Nanometer self-cleaning outer-wall latex paint and preparing method thereof
A nano self-cleaning, latex paint technology, applied in the field of coatings, can solve the problems of poor water resistance, difficult to clean, easy to crack, etc., and achieves the effects of good weather resistance, good adhesion, and reduced surface tension.
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Embodiment 1
[0046] A preparation method of nano titanium dioxide, comprising the following steps:
[0047] (1) Synthesis of star macromolecular initiator 21Br-β-CD:
[0048] Take 6.82g of β-cyclodextrin, dry it at 80°C for 12h under vacuum, then dissolve it in 60mL of N-methylpyrrolidone at room temperature, put it in an ice-water bath, and cool it to 0°C. Under this condition, Add 58g of 2-bromoisobutyryl bromide dropwise within 2h. After the dropwise addition, warm up to room temperature and continue to react for 24h to obtain a brown solution. Concentrate by distillation under reduced pressure, add 100mL of dichloromethane to dilute, and wash with 100mL of saturated aqueous sodium bicarbonate solution and 100 mL of deionized water were washed three times each, and the obtained organic phase was dried with anhydrous magnesium sulfate, then concentrated with a rotary evaporator, and finally precipitated in n-hexane below -20°C to obtain a white precipitate, which was dried in a vacuum ov...
Embodiment 2
[0072] A nano self-cleaning latex paint for exterior walls, comprising the following raw materials in parts by weight: 150 parts of water, 30 parts of propylene glycol, 1 part of wetting agent, 6 parts of dispersing agent, 2 parts of defoaming agent, 2 parts of preservative, film-forming 20 parts of additives, 10 parts of nano titanium dioxide, 230 parts of titanium dioxide, 100 parts of heavy calcium carbonate, 50 parts of wollastonite powder, 50 parts of kaolin, 320 parts of pure acrylic emulsion, 100 parts of silicone modified acrylic emulsion, multifunctional auxiliary 2 parts of agent, 2 parts of thickener, 1 part of leveling agent.
[0073] Described wetting agent is PE-100 wetting agent; Described dispersant is 5040 dispersant; Described defoamer is NXZ defoamer; Described preservative is LXE preservative; The film aid is alcohol ester twelve film-forming aid; the thickener is HASE thickener H-609; the leveling agent is polyurethane leveling agent RM-2020; the multifunc...
Embodiment 3
[0080] A nano self-cleaning latex paint for exterior walls, comprising the following raw materials in parts by weight: 140 parts of water, 10 parts of propylene glycol, 0.5 parts of wetting agent, 3 parts of dispersant, 1 part of defoaming agent, 1 part of preservative, film-forming 10 parts of additives, 30 parts of nano titanium dioxide, 180 parts of titanium dioxide, 80 parts of heavy calcium carbonate, 40 parts of wollastonite powder, 40 parts of kaolin, 280 parts of pure acrylic emulsion, 80 parts of silicone modified acrylic emulsion, multifunctional auxiliary 2 parts of agent, 3 parts of thickener, 2 parts of leveling agent.
[0081] Described wetting agent is PE-100 wetting agent; Described dispersant is 5040 dispersant; Described defoamer is NXZ defoamer; Described preservative is LXE preservative; The film aid is alcohol ester twelve film-forming aid; the thickener is HASE thickener H-609; the leveling agent is polyurethane leveling agent RM-2020; the multifunctional...
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