A kind of preparation method of current collector for lithium ion battery
A lithium-ion battery, current collector technology, applied in battery electrodes, electrode carriers/current collectors, circuits, etc., can solve the problems of reducing the internal resistance and polarization of the battery, unable to improve the lithium ion transmission speed of the lithium battery, and limited effect, etc. Achieve the effect of improving the transmission characteristics and improving the lithium ion transmission characteristics
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Embodiment 1
[0016] Prepare polyoxometalate lithium salt solution and aniline monomer solution at a molar ratio of 1:4, cover one side of the current collector aluminum foil with insulating tape, connect the other side to the negative pole of the DC power supply, connect the positive pole of the DC power supply to the counter electrode, and connect the The two electrodes are placed in the prepared conductive polymer monomer solution, and the prepared lithium polyoxometalate Li 3 PMo 12 o 40 The solution was slowly added to the aniline solution drop by drop, and at the same time, the DC power switch was turned on, and the power was turned on. The current was 0.5mA, and the voltage range was 1.5V. It was reacted at room temperature for 16 hours, and then the current collector after electroplating was repeatedly washed with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collector in a vacuum drying oven at 40-200°C for 2-10 hours and set i...
Embodiment 2
[0022] Prepare lithium polyoxometalate lithium phosphotungstate Li at a molar ratio of 1:3 3 PW 12 o 40 solution and pyrrole monomer solution, one side of the current collector aluminum foil is covered with insulating tape, the other side is connected to the negative pole of the DC power supply, the positive pole of the DC power supply is connected to the opposite electrode, and the two electrodes are placed in the prepared conductive polymer monomer solution. Replace the prepared lithium polyoxometalate with lithium phosphotungstate Li 3 PW 12 o 40 Slowly add the solution to the pyrrole solution drop by drop, and at the same time turn on the DC power switch, start to energize, the current is 50mA, the voltage range is 5V, react at room temperature for 8-10 hours, and then wash the electroplated current collector repeatedly with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collector in a vacuum drying oven at 40-200°C ...
Embodiment 3
[0025] According to the molar ratio of 1:9, lithium polyoxometalate lithium silicotungstate Li was prepared respectively 4 SiW 12 o 40 solution and pyrrole monomer solution, one side of the current collector aluminum foil is covered with insulating tape, the other side is connected to the negative pole of the DC power supply, the positive pole of the DC power supply is connected to the opposite electrode, and the two electrodes are placed in the prepared conductive polymer monomer solution. Replace the prepared lithium polyoxometalate with lithium silicotungstate Li 4 SiW 12 o 40 The solution is slowly added to the pyrrole solution drop by drop, and at the same time turn on the DC power switch, start to energize, the current is 100mA, the voltage range is 10V, react at room temperature for 8-10 hours, and then wash the electroplated current collector repeatedly with distilled water and alcohol until the filtrate Until it is colorless, put the electroplated current collecto...
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