A core-shell structure nano-metal interconnection process
A core-shell structure and nano-metal technology, applied in metal processing equipment, nanotechnology, nanotechnology, etc., can solve problems such as large energy environment, high interconnection temperature, and device damage, and achieve lower interconnection temperature and interconnection conditions, compact morphology, and the effect of improving oxidation resistance and stability
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[0035] The preparation method of the nanoparticle interconnection material of the core-shell structure provided by the present invention comprises:
[0036] a) mixing the nano-copper particles with a protective agent to obtain a nano-copper solution;
[0037] b) mixing the shell precursor and the nano-copper solution, reacting, centrifuging and washing to obtain core-shell bimetallic nanoparticles;
[0038] c) Dispersing the core-shell bimetallic nanoparticles in a solvent and performing defoaming treatment to obtain a nanoparticle interconnection material with a core-shell structure.
[0039] The preparation method of the nano-particle interconnection material with a core-shell structure provided by the present invention firstly mixes the nano-copper particles and the protective agent to obtain a nano-copper solution. Preferably specifically:
[0040] Disperse the nano-copper particles and the protective agent in a solvent, and stir magnetically at room temperature to form a ...
Embodiment 1
[0077] Add nano-copper particles with a size of 20nm and protective agent polyacrylamide in ethylene glycol solvent, wherein the molar ratio of protective agent to nano-copper particles is 2:1; magnetically stir at room temperature for 30min to form uniformly dispersed nano-copper solution; chloroauric acid is added in the nano-copper solution, wherein the molar ratio of chloroauric acid to nano-copper particles is 0.01:1, the mixed solution is stirred and reacted at room temperature for 90min, and deionized water and Centrifuge and wash with absolute ethanol 4 times each to obtain bimetallic core-shell nanoparticles; disperse the core-shell nanoparticles in a solvent of diethylene glycol and ethylene glycol butyl ether, and go through 2000r / min vacuum defoaming and mixing treatment After 5 minutes, the core-shell nanoparticle interconnection material was obtained, and the mass ratio of the core-shell nanoparticle powder to the interconnection material was 60%.
[0078] Print ...
Embodiment 2
[0080] Add nano-copper particles with a size of 300nm and protective agent polyvinylpyrrolidone into glycerol solvent, wherein the molar ratio of protective agent to nano-copper particles is 5:1; magnetically stir at room temperature for 30min to form uniformly dispersed nano-copper solution; palladium acetate is added to the nano-copper solution, wherein the molar ratio of palladium acetate to nano-copper particles is 0.005:1, the mixed solution is stirred and reacted for 120 min at room temperature, and deionized water and anhydrous Each was centrifuged and washed 4 times with ethanol to obtain bimetallic core-shell structure nanoparticles. The core-shell nanoparticles are dispersed in the solvent of ethylene glycol and ethylene glycol methyl ether, and after 3000r / min vacuum defoaming and mixing for 5 minutes, the core-shell nanoparticle interconnection material is obtained, and the core-shell nanoparticle powder accounts for the interconnection material. The mass ratio is ...
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