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Scale inhibitor, and preparation method thereof

A technology of scale inhibitor and catalyst, which is applied in the field of scale inhibitor preparation, can solve the problems of high preparation process requirements and high production cost, unsatisfactory scale inhibition effect of scale inhibitor, and given biodegradability of scale inhibitor, etc., to achieve Improve degradation performance and scale inhibition performance, excellent biodegradation performance, good inhibition effect

Inactive Publication Date: 2018-08-28
OCHEMATE MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Zhou Yuming, Liu Guangqing, etc. described the preparation and application effect of polyether scale inhibitors in CN103159333 and CN103145925, and their good effects in scale inhibition, corrosion inhibition and compatibility, etc., but did not discuss the biodegradation of the scale inhibitors. give specific data
The second type is polyamino acid, which has better biodegradability, such as polyaspartic acid (PASP) and polyepoxysuccinic acid (PESP), etc., can reach more than 80%. However, the scale inhibition effect of this type of scale inhibitor is not ideal, and the preparation process requirements and production cost are high, so this type of scale inhibitor is rarely used
Tian Caili, Chen Xiaochun, etc. introduced a biodegradable scale inhibitor obtained by copolymerization of aconitic acid and a small amount of acrylic acid in "Synthesis and Performance Research of New Green Scale Antiscalant AA-AA", but the aconitic acid used in it The acid is expensive and the yield of the prepared antiscalant is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] Under nitrogen protection, 20g itaconic acid and 10g maleic anhydride are dissolved in 60g deionized water to be mixed with monomer A solution, add chain transfer agent 6g isopropanol and catalyzer 0.03g ferric sulfate in above-mentioned monomer A solution, regulate Temperature to 70°C, stirred for 10 minutes, and prepared as a mixed solution; weighed 12g of potassium persulfate dissolved in 27g of deionized water to prepare an oxidizing agent solution, weighed 8g of sodium sulfite dissolved in 27g of deionized water to prepare a reducing agent solution, weighed 10g respectively Acrylic acid, 10g methyl acrylate, and 10g vinyl acetate are mixed as monomer B, and the oxidant solution, reducing agent solution and monomer B are added dropwise to the above mixed solution at the same time within 3 hours (hrs), and the temperature is adjusted to 80 ° C for 6 hrs , cooled to room temperature to obtain antiscalant samples. When the dosage of the obtained scale inhibitor is 5ppm...

Embodiment 2

[0042] Under nitrogen protection, 15g itaconic acid and 15g maleic anhydride are dissolved in 60g deionized water and are mixed with monomer A solution, add chain transfer agent 6g isopropanol and catalyzer 0.03g ferric sulfate in above-mentioned monomer A solution, regulate Temperature to 70°C, stirred for 10 minutes, and prepared as a mixed solution; weighed 12g of potassium persulfate dissolved in 27g of deionized water to prepare an oxidizing agent solution, weighed 8g of sodium sulfite dissolved in 27g of deionized water to prepare a reducing agent solution, weighed 10g respectively Mix acrylic acid, 10g methyl acrylate, and 10g vinyl acetate as monomer B, add the oxidizing agent solution, reducing agent solution and monomer B to the above mixed solution dropwise within 3hrs, adjust the temperature to 80°C for 6hrs, and cool to room temperature Obtain antiscalant samples. When the dosage of the obtained scale inhibitor is 5ppm, the scale inhibition rate to calcium carbona...

Embodiment 3

[0044] Under nitrogen protection, 10g itaconic acid and 20g maleic anhydride are dissolved in 60g deionized water to be mixed with monomer A solution, add chain transfer agent 6g isopropanol and catalyst 0.03g ferric sulfate in above-mentioned monomer A solution, regulate Temperature to 70°C, stirred for 10 minutes, and prepared a mixed solution; weighed 12g potassium persulfate dissolved in 27g deionized water to prepare an oxidizing agent solution, weighed 8g sodium sulfite dissolved in 27g deionized water to prepare a reducing agent solution, weighed 10g respectively Mix acrylic acid, 10g methyl acrylate, and 10g vinyl acetate as monomer B, add the oxidizing agent solution, reducing agent solution and monomer B to the above mixed solution dropwise within 3hrs, adjust the temperature to 80°C for 6hrs, and cool to room temperature Obtain antiscalant samples. When the dosage of the obtained scale inhibitor is 5ppm, the scale inhibition rate to calcium carbonate is 62.1%; when ...

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Abstract

The invention discloses a preparation method of a scale inhibitor. According to the preparation method, the scale inhibitor is prepared through copolymerization reaction of a monomer A and a monomer Bunder the action of a catalyst and an initiator; the initiator comprises an oxidizing agent and a reducing agent; the monomer A is at least one ingredient selected from itaconic acid, maleic anhydride, maleic acid, a monomethyl maleate, a monoethyl maleate, a monoisopropyl maleate, a isobutyl maleate, a mono-tert-butyl maleate, fumaric acid, monomethyl fumarate, monoethyl fumarate, and acomitic acid; and the monomer B is at least one selected from acrylic acid, methyl acrylate, ethyl acrylate, hydroxyethyl acrylate, hydroxy-propyl acrylate, methacrylic acid, hydroxyethyl methylacrylate, hydroxypropyl methacrylate, and vinyl acetate. The preparation method is simple in operation, and low in cost.

Description

technical field [0001] The invention relates to a preparation method of a scale inhibitor and the scale inhibitor. Background technique [0002] With the development of my country's economy, industrial water consumption is increasing year by year, and the demand for fresh water resources is also increasing year by year, and the problem of water conservation is becoming increasingly prominent. At present, circulating cooling water consumes the most in industrial water. In order to obtain fresh water, the concentration ratio of circulating cooling water must be increased. However, when increasing the concentration of circulating cooling water, a large amount of scale will be attached to the equipment and pipelines, which will not only affect the heat exchange but also cause corrosion. Therefore, it is necessary to use scale inhibitors to reduce the formation of scale. The scale inhibitors currently used are mainly phosphorus-based scale inhibitors or natural polymer scale inh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F5/10C08F222/02C08F222/06C08F220/06C08F220/14C08F218/08
CPCC02F5/10C08F222/02C08F222/06C08F220/06C08F220/14C08F218/08
Inventor 袁新兵李彬施力
Owner OCHEMATE MATERIAL TECH CO LTD
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