Modified transformer oil, preparation method and application

A transformer oil and modification technology, applied in the petroleum industry, lubricating composition and other directions, can solve the problems of low viscosity of transformer oil, low thermal conductivity, limited local electric field distortion, etc., to improve thermal conductivity, improve breakdown resistance, The effect of high thermal conductivity

Active Publication Date: 2018-02-27
INST OF PROCESS ENG CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

CN105132079A discloses a preparation method of aluminum nitride nanoparticle modified transformer oil, but does not report the effect of improving the performance of transformer oil after modification
CN105296108A discloses a mixed modified nano-particle transformer oil and its preparation method, using modified nano-silicon dioxide and boron nitride composite nanoparticles in the transformer oil, using ultrasonic dispersion and mechanical stirring as the main treatment process, but not The improvement effect of composite nanoparticles on transformer oil has not been reported
However, due to the isotropic characteristics of zero-dimensional nano-insulation particles, the distortion effect on the local electric field is limited, so the improvement of the anti-breakdown performance of transformer oil is limited; on the other hand, due to the low thermal conductivity of zero-dimensional nano-insulation particles, it is necessary to The thermal conductivity of transformer oil can be improved only with a large amount of addition, but the viscosity of transformer oil is low, and the stability of the high-solid content system is poor, so it is difficult to obtain stable nano-transformer oil products
Therefore, zero-dimensional nano-insulating particles have limited effect on improving the insulation and thermal conductivity of transformer oil.

Method used

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  • Modified transformer oil, preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~3

[0096] A preparation method for graphene derivative lamellar modified transformer oil, comprising the steps of:

[0097] (1) Use graphite paper as the positive and negative poles of the electrochemical reaction, use 0.5mol / L dodecylbenzyl ammonium bromide solution as the electrolyte, pass through a direct current of 0.7A, and conduct electrolysis on the graphite material at 30°C Chemical peeling; the electrochemical peeling product is filtered, the filter cake is dispersed with acetone, the upper suspension is taken to filter, and dried to obtain graphene derivative sheets; the graphene derivative sheets are observed by scanning electron microscopy (such as figure 1 ), found that the sheet diameter of its two-dimensional nanosheets was between 200nm and 350nm; the graphene derivative sheets were subjected to Raman scanning (such as figure 2 ), found that its thickness is about 10nm;

[0098] (2) Mix the graphene derivative sheets and oleic acid amide obtained in step (1) wit...

Embodiment 4

[0104] The difference from Example 2 is that the base oil used is 10# transformer oil.

Embodiment 5

[0106] The difference from Example 2 is that the base oil used is 45# transformer oil.

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Abstract

The invention relates to modified transformer oil. The modified transformer oil consists of base oil and heat-conducting two-dimensional nanosheets dispersed in the base oil; the thickness of the heat-conducting two-dimensional nanosheets is less than 30nm, the sheet diameter is less than 500nm, and the ratio of thickness to radial dimension is less than 1. Since the invention adds the two-dimensional nanosheets in the base oil of the transformer oil, the two-dimensional structures are utilized to form electron traps in the transformer oil, the anisotropy of electron transfer can enhance the distortion of a local electric field in the transformer oil, thus impeding the development of streams and playing an insulating role, and thereby the anti-breakdown property of the transformer oil is effectively increased; the two-dimensional nanosheets added by the invention can form a nanofluid system along with the transformer oil, the heat conductivity coefficient is high, and the heat dispersion of the transformer oil is increased.

Description

technical field [0001] The invention belongs to the field of transformer oil modification, and in particular relates to a modified transformer oil, a preparation method and an application. Background technique [0002] In order to enhance the insulation performance and heat dissipation performance of the transformer, most of its iron core and winding are immersed in an oil tank filled with transformer oil, which is called an oil-immersed transformer. [0003] Transformer oil is the most important special lubricating oil among electrical insulating oils. Its demand accounts for more than 98% of the total demand for electrical insulating oil. It is mainly used as the insulation and heat conduction medium of transformers, and plays the role of insulation protection, heat dissipation and cooling, and arc extinguishing. role. The quality and performance of transformer oil are related to the safe operation of the power grid, and are closely related to industrial production and re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10M169/04C10N40/16
CPCC10M169/04C10M2201/041C10M2201/061C10M2201/066C10M2207/026C10M2215/065C10M2215/08C10N2040/16
Inventor 王钰赵栋
Owner INST OF PROCESS ENG CHINESE ACAD OF SCI
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