Oil-proof packaging paper
A wrapping paper and oil-proof technology, which is applied in wrapping paper, wrapping paper, packaging, etc., can solve the problems of oil-proof wrapping paper with insignificant oil-proof effect and toxic substances, etc., achieve superior oil resistance, weaken lipophilicity, and reduce porosity rate effect
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[0026] The preparation method of composite oil-repellent component comprises the following steps:
[0027] S1. Preparation of composite modified starch: take cornstarch, add 0.1mol / L sodium hydroxide solution, ferric thiocyanate, and water at a mass ratio of 3:1:1:7~9, at 80~85°C, Mix and stir at 90~110r / min to get mixed solution A, add solvent A with 10~15% of mixed solution A mass, mix and stir for 20~30min, let stand for 22~24h, get modified starch, take modified starch, add Water with 1.5~2 times the mass of modified starch is stirred and mixed at 55~60°C at 230~250r / min to obtain the mixed solution B.
[0028] S2. Add fatty alcohol polyoxyethylene ether sodium sulfate of 4~8% of the mass of the mixed solution B, and stir for 20~30min with nitrogen gas, then add 2~5% of the initiator of the mass of the mixed solution B, 7~12% of the Solvent B and 3-8% hexafluorobutyl methacrylate, mixed and stirred for 4-5 hours, then added 7-12% hydroquinone of the mass of the mixed solu...
Embodiment 1
[0036] Silk fibroin powder: purchased from Silk Biotechnology Co., Ltd.
[0037]Pulp: purchased from Shandong Tranlin Paper Co., Ltd.
[0038] Solvent A: Take epichlorohydrin, trimethylamine hydrochloride, and water and mix them in a mass ratio of 1:1:3 to obtain solvent A.
[0039] Solvent B: Take calcium chloride, ethanol, and water and mix them in a mass ratio of 2:1:4 to obtain solvent B.
[0040] Initiator: Potassium persulfate and sodium bisulfite are mixed in a molar ratio of 1:0.45 to obtain the initiator.
[0041] The preparation method of composite oil-repellent component comprises the following steps:
[0042] S1. Preparation of composite modified starch: Take cornstarch, add 0.1mol / L sodium hydroxide solution, ferric thiocyanate, and water at a mass ratio of 3:1:1:7, and heat it at 80°C at 90r / min Mix and stir to obtain mixed solution A, add solvent A with 10% of the mass of mixed solution A, mix and stir for 20 minutes, and let it stand for 22 hours to obtain m...
Embodiment 2
[0051] Silk fibroin powder: purchased from Silk Biotechnology Co., Ltd.
[0052] Pulp: purchased from Shandong Tranlin Paper Co., Ltd.
[0053] Solvent A: Take epichlorohydrin, trimethylamine hydrochloride, and water and mix them in a mass ratio of 1:2:3 to obtain solvent A.
[0054] Solvent B: Take calcium chloride, ethanol, and water and mix them in a mass ratio of 2:1:5 to obtain solvent B.
[0055] Initiator: Potassium persulfate and sodium bisulfite are mixed in a molar ratio of 1:0.75 to obtain the initiator.
[0056] The preparation method of composite oil-repellent component comprises the following steps:
[0057] S1. Preparation of composite modified starch: Take cornstarch, add 0.1mol / L sodium hydroxide solution, ferric thiocyanate, and water at a mass ratio of 3:1:1:9, and heat it at 85°C at 110r / min Mix and stir to obtain mixed solution A, add solvent A with 15% of the mass of mixed solution A, mix and stir for 30 minutes, and let it stand for 24 hours to obtain...
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