Well cementing slurry capable of preventing CO2 and H2S corrosion

A technology for cementing cement slurry and cement slurry, which can be used in wellbore/well components, drilling composition, earth-moving drilling, etc., and can solve the problems of increased permeability, decreased compressive strength, and shortened life of oil and gas wells. , to achieve the effect of improving compressive strength, eliminating tiny bubbles and prolonging setting time

Active Publication Date: 2017-07-21
SHAANXI RES DESIGN INST OF PETROLEUM CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

in CO 2 、H 2 Under the joint influence of corrosive media such as S and groundwater, the cement components in the cement stone will continue to decrease, and the permeability will increase, resulting in a decrease in its compressive strength or even no strength at all.
The performance of the cement sheath deteriorates, which will gradually lose the protective effect on the casing, water and gas channeling will occur, and the casing will be completely in the corrosive medium, which will greatly shorten the life of the oil and gas well and affect the normal production
At present, cement extrusion is usually used at home and abroad to block the cement stone corrosion channel, but cement extrusion requires professional equipment, which is expensive and risky
Adding corrosion in

Method used

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  • Well cementing slurry capable of preventing CO2 and H2S corrosion
  • Well cementing slurry capable of preventing CO2 and H2S corrosion

Examples

Experimental program
Comparison scheme
Effect test

Example Embodiment

[0014] Example 1

[0015] An anti-CO 2 , H 2 S-corrosion cementing cement slurry, which is composed of water and cement with a mass ratio (water-cement ratio) of 0.45:1. The cement comes from the following materials: 100 mass units of G-grade high sulfate-resistant oil well cement , 12 mass units of fine cement, 1 mass unit of dispersant SXY, 1.2 mass units of fluid loss agent BXF-200L, 6 mass units of microsilica JM-1, 8 mass units of fly ash , 1.2 mass units of expansion agent M53S, 9 mass units of latex BCT-800L, 1 mass unit of water-soluble methyl etherified urea-formaldehyde resin, 1.5 mass units of early strength agent CK21, 0.1 mass unit of retarder Agent SN-2, 0.6 mass unit defoamer D50.

[0016] The CO 2 , H 2 The preparation method of S-corrosion cementing cement slurry is: firstly mix the water-soluble methyl etherified urea-formaldehyde resin and water evenly, and then mix the mixture with fluid loss agent BXF-200L, latex BCT-800L, and retarder SN-2 , The defoamer D50...

Example Embodiment

[0017] Example 2

[0018] An anti-CO 2 , H 2 S-corrosion cementing cement slurry, which is composed of water and cement with a mass ratio (water-cement ratio) of 0.45:1. The cement comes from the following materials: 100 mass units of G-grade high sulfate-resistant oil well cement , 15 mass units of fine cement, 1.5 mass units of dispersant SXY, 1.3 mass units of fluid loss agent BXF-200L, 5 mass units of microsilica JM-1, 8 mass units of fly ash , 1.3 mass units of expansion agent M53S, 6 mass units of latex BCT-800L, 1.4 mass units of water-soluble maleic anhydride modified epoxy resin, 2.5 mass units of early strength agent CK21, 0.2 mass units The retarder SN-2, 0.7 mass unit defoamer D50.

[0019] The CO 2 , H 2 The preparation method of S-corrosion cement slurry is the same as in Example 1. Code formula 2.

Example Embodiment

[0020] Example 3

[0021] An anti-CO 2 , H 2 S-corrosion cementing cement slurry, which is composed of water and cement with a mass ratio (water-cement ratio) of 0.45:1. The cement comes from the following materials: 100 mass units of G-grade high sulfate-resistant oil well cement , 17 mass units of fine cement, 1.8 mass units of dispersant SXY, 1.2 mass units of fluid loss agent BXF-200L, 7 mass units of microsilica JM-1, 6 mass units of fly ash , 1.7 mass units of expansion agent M53S, 7 mass units of latex BCT-800L, 1.3 mass units of water-soluble acrylic modified alkyd resin, 2 mass units of early strength agent CK21, 0.2 mass units of retarder Coagulant SN-2, 0.7 mass unit defoamer D50.

[0022] The CO 2 , H 2 The preparation method of S-corrosion cement slurry is the same as in Example 1. Code formula 3.

[0023] In order to study the performance of the present invention, the designer conducted a comparative experiment of formula 1, formula 2, formula 3 and conventional ceme...

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Abstract

The invention relates to well cementing slurry capable of preventing CO2 and H2S corrosion. The well cementing slurry comprises water and cement, wherein the mass ratio of the water to the cement is (0.40-0.50):1, and the cement comprises G-grade high-sulfate-resistance oil well cement, micro-cement, a dispersing agent, a fluid loss agent, micro-silicon, fly ash, an expanding agent, latex, water-soluble resin, an early strength agent, retarder and a defoaming agent. The well cementing slurry is excellent in CO2 and H2S corrosion resistance, capable of effectively resisting the corrosion of CO2 and H2S, capable of protecting underground tools such as sleeves to the maximum degree, and especially applicable to the well cementing of a high-CO2 and high-H2S acid oil-gas field.

Description

technical field [0001] The invention belongs to the technical field of preparation of petrochemical products, and relates to a 2 、H 2 Cement slurry formula in the cementing process of sour oil and gas fields such as S. Background technique [0002] With the deepening of exploration and development of oil and gas resources, many 2 、H 2 The oil and gas resources of S have been brought into the focus of development, and there are more and more acid oil and gas fields. The cement sheath is in direct contact with the formation environment, and acts as the first protective barrier for oil and gas wells to seal the formation. in CO 2 、H 2 Under the combined influence of corrosive media such as S and groundwater, the cementing components in the cement stone will decrease continuously, and the permeability will increase, resulting in a decrease in its compressive strength or even no strength at all. If the performance of the cement sheath deteriorates, it will gradually lose i...

Claims

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Application Information

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IPC IPC(8): C04B28/02C09K8/467C09K8/54C04B111/23
CPCC04B28/02C04B2111/00724C04B2111/23C09K8/467C09K8/54C04B2103/408C04B2103/46C04B14/062C04B18/08C04B24/24C04B24/281C04B2103/12C04B2103/22C04B2103/50C04B24/307C04B24/283
Inventor 张颖李俊莉刘彦锋刘世川
Owner SHAANXI RES DESIGN INST OF PETROLEUM CHEM IND
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