapsule foamed melamine foam material and preparation method thereof
A technology of microcapsule foaming and foam materials, which is applied in the field of foam materials, can solve the problems of low compressive strength, uneven performance, and good thermal conductivity of foam, and achieve good flame retardancy, good heat preservation effect, and good mechanical properties.
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Embodiment 1
[0028] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:
[0029] (1) Preparation of microcapsule foaming agent
[0030] Weigh 260g of deionized water into a 500ml four-neck flask, add 30g of sodium lauryl sulfate, stir, and ultrasonically treat to obtain the aqueous phase.
[0031] Weigh 60g of hydroxyethyl methacrylate, 22g of a saturated aqueous solution of sodium bicarbonate, 1.8g of azobisisobutyronitrile, and 0.27g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.
[0032] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, blow nitrogen into the four-neck flask for 30 minutes, polymerize at 65°C for 3 hours, and polymerize at 70°C for 12 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.
[0033] (2...
Embodiment 2
[0038] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:
[0039] (1) Preparation of microcapsule foaming agent
[0040] Weigh 285g of deionized water into a 500ml four-neck flask, add 15g of sodium lauryl sulfate and 20g of Span-60, stir and ultrasonically treat to obtain the aqueous phase.
[0041] Weigh 50g of hydroxypropyl methacrylate, 15g of cyclohexane, 1.3g of azobisisobutyronitrile, and 0.21g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.
[0042] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, pass nitrogen gas into the four-neck flask for 30 minutes, polymerize at 60°C for 10 hours, and polymerize at 65°C for 5 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.
[0043] (2) Preparation of...
Embodiment 3
[0048] The concrete operating steps of the melamine foam material that prepares microcapsule foaming are as follows:
[0049] (1) Preparation of microcapsule foaming agent
[0050] Weigh 300g of deionized water into a 500ml four-neck flask, add 28g of sodium dodecylbenzenesulfonate, stir and ultrasonically treat to obtain the aqueous phase.
[0051] Weigh 20g of hydroxyethyl methacrylate, 55g of hydroxypropyl methacrylate, 25g of heptane, 2.3g of azobisisobutyronitrile, and 0.32g of ethylene glycol dimethacrylate, and mix them uniformly to obtain an oil phase.
[0052] After fully mixing the prepared water phase and oil phase, emulsify for 20 minutes, stir, blow nitrogen into the four-neck flask for 30 minutes, polymerize at 65°C for 3 hours, and polymerize at 75°C for 10 hours. After the reaction, cool to room temperature, filter, and use ethanol and The distilled water is washed, and after drying, the microcapsule foaming agent with hydroxyl groups is obtained.
[0053] (2) ...
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