Preparation method for ring crush reinforcing agent of corrugated paper
A technology of ring pressure strengthening and corrugated paper, which is applied in the direction of strengthening agent addition, paper, papermaking, etc., can solve the problems of residual ring pressure strengthening agent, low ring pressure strength, and can not be reused, so as to improve degradability and increase the surface Adhesion, the effect of increasing the degree of bonding
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[0017] The preparation method of corrugated paper ring pressure reinforcing agent of the present invention comprises the following steps:
[0018] (1) In parts by weight, take 60-65 parts of 1.9mol / L ethanol solution, 40-45 parts of N,N-dimethylformamide, 37-43 parts of polyglutamic acid, 12-14 parts of methyl Acryloyl chloride, 7 to 9 parts of dicyclohexylcarbodiimide and 3 to 6 parts of triethanolamine are placed in a reactor and reacted at -6 to 0°C for 5 to 8 hours;
[0019] (2) After the reaction, use ammonia water to adjust the pH to 8.0-8.5, let it stand for 1-3 hours, then add petroleum ether with 1-2 times the mass of polyglutamic acid and stir evenly, continue to stand for 60-80 minutes, and collect the reaction mixture , filter, collect the filter residue, wash the filter residue with absolute ethanol with 4 to 6 times the quality of the filter residue, air-dry the washed filter residue, and collect the air-dried matter;
[0020] (3) According to the mass ratio of ...
example 1
[0023] The preparation method of corrugated paper ring pressure reinforcing agent of the present invention comprises the following steps:
[0024] (1) In parts by weight, take 60 parts of 1.9mol / L ethanol solution, 40 parts of N,N-dimethylformamide, 37 parts of polyglutamic acid, 12 parts of methacryloyl chloride, 7 parts of dicyclohexyl Put carbodiimide and 3 parts of triethanolamine into the reactor, and react at -6°C for 5 hours;
[0025] (2) After the reaction, use ammonia water to adjust the pH to 8.0, let it stand for 1 hour, then add petroleum ether with 1 times the mass of polyglutamic acid and stir evenly, continue to stand for 60 minutes, collect the reaction mixture, filter, collect the filter residue, and use the filter residue Wash the filter residue with 4 times the quality of absolute ethanol, air-dry the washed filter residue, and collect the air-dried matter;
[0026] (3) According to the mass ratio of 7:2:1:1:15, put the air-dried material, methacrylamide, d...
example 2
[0029] The preparation method of corrugated paper ring pressure reinforcing agent of the present invention comprises the following steps:
[0030] (1) In parts by weight, take 63 parts of 1.9mol / L ethanol solution, 43 parts of N,N-dimethylformamide, 40 parts of polyglutamic acid, 13 parts of methacryloyl chloride, 8 parts of dicyclohexyl Put carbodiimide and 5 parts of triethanolamine into the reactor, and react at -3°C for 7 hours;
[0031] (2) After the reaction, use ammonia water to adjust the pH to 8.3, let it stand for 2 hours, then add petroleum ether with 1 times the mass of polyglutamic acid and stir evenly, continue to stand for 70 minutes, collect the reaction mixture, filter, collect the filter residue, and use the filter residue Wash the filter residue with 5 times the quality of absolute ethanol, air-dry the washed filter residue, and collect the air-dried matter;
[0032] (3) According to the mass ratio of 8:2:2:1:18, put the air-dried material, methacrylamide, ...
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