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Fireproof fabric capable of being porcelainized and preparation method of fireproof fabric

A technology of fire-proof cloth and porcelain, which is applied in the direction of textiles and papermaking, fiber treatment, flame-retardant fibers, etc. It can solve the problems of expensive fibers, reduced fire resistance, and poor air isolation ability, and achieves high safety performance and high operating temperature. High, good air tightness effect

Inactive Publication Date: 2018-09-21
蓝热新材料(嘉兴)有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] 1. A kind of cotton cloth, NOMEX, BA-SOFIL, KEVLAR, carbon fiber, etc., which has been treated with a saturated ammonium chloride solution. Most of the inorganic salts used for treatment are compounds containing phosphorus, nitrogen and other elements, many of which are harmful to the human body, and will lose their fireproof function after a long time, while fibers such as NOMEX are expensive, and domestic production capacity is limited
[0004] 2. Another kind of silicone rubber coated glass fiber cloth Silicone rubber coated glass fiber fireproof cloth is made of high temperature resistant, anti-corrosion and high-strength glass fiber cloth, impregnated with silicone or impregnated. This fireproof cloth is mainly used in low temperature- Between 70°C and 230°C, at a higher temperature, the silicone on the surface of the fiber will pyrolyze and fall off, resulting in the exposure of the fiber, the decrease of gas barrier performance, and the decrease of fire resistance
[0005] 3. There is also an inorganic fiber fabric fireproof cloth, which is mainly made of fiber fabrics such as asbestos, basalt fiber, and high silica fiber. This fireproof cloth has excellent high temperature resistance, and the service temperature can reach above 1000 °C. The ability to isolate air is poor, it cannot be used for fire extinguishing, hot air flow is easy to penetrate, and asbestos itself is easy to cause cancer, and its use has been basically banned at present; basalt or high silica fiber is more expensive, and the fabric flexibility is poor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A kind of porcelainable fireproof cloth, the fireproof cloth is composed of liquid porcelainable silicone rubber and surface-treated glass fiber cloth; wherein, the glass fiber cloth is made of alkali-free glass cloth, and the coupling agent used to treat the surface of the glass fiber cloth is silane coupling Agent HK550;

[0036] The mass parts composition of the liquid porcelainable silicone rubber is as follows:

[0037] Methyl vinyl liquid silicone rubber (110 glue) base rubber with kinematic viscosity of 20000mPa·s: 100 parts, solvent cyclohexane: 300 parts, inorganic porcelain-forming agent mica: 30 parts, low melting point porcelain-forming additive 400°C low melting point Glass powder: 30 parts, flame retardant aluminum hydroxide and magnesium hydroxide (weight ratio 2:1): 40 parts, anti-aging agent iron oxide: 2 parts, crosslinking agent hydrogen-containing silicone oil: 1 part, platinum catalyst: 0.3 share.

[0038] The preparation method of vitrified firep...

Embodiment 2

[0043] A ceramicable fireproof cloth, the fireproof cloth is composed of liquid porcelainable silicone rubber and surface-treated glass fiber cloth; wherein, the glass fiber cloth is made of low-alkali glass cloth, and the coupling agent used to treat the surface of the glass fiber cloth is silane coupling Agent HK570;

[0044] The mass parts composition of the liquid porcelainable silicone rubber is as follows:

[0045] Methyl vinyl liquid silicone rubber (110 glue) base rubber with a kinematic viscosity of 20000mPa·s: 100 parts, solvent n-hexane: 500 parts, inorganic porcelain forming agent kaolin: 50 parts, low melting point porcelain forming additive zinc borate: 10 parts , flame retardant aluminum hydroxide and magnesium hydroxide (weight ratio 2:1): 20 parts, anti-aging agent iron oxide: 5 parts, crosslinking agent hydrogen-containing silicone oil: 10 parts, platinum catalyst: 0.8 parts.

[0046] The preparation method of vitrified fireproof cloth comprises the followin...

Embodiment 3

[0051] A kind of ceramicable fireproof cloth, the fireproof cloth is composed of liquid ceramicable silicone rubber and surface-treated glass fiber cloth; wherein, the glass fiber cloth is made of low-alkali glass cloth, and the coupling agent used to treat the surface of the glass fiber cloth is tetrabutyl Titanate;

[0052] The mass parts composition of the liquid porcelainable silicone rubber is as follows:

[0053] α, ω-dihydroxypolydimethylsiloxane (107 glue) base glue with a kinematic viscosity of 20000mPa·s: 100 parts, solvent toluene: 400 parts, inorganic porcelain-forming agent montmorillonite and wollastonite (mass ratio 1 :2): 40 parts, low melting point ceramic additive ammonium polyphosphate: 30 parts, flame retardant melamine cyanurate: 30 parts, anti-aging agent iron oxide: 4 parts, crosslinking agent orthosilicate ethyl ester : 10 parts, catalyst dibutyltin laurate: 0.5 parts.

[0054] The preparation method of vitrified fireproof cloth comprises the followin...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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PUM

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Abstract

The invention relates to the technical field of fireproof fabrics and in particular relates to a fireproof fabric capable of being porcelainized and a preparation method of the fireproof fabric. The fireproof fabric is prepared from liquid silicone rubber capable of being porcelainized and a surface-treated glass fiber fabric, wherein the glass fiber fabric is an alkali-free glass fiber fabric ora low-alkali glass fiber fabric; a coupling agent for treating the surface of the glass fiber fabric is one or two of a silane coupling agent HK550, a silane coupling agent KH570 and tetrabutyl titanate; the fireproof fabric provided by the invention does not utilize inorganic salts which are harmful to bodies and fireproof inorganic components are covered with the silicone rubber and are not in contact with human bodies, so that the safety performance is high; compared with common silicone rubber, the liquid silicone rubber capable of being porcelainized has the advantages that the liquid silicone rubber capable of being porcelainized does not crack and fall off at high temperature so that glass fibers in the silicone rubber can be protected from high-temperature invasion, and furthermore, the utilization temperature can be higher and a high-temperature utilization range of 600 to 900 DEG C can be reached; the fireproof fabric provided by the invention has better air tightness, does not contain carcinogenic substances and has lower cost.

Description

technical field [0001] The invention relates to the technical field of fireproof cloth, in particular to a vitrified fireproof cloth and a preparation method thereof. Background technique [0002] High-temperature-resistant fireproof cloth has the characteristics of withstanding instantaneous high temperature and no open flame, and is widely used in aerospace, metallurgy, chemical industry, building materials, fire protection and other industrial fields. The existing domestic fire protection and fire extinguishing products mainly include the following three types: [0003] 1. A kind of cotton cloth, NOMEX, BA-SOFIL, KEVLAR, carbon fiber, etc., which has been treated with a saturated ammonium chloride solution. Most of the inorganic salts used for treatment are compounds containing phosphorus, nitrogen and other elements, many of which are harmful to the human body, and will lose their fireproof function after a long time. Fibers such as NOMEX are expensive, and domestic pro...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D06M13/513D06M15/643D06M11/79D06M11/45D06M11/44D06M11/49
CPCD06M11/44D06M11/45D06M11/49D06M11/79D06M13/513D06M15/643D06M2200/30
Inventor 王金合邹雄李文君
Owner 蓝热新材料(嘉兴)有限公司
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