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High-concentration chemical wastewater resourceful integrated treatment technology

A chemical wastewater, high-concentration technology, applied in electrochemical water/sewage treatment, water/sewage treatment, water/sewage multi-stage treatment, etc., can solve problems such as increasing treatment difficulty, secondary water pollution, and waste of water resources , to achieve the effect of improving resource reuse

Inactive Publication Date: 2017-07-14
南京工大膜应用技术研究所有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] Chinese patent (application number: 201511021752.7) discloses a chemical wastewater treatment method, using ionizing radiation catalysis to generate strong oxidative hydroxyl radicals to treat chemical wastewater, but this method is only for acrylonitrile, which contains a single pollutant. Wastewater treatment cannot meet the treatment requirements of high-concentration chemical wastewater with various pollutants
[0015] ①Complicated process: The existing technology usually requires multiple treatment processes to gradually remove the corresponding pollutants, resulting in complex processes, long treatment cycles and high costs;
[0016] ②Secondary pollution: In the multi-channel treatment process of the prior art, it is usually necessary to add different treatment reagents, and the addition of corresponding treatment reagents causes secondary pollution of the water body, thus increasing the difficulty of subsequent treatment;
[0017] ③In the existing technology, the treated water is usually discharged directly. Although zero discharge is achieved, a large amount of water resources and inorganic salts are wasted due to the inability to recycle and reuse, resulting in high treatment costs

Method used

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  • High-concentration chemical wastewater resourceful integrated treatment technology

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Effect test

Embodiment 1

[0035]The COD of production wastewater in a coal chemical plant workshop is 10g / L, and the TDS is 6g / L. A tubular ceramic membrane with a pore size of 4nm is used to filter under the conditions of a transmembrane pressure difference of 0.8MPa and an operating temperature of 80°C. The COD of the produced water is 5g / L; the permeate after membrane filtration is transported to the electrocatalytic oxidation system with a high-pressure pump, the catalyst is alumina particles loaded with manganese oxide, the catalyst dosage is 10wt.% of the system weight percentage, and the reaction current density is 20mA / cm 2 , the pH is controlled at 10, the reaction residence time is 2.5h, and the COD of the wastewater after electrocatalytic oxidation is 20mg / L; the wastewater after electrocatalytic oxidation enters the evaporation unit, and the evaporation process uses a three-effect evaporator with an operating temperature of 50°C. The operating pressure is 0.1kPa, the COD of the water vapor c...

Embodiment 2

[0037] The COD of wastewater produced by a chemical factory is 300g / L, and the TDS is 250g / L. A tubular ceramic membrane with a pore size of 500nm is used to filter under the conditions of a transmembrane pressure difference of 0.1MPa and an operating temperature of 50°C. The COD of the produced water is 100g / L. L; The permeate after membrane filtration is transported to the electrocatalytic oxidation system with a high-pressure pump, and the catalyst is used to support tin oxide on ceramic particles. The catalyst dosage is 30wt.% of the system weight percentage, and the reaction current density is 100mA / cm 2 , the pH is controlled at 5, the reaction residence time is 5h, the COD of the wastewater after electrocatalytic oxidation is 60mg / L; the wastewater after electrocatalytic oxidation enters the evaporation unit, and the evaporation process adopts a mechanical vapor compressor (MVR) evaporator. The temperature is 180°C, the operating pressure is 200kPa, the COD of the water ...

Embodiment 3

[0039] The COD of production wastewater in a fine chemical factory workshop is 130g / L, and the TDS is 110g / L. An organic hollow fiber membrane with a pore size of 100nm is used to filter under the conditions of a transmembrane pressure difference of 0.2MPa and an operating temperature of 10°C. The COD of the produced water is 10g / L; the permeate after membrane filtration is transported to the electrocatalytic oxidation system with a high-pressure pump, and the catalyst is used to support vanadium pentoxide on alumina particles. The catalyst dosage is 20wt.% of the system weight percentage, and the reaction current density is 50mA / cm 2 , the pH is controlled at 7, the reaction residence time is 2.5h, and the COD of the wastewater after electrocatalytic oxidation is 50mg / L; the wastewater after electrocatalytic oxidation enters the evaporation unit, and the evaporation process uses a mechanical vapor compressor (MVR) evaporator. The operating temperature is 130°C, the operating...

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Abstract

The invention relates to a high-concentration chemical wastewater resourceful integrated treatment technology. The high-concentration chemical wastewater resourceful integrated treatment technology is implemented by the following steps: performing membrane filtering treatment on high-concentration chemical wastewater; introducing the wastewater filtered by an ultrafiltration membrane into an electro-catalysis oxidization system; introducing the wastewater being subjected to electro-catalysis oxidization into an evaporating system; introducing evaporation effluent into a recycling system; introducing an evaporation mother solution into a divided crystalizing system; and recycling inorganic salt in the wastewater through a divided crystalizing technology. By adopting the high-concentration chemical wastewater resourceful integrated treatment technology, a treatment process combining ultrafiltration membrane filtering, electro-catalysis, evaporation and divided crystallization is adopted, so that up-to-standard treatment of the wastewater is realized; meanwhile, resourceful utilization of the wastewater is realized; the high-concentration chemical wastewater resourceful integrated treatment technology has the advantages of advanced process, high efficiency and stable and reliable effect.

Description

technical field [0001] The invention belongs to the technical field of environmental protection water treatment, and in particular relates to a resource-based integrated treatment technology for high-concentration chemical wastewater, which realizes the recycling of water resources and inorganic salts while effectively treating high-concentration chemical wastewater, so as to reduce waste of resources and recover costs . Background technique [0002] High-concentration chemical wastewater has a high concentration of pollutants and many components that are difficult to treat. Due to the water quality characteristics of soluble solids such as toxic and harmful components and inorganic salts, it belongs to highly polluted organic wastewater that is difficult to treat. If chemical wastewater is discharged directly without treatment, it will not only pollute water resources, but also have toxic effects on human body and aquatic organisms. Once consumed by humans and animals, it w...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/10C01D5/00C01D3/04
CPCC01D3/04C01D5/00C02F1/048C02F1/444C02F1/46C02F9/00C02F2001/5218
Inventor 周汉涛李佳尧
Owner 南京工大膜应用技术研究所有限公司
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