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A preparation method of high-strength wear-resistant nano-polyvinyl chloride composite film

A polyvinyl chloride and composite film technology is applied in the field of preparation technology of nano-composite materials, which can solve the problems of poor strength and anti-ultraviolet light aging performance, and achieve the effects of small thermal expansion coefficient, cheap raw materials and good anti-oxidation performance.

Active Publication Date: 2019-07-02
NANJING TECH UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Most of the inflatable toys on the market use polyvinyl chloride resin as the base material, but after long-term use, PVC materials will have problems such as heat resistance, UV aging resistance and strength deterioration

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0022] Add 10 parts of nano-alumina whiskers with an average particle size of 30nm into ethanol and mix evenly, then add 5 parts of silane coupling agent and 1 part of titanate coupling agent, carry out ultrasonic vibration for 0.5h, filter and dry, at 130°C After being activated for 7 hours at low temperature, it was cooled to room temperature to obtain 10 parts of modified nano-alumina whiskers. Dry 100 parts of polyvinyl chloride material in a vacuum oven at 75 °C for 12 hours, then cool to 30 °C, add 5 parts of CaCO 3 Fill and stir well. Add 1 part dibasic lead stearate and 1 part dibutyltin dilaurate heat stabilizer, 5 parts dioctyl phthalate (DOP) and 5 parts di-n-butyl sebacate (DBS) plasticizer , Stir evenly, the stirring temperature is 65°C, and keep warm for 3h. Mix the modified nano-alumina whiskers with PVC, stir evenly, and keep the stirring temperature between 60°C. The final material whose temperature was lowered to 40° C. was put into a twin-screw extruder f...

example 2

[0024] Add 20 parts of nano-alumina whiskers with an average particle size of 35nm into ethanol and mix evenly, then add 4 parts of silane coupling agent, 1 part of titanate coupling agent and 1 part of aluminate coupling agent, and perform ultrasonic vibration for 0.6h , filtered and dried, activated at 140°C for 9h and then cooled to room temperature to obtain modified nano-alumina whiskers. Dry 100 parts of PVC in a vacuum oven at 80°C for 11 hours, then cool to 35°C, add 6 parts of CaCO 3 Fill and stir well. Add 1 part of dibasic lead stearate and 2 parts of calcium stearate heat stabilizer, 5 parts of dibutyl phthalate (DBP) and 6 parts of di-n-butyl sebacate (DBS) plasticizer, Stir evenly, the stirring temperature is 85°C, and keep warm for 4h. Mix 20 parts of nano-alumina whiskers with PVC after modification, stir evenly, and keep the stirring temperature between 70°C. The final material whose temperature was lowered to 45° C. was put into a twin-screw extruder for e...

example 3

[0026] Add 15 parts of nano-alumina whiskers with an average particle size of 40nm into ethanol and mix evenly, then add 3 parts of silane coupling agent, 1 part of titanate coupling agent and 2 parts of aluminate coupling, and carry out ultrasonic vibration for 0.5h. Filter and dry, activate at 150° C. for 7 hours, and then cool to room temperature to obtain modified nano-alumina whiskers. Dry 100 parts of PVC in a vacuum oven at 85°C for 11 hours, then cool to 40°C, add 8 parts of CaCO 3 Fill and stir well. Add 2 parts calcium stearate and 2 parts dibutyltin dilaurate heat stabilizer, 3 parts dibutyl phthalate (DBP), 3 parts dioctyl phthalate and 5 parts di-n-butyl sebacate Ester (DBS) plasticizer, stir evenly, the stirring temperature is 90°C, and keep warm for 2h. Mix 15 parts of nano-alumina whiskers and PVC after modification, stir evenly, and keep the stirring temperature between 85°C. The final material whose temperature was lowered to 45° C. was put into a twin-scr...

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Abstract

The invention relates to a making method of a high-strength wear resistant nanometer polyvinyl chloride composite film. The method comprises the following steps: drying a polyvinyl chloride material in a vacuum oven, adding a calcium carbonate filler, and uniformly stirring the polyvinyl chloride material and the filler; and adding a heat stabilizer and a plasticizer, uniformly stirring all above substances, adding surfactant modified nanometer alumina whiskers after heat insulation ends, uniformly stirring the above obtained mixture and the whiskers, adding the finally obtained material into a double screw extruder, carrying out extrusion granulation, adding obtained granules into a forming machine, and carrying out traction and cutting to finally obtain the composite film. The nanometer alumina whisker / polyvinyl chloride composite film made in the invention can be widely applied to various sizes of inflatable toys, trampolines, water pools, tents and other leisure and entertainment devices to meet people's relentless pursuit of the quality of life.

Description

technical field [0001] The invention belongs to the field of preparation technology of nano-composite materials, and relates to a preparation method of high-strength wear-resistant nano-polyvinyl chloride composite film. Background technique [0002] With the continuous development and progress of society, people's travel, leisure and entertainment methods have become rich and colorful, and water inflatable toys have become more popular. Most of the inflatable toys on the market use polyvinyl chloride resin as the base material, but after long-term use, PVC materials will have problems such as heat resistance, UV aging resistance and strength deterioration. Nano-alumina whiskers have excellent properties such as high hardness, high temperature strength, good oxidation resistance, and small thermal expansion coefficient, so they are widely used as polymer fillers to improve their strength and heat resistance. Nano-alumina whisker / polyvinyl chloride composite film combines th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08K13/06C08K9/06C08K9/04C08K7/08C08K3/26
CPCC08J5/18C08J2327/06C08K3/26C08K7/08C08K9/04C08K9/06C08K13/06C08K2003/265C08K2201/003C08K2201/011C08L2201/08C08L2203/16C08L27/06
Inventor 崔升锁浩林本兰沈晓冬江胜君
Owner NANJING TECH UNIV