A core-shell structure nano-metal interconnection process

A core-shell structure and nano-metal technology, applied in metal processing equipment, nanotechnology, nanotechnology, etc., can solve problems such as large energy environment, high interconnection temperature, and device damage, and achieve lower interconnection temperature and interconnection conditions, compact morphology, and the effect of improving oxidation resistance and stability

Active Publication Date: 2019-08-16
GUANGDONG UNIV OF TECH
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

On the one hand, the high interconnection temperature will pose severe challenges to the heat resistance of interconnection equipment, electronic components and substrate materials. For some electronic devices with poor heat resistance, it is easy to cause device damage at high interconnection temperatures; and, for Some special electronic products such as solar film, LED, LCD, temperature control components, etc. must be interconnected at low temperature; on the other hand, high interconnection temperature is not conducive to energy saving and emission reduction, and the interconnection and packaging of electronic components is the main industry, high-temperature interconnection is bound to cause considerable problems to the energy environment

Method used

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  • A core-shell structure nano-metal interconnection process

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preparation example Construction

[0035] The preparation method of the nanoparticle interconnection material of the core-shell structure provided by the present invention comprises:

[0036] a) mixing the nano-copper particles with a protective agent to obtain a nano-copper solution;

[0037] b) mixing the shell precursor and the nano-copper solution, reacting, centrifuging and washing to obtain core-shell bimetallic nanoparticles;

[0038] c) Dispersing the core-shell bimetallic nanoparticles in a solvent and performing defoaming treatment to obtain a nanoparticle interconnection material with a core-shell structure.

[0039] The preparation method of the nano-particle interconnection material with a core-shell structure provided by the present invention firstly mixes the nano-copper particles and the protective agent to obtain a nano-copper solution. Preferably specifically:

[0040] Disperse the nano-copper particles and the protective agent in a solvent, and stir magnetically at room temperature to form a ...

Embodiment 1

[0077] Add nano-copper particles with a size of 20nm and protective agent polyacrylamide in ethylene glycol solvent, wherein the molar ratio of protective agent to nano-copper particles is 2:1; magnetically stir at room temperature for 30min to form uniformly dispersed nano-copper solution; chloroauric acid is added in the nano-copper solution, wherein the molar ratio of chloroauric acid to nano-copper particles is 0.01:1, the mixed solution is stirred and reacted at room temperature for 90min, and deionized water and Centrifuge and wash with absolute ethanol 4 times each to obtain bimetallic core-shell nanoparticles; disperse the core-shell nanoparticles in a solvent of diethylene glycol and ethylene glycol butyl ether, and go through 2000r / min vacuum defoaming and mixing treatment After 5 minutes, the core-shell nanoparticle interconnection material was obtained, and the mass ratio of the core-shell nanoparticle powder to the interconnection material was 60%.

[0078] Print ...

Embodiment 2

[0080] Add nano-copper particles with a size of 300nm and protective agent polyvinylpyrrolidone into glycerol solvent, wherein the molar ratio of protective agent to nano-copper particles is 5:1; magnetically stir at room temperature for 30min to form uniformly dispersed nano-copper solution; palladium acetate is added to the nano-copper solution, wherein the molar ratio of palladium acetate to nano-copper particles is 0.005:1, the mixed solution is stirred and reacted for 120 min at room temperature, and deionized water and anhydrous Each was centrifuged and washed 4 times with ethanol to obtain bimetallic core-shell structure nanoparticles. The core-shell nanoparticles are dispersed in the solvent of ethylene glycol and ethylene glycol methyl ether, and after 3000r / min vacuum defoaming and mixing for 5 minutes, the core-shell nanoparticle interconnection material is obtained, and the core-shell nanoparticle powder accounts for the interconnection material. The mass ratio is ...

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Abstract

The invention provides a nano-metal interconnection process with a core-shell structure, comprising: A) printing a nano-particle interconnection material with a core-shell structure on a substrate; the nano-particle interconnection material with a core-shell structure includes a metal shell layer Covered nano copper particles; the metal is selected from one or more of gold, silver, tin, platinum and palladium; B) the chip is covered on the surface of the nano particle interconnection material to obtain a whole device; C) the The monolithic device is sintered to obtain an interconnected device. In the metal-shell-coated nano-copper particles of the present invention, the shell metal has a dense shape, uniform and controllable size, and is easy to undergo atomic diffusion at a relatively low temperature, and is connected with the core-layer nano-copper particles to form a three-dimensional interconnection system. , not only improves the oxidation resistance and stability of nano-copper, but also greatly reduces the interconnection temperature and interconnection conditions. This process can interconnect chips and substrates under low temperature and pressure-free conditions to complete the connection and packaging of electronic devices.

Description

technical field [0001] The invention relates to the technical field of electronic packaging, in particular to a core-shell structure nano-metal interconnection process. Background technique [0002] Electronic packaging technology is an extension of electronic manufacturing technology. The speed of its development and the technical level and production scale it has achieved directly affect the development of complete machine products or electronic systems. The development power of electronic packaging technology comes from the upgrading of electronic products. One generation of products creates a new generation of technology. With the development trend of light, thin, short and small electronic products and the continuous updating of microelectronics technology, electronic packaging technology is The characteristics of high performance are gradually entering a period of ultra-high-speed development, which also puts forward higher requirements for the interconnection process:...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B22F1/02H01L23/532B82Y30/00B82Y40/00
CPCH01L23/53228B82Y30/00B82Y40/00B22F1/17
Inventor 张昱崔成强陈新
Owner GUANGDONG UNIV OF TECH
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