The invention relates to a preparation method for a hyperbranched polymide film with the low
dielectric constant. A series of the low-
dielectric constant PI films with a hyperbranched structure are synthesized by taking 2,4,6-triaminopyrimidine (TAP) as a branching center through a one-
step method. Through introduction of the hyperbranched structure, the
dielectric constant of the PI film is significantly lowered, the inherent advantages of PI are better kept, and the good
mechanical strength and thermo-oxidative stability are supplied to the film. The hyperbranched structure contains a large quantity of molecular chain end groups,
dense packing of molecular chains is effectively inhibited, and therefore the hyperbranched PI film has the excellent
dissolution characteristic to be more prone to be processed into a complex device. Compared with a
Kapton standard film which is generally used at present, under the same testing conditions, the dielectric constant of the hyperbranched PI film prepared through the method is lowered by 20%-40%, the lowest dielectric constant even gets close to 2.0 and reaches the ultralow dielectric constant level, and the urgent demand for micro-
electronic industry development in future can be met.