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Preparation method of lithium type low-silicon molecular sieve loading filler

A silicon molecular sieve and slurry technology, applied in the chemical field, can solve the problems of difficult processing and molding, large pressure drop, high energy consumption, etc.

Inactive Publication Date: 2018-05-01
SUZHOU SMART ADVANCED COATING TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The existing packing structure design technology mainly follows the idea of ​​spherical adsorbent molecular sieves, mainly by making lithium-type low-silicon molecular sieves into spherical packings. The reduction in the diameter of spherical packings will help increase the specific surface area and bulk density. Type low-silicon molecular sieve spherical packing with a diameter of 1-2mm. However, the structural design method to reduce the diameter of the spherical packing is close to the limit. If the diameter of the spherical packing is too small, it will not only make it difficult to process and form, but the dense packing caused by the small particle size of the packing will also cause air pressure. The drop is too large, resulting in high energy consumption

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Example 1 Carrier-loaded lithium-type low-silicon molecular sieve to prepare packing

[0034] First disperse the powdered lithium-type low-silicon molecular sieve into toluene, the amount of organic solvent per gram of molecular sieve is 50mL, add siloxane KH560, the amount of silane coupling agent per gram of molecular sieve is 2, mL, the reaction time is 12h, centrifuge, and wash with solvent , After separation, vacuum-dry at 40-120°C for 12h.

[0035] After surface treatment, the lithium-type low-silicon molecular sieve is dispersed in water, and silica sol is added. The silica sol accounts for 20% of the total solids, and the total solid content is 40%. Then, 3% glycerin is added to form a relatively stable slurry-like dispersion system; take 100 For honeycomb ceramics, immerse in the above slurry dispersion system for 1-30min, take it out and dry it at 80°C, repeat the immersion-drying process until the loading capacity reaches 40%; after loading, the carrier is he...

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PUM

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Abstract

The invention requires protecting a preparation method of lithium type low-silicon molecular sieve loading filler. The preparation method comprises the following steps: a surface treatment step of a lithium type low-silicon molecular sieve, a slurry preparation step and a loading filler molding step. A design thought of a novel loading filler structure is mainly aiming at improving space occupation and reduces energy consumption of a pressure swing adsorption oxygen preparation technology; the novel loading filler ensures that the air treatment amount of each kilogram of the molecular sieve isnot lower than 100L / min, the oxygen output amount of each kilogram of the molecular sieve is not lower than 10L / min and the power consumption amount per unit is not higher than 0.5Kwh / Nm<3>.

Description

technical field [0001] The invention belongs to the field of chemical technology, and in particular relates to the preparation technology of lithium-type low-silicon molecular sieve loaded filler, especially the molecular sieve coating technology and processing molding technology. Background technique [0002] Pressure swing adsorption separation technology (PSA) is a new gas separation technology that has emerged in the separation industry in recent years. The pressure conversion process realizes the separation or purification of gas. Adsorbent is the basis of pressure swing adsorption separation technology (PSA), and the performance of the adsorbent directly affects the final separation effect, and even affects the complexity of the process steps and the service life of the adsorption operation unit. With the popularization of the application of PSA technology, the demand for excellent molecular sieve adsorbents with high nitrogen adsorption capacity and large nitrogen-ox...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/18B01J20/28B01J20/32B01D53/047C01B13/02
CPCB01D53/047B01D2256/12B01J20/046B01J20/186B01J20/2803B01J20/3234B01J20/3246C01B13/0274Y02C20/40Y02P20/151
Inventor 钱中宇龚强
Owner SUZHOU SMART ADVANCED COATING TECH CO LTD