Leather preparation method and application
A leather and leather-based fabric technology, applied in the chemical industry, can solve the problems of troublesome storage and maintenance, inconsistent color fastness to rubbing, affecting the service life of products, etc., and achieve excellent color fastness to water stains, excellent color fastness to rubbing, The effect of increasing maintenance costs
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[0030] The invention provides a kind of preparation method of leather, comprises the following steps:
[0031] S101: dissolving the graphene in an acid solution, and heating at 110° C. to 130° C. for 3 hours to 5 hours. Wherein, the acid solution is specifically: the solute is sulfuric acid and phosphoric acid, and the mass ratio of sulfuric acid and phosphoric acid is 1: (0.5-0.8), and the mass ratio of solute and solvent is (3-5): 100; The mass ratio is (1-3):10.
[0032] S102: Add polyethylacrylate and tourmaline powder to the product obtained in S101, and then stir at 85° C. to 90° C. for 100 min to 300 min, and adjust the pH value of the product to 5.8 to 6.3.
[0033] S103: Add polyurethane resin and polyvinyl alcohol to the product obtained in S102 and stir evenly. Among them, the polyurethane resin is prepared from polyether polyol and isocyanate; the molar ratio of polyether polyol to isocyanate is (1.2-2): 1; polyether polyol includes polytetrahydrofuran ether glyc...
Embodiment 1
[0040] The invention provides a kind of preparation method of leather, comprises the following steps:
[0041] S101: dissolving the graphene in an acid solution, and heating at 110° C. for 5 hours. Among them, the acid solution is specifically: the solute is sulfuric acid and phosphoric acid, and the mass ratio of sulfuric acid and phosphoric acid is 1:0.8, the mass ratio of solute to solvent is 3:100; the mass ratio of graphene to acid solution is 2:10.
[0042] S102: Add polyethylacrylate with a number average molecular weight of 20,000 and tourmaline powder to the product obtained in S101, and then stir at 90° C. for 100 min to adjust the pH value of the product to 6.3.
[0043] S103: Add polyurethane resin and polyvinyl alcohol to the product obtained in S102 and stir for 3 hours at a temperature of 65° C. and a rotational speed of 3500 rpm. Among them, the polyurethane resin is prepared from polytetrahydrofuran ether diol and 2,4,4-trimethylhexamethylene diisocyanate wit...
Embodiment 2
[0046] The invention provides a kind of preparation method of leather, comprises the following steps:
[0047] S101: dissolving the graphene in an acid solution, and heating at 130° C. for 3 hours. Among them, the acid solution is specifically: the solute is sulfuric acid and phosphoric acid, and the mass ratio of sulfuric acid and phosphoric acid is 1:0.5, the mass ratio of solute to solvent is 5:100; the mass ratio of graphene to acid solution is 1:10.
[0048] S102: Add polyethylacrylate with a number average molecular weight of 8000 and tourmaline powder to the product obtained in S101, and then stir at 85° C. for 300 min to adjust the pH of the product to 5.8.
[0049] S103: Add polyurethane resin and polyvinyl alcohol to the product obtained in S102 and stir for 6 hours at a temperature of 75° C. and a rotation speed of 2500 rpm. Among them, the polyurethane resin is prepared from polytetrahydrofuran ether diol and 2,4,4-trimethylhexamethylene diisocyanate with a molar ...
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