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Nano metal powder-enhanced silicon carbide/graphite composite ceramic coating layer and preparation method thereof

A technology of nano-metal powder and composite ceramics, which is applied in the field of ceramics, can solve problems such as limited application and promotion, easy cracks, service life, and high material brittleness, and achieves the effect of simple spraying process

Inactive Publication Date: 2018-07-24
四川共拓新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, since silicon carbide is a stable compound with strong covalent bonds, it is difficult to achieve material densification under high-temperature sintering environment, which makes the material appear brittle, prone to cracks and short service life, which limits further development. app promotion for

Method used

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  • Nano metal powder-enhanced silicon carbide/graphite composite ceramic coating layer and preparation method thereof
  • Nano metal powder-enhanced silicon carbide/graphite composite ceramic coating layer and preparation method thereof
  • Nano metal powder-enhanced silicon carbide/graphite composite ceramic coating layer and preparation method thereof

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Effect test

Embodiment 1

[0021] Nano metal powder reinforced silicon carbide / graphite composite ceramic coating, which includes 100 parts of silicon carbide micropowder, 3 parts of nano-tungsten powder, 3 parts of ultra-fine graphite powder, 6 parts of sodium carboxymethyl cellulose and 3-aminopropyl trioxide 2 parts of ethoxysilane.

[0022] The preparation steps are as follows: the silicon carbide micropowder, nano-tungsten powder, ultrafine graphite powder and sodium carboxymethyl cellulose are ground and mixed uniformly in a mortar in a proportion of 100:3:3:6 by weight; Deionized water and 2% dispersant were wet ball milled in a planetary ball mill at a speed of 1500 r / min for 18 hours to obtain a homogeneous suspension; after drying and pulverizing the above suspension, sieved with an 80-mesh sieve to obtain Mixing powders; melting the above-mentioned powders at a high temperature of 1500°C for 1.0h to form a molten particle flow, which is sprayed on the surface of the metal substrate at a speed...

Embodiment 2

[0026] Silicon carbide / graphite composite ceramic coating reinforced by nano metal powder, the parts by weight of each component are: 100 parts of silicon carbide micropowder, 2 parts of nano iron powder, 3 parts of ultrafine graphite powder, 8 parts of potassium water glass and octadecane 3 parts of trimethylammonium chloride.

[0027] The preparation steps are as follows: the silicon carbide micropowder, nano iron powder, ultrafine graphite powder and potassium water glass are ground and mixed uniformly in a mortar according to the ratio of 100:2:3:8 by weight; 120% deionized water is added and 3% dispersant, in a planetary ball mill, perform wet ball milling at 1800r / min for 20h to obtain a homogeneous suspension; after drying and pulverizing the above suspension, sieve with a 200-mesh sieve to obtain a mixed powder ; Melt the above powder at a high temperature of 1500°C for 1.5h to form a molten particle flow, spray it on the surface of the metal substrate at a speed of 12...

Embodiment 3

[0031] Nano metal powder reinforced silicon carbide / graphite composite ceramic coating, which includes 100 parts of silicon carbide micropowder, 3 parts of nano aluminum powder, 3 parts of ultrafine graphite powder, 6 parts of hydroxyethyl cellulose and 3 parts of polyethylene glycol.

[0032] The preparation steps are as follows: silicon carbide micro-powder, nano-aluminum powder, ultra-fine graphite powder and hydroxyethyl cellulose are ground and mixed uniformly in a mortar according to the ratio of 100:3:3:6 by weight; Ionized water and 3% dispersant were wet ball milled in a planetary ball mill at a speed of 1500 r / min for 16 hours to obtain a homogeneous suspension; after drying and pulverizing the above suspension, sieved with a 100-mesh sieve to obtain a mixed solution Powder; the above powder is melted at a high temperature of 1600°C for 2.0h to form a molten particle flow, which is sprayed on the surface of the metal substrate at a speed of 1800m / s to obtain a silicon...

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Abstract

The invention discloses a nano metal powder-enhanced silicon carbide / graphite composite ceramic coating layer, which is prepared from 100 parts of silicon carbide micro powder, 2 to 8 parts of nano metal powder, 2 to 8 parts of ultrafine graphite powder, 5 to 10 parts of an adhesive and 1 to 3 parts of a dispersant. The invention further discloses a preparation method. The preparation method comprises the following steps: S1, grinding and mixing; S2, wet grinding; S3, combining powder; S4, preparation of the coating layer. The nano metal powder-enhanced silicon carbide / graphite composite ceramic coating layer has the beneficial effects of environmental friendliness and a simple spraying process. The obtained composite ceramic coating layer has advantages of high-temperature resistance, wear resistance, corrosion resistance and the like of a ceramic material, and has intensity and toughness of a metal material.

Description

technical field [0001] The invention relates to the technical field of ceramics, in particular to a nanometer metal powder reinforced silicon carbide / graphite composite ceramic coating and a preparation method thereof. Background technique [0002] Silicon carbide ceramic coating has the advantages of high temperature resistance, chemical corrosion resistance, high thermal conductivity, low thermal expansion coefficient, dielectric and wave transmission. It has been widely used in aerospace, national defense, petroleum, chemical, machinery, metallurgy, transportation and Electricity and many other fields. Since the 1990s, the application of silicon carbide ceramic coatings has been continuously and rapidly developed. In developed countries in Europe and the United States, the annual growth rate has been maintained at more than 12%, and the annual growth rate of applications in some fields (such as aero-engine silicon carbide thermal barrier coating) is as high as 20%. [0...

Claims

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Application Information

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IPC IPC(8): C04B41/87
CPCC04B41/5133C04B41/5144C04B41/87C04B41/5059C04B41/5001C04B41/4543C04B41/5079
Inventor 楼日新
Owner 四川共拓新材料股份有限公司