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Geopolymer coating material for marine concrete protection

A polymer coating, marine concrete technology, applied in cement production and other directions, can solve the problem of insufficient mitigation effect, and achieve the effects of eliminating air bubbles, improving rheological properties, and enhancing anti-drying shrinkage cracking performance.

Active Publication Date: 2019-10-01
TAIZHOU BRANCH ZHEJIANG-CALIFORNIA INT NANOSYSTEMS INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the easy shrinkage and cracking of geopolymers in the process of setting and hardening can be alleviated by MgO-based expansion agents and PP fibers, but in practical applications, this mitigation effect is not enough

Method used

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  • Geopolymer coating material for marine concrete protection
  • Geopolymer coating material for marine concrete protection
  • Geopolymer coating material for marine concrete protection

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] A geopolymer coating material for marine concrete protection comprises the following components by weight fraction: 50 parts of slag (particle size ≤ 325 mesh), 50 parts of fly ash (particle size ≤ 325 mesh), 10 parts of NaOH, natural sand Sand (particle size ≤ 2.36mm, mud content less than 0.5%) 50 parts, ethylene / vinyl acetate copolymer 5 parts, PP fiber (length ≤ 10mm) 0.2 parts, CaO-based expansion agent 3 parts, polycarboxylic acid system 0.5 parts of water reducer, 0.5 parts of sodium bentonite, 0.5 parts of isobutyltriethoxysilane, 0.2 parts of octanol, and 50 parts of water.

[0029] The preparation method is as follows: 1) Add slag, fly ash, CaO-based expansion agent and PP fiber into the high-speed mixer, and stir for 5 minutes (rotation speed 1000rpm) to disperse the fibers evenly; 2) Add water, NaOH, polycarboxylate into the high-speed mixer Acid-based water reducer and sodium bentonite, stirring (speed 600rpm), after the alkali activator, water reducer is d...

Embodiment 2

[0032] A geopolymer coating material for marine concrete protection comprises the following components by weight fraction: 80 parts of slag (particle size≤325 mesh), 20 parts of metakaolin (particle size≤325 mesh), Na 2 O 1.2SiO 2 15 parts, 80 parts of artificial sand (particle size ≤ 2.36mm, mud content less than 0.5%), 8 parts of vinyl acetate / ethylene tertiary carbonic acid copolymer, 0.5 parts of PVA fiber (length ≤ 10mm), 5 parts of MgO-based expansion agent , 2 parts of polycarboxylic acid-based water reducer, 1 part of lithium bentonite, 1 part of isooctyltriethoxysilane, 0.5 parts of octanol, and 30 parts of water.

[0033] The preparation method is as follows: 1) Add slag, metakaolin, MgO-based expansion agent and PVA fiber into a high-speed mixer, and stir for 10 minutes (rotating speed 600rpm) to disperse the fibers evenly; 2) Add water, Na 2 O 1.2SiO 2 , polycarboxylate water-reducer and lithium-based bentonite, stirring (rotating speed 1000rpm), after the alkal...

Embodiment 3

[0036] A geopolymer coating material for marine concrete protection includes the following components by weight fraction: 75 parts of slag (particle size ≤ 325 mesh), 20 parts of metakaolin (particle size ≤ 325 mesh), silicon powder (particle size ≤ 325 mesh) mesh) 5 parts, KOH 15 parts, artificial sand (particle size ≤ 2.36mm, mud content less than 0.5%) 100 parts, polyurethane emulsion 20 parts, PVA fiber (length ≤ 10mm) 0.3 parts, calcium sulfoaluminate base 4 parts of expansion agent, 2 parts of polycarboxylate water reducer, 0.8 part of sodium bentonite, 0.8 part of isooctyltriethoxysilane, 0.3 part of octanol, 40 parts of water.

[0037] The preparation method is as follows: 1) Add slag, metakaolin, silicon powder, calcium sulfoaluminate-based expansion agent and PVA fiber into the high-speed mixer, and stir for 8 minutes (800 rpm) to disperse the fibers evenly; 2) Add to the high-speed mixer Water, KOH, polycarboxylate water reducer and sodium bentonite, stirring (speed...

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Abstract

The invention relates to the technical field of concrete anticorrosion and aims at providing a geopolymer coating material for marine concrete protection. The coating material is prepared from the following raw material ingredients in parts by weight: 100 parts of aluminum silicate material, 10 to 20 parts of alkali activator, 50 to 200 parts of fine aggregate, 5 to 20 parts of water-soluble polymer, 0.2 to 0.5 part of fiber material, 3 to 5 parts of expanding agent, 0.5 to 2 parts of water reducing agent, 0.5 to 1 part of suspending agent, 0.5 to 1 part of coupling agent, 0.2 to 0.5 part of defoaming agent and 30 to 50 parts of water. The geopolymer coating material disclosed by the invention uses multiple safeguard measures, so that a shrinkage and crack performance of the polymer coating material is synergetically enhanced; the geopolymer coating material is compounded with an organic functional material, so that a dewatering function and an iontophoresis resistance function are enhanced; by means of optimizing a functional additive, a rheological property of the geopolymer coating material is improved, bubbles in slurry in a preparation process are eliminated, and a construction performance of the geopolymer coating material is enhanced.

Description

technical field [0001] The invention relates to the technical field of marine high-performance concrete anticorrosion, in particular to a geopolymer coating material for marine concrete protection. Background technique [0002] my country is a big ocean country, and it is an important strategic decision to develop marine resources and develop marine economy. Marine engineering construction is an important prerequisite and basic guarantee for comprehensive marine development. However, due to the particularity of the marine environment (strong radiation, high salinity, high humidity, etc.), it will cause corrosion and damage of metal materials, cracking and expansion of reinforced concrete structures, and polymer materials. Deformation and deterioration etc. As an important material in marine engineering, concrete has high requirements for its durability. Conventional marine high-performance concrete has certain effects on inhibiting the deterioration and failure of material...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B28/00C04B111/24
CPCC04B28/006C04B2111/00482C04B2111/24C04B22/062C04B14/06C04B24/26C04B16/0633C04B22/064C04B14/104C04B2103/302C04B24/42C04B24/026C04B16/0641C04B22/066C04B24/282C04B22/14Y02P40/10
Inventor 汪海风林洲吴春春盛建松杨辉方竹根
Owner TAIZHOU BRANCH ZHEJIANG-CALIFORNIA INT NANOSYSTEMS INST