High-strength refractory material and preparation method thereof

A refractory, high-strength technology, applied in the field of refractories, can solve the problems of poor mechanical toughness, reduced service life of refractories, material erosion, etc., achieve small expansion rate and reburning line changes, enhance reliability in use, and preparation methods simple effect

Inactive Publication Date: 2018-10-26
HEFEI MINGYOU HIGH TEMPERATURE TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The poor mechanical toughness of inorganic non-metallic materials is a common problem in inorganic non-metallic materials and materials. As refractory materials that belong to inorganic non-metallic materials, their mechanical toughness is also poor. However, its poor mechanical toughness also affects its thermal shock resistance at high temperatures. Due to the large temperature difference between rapid cooling and rapid heating and use, refractory materials are prone to cracking and peeling under the action of thermal expansion and contraction. The situation that affects the integrity of refractory materials reduces the service life of refractory materials; at the same time, for those refractory products that need to be moved frequently, their poor mechanical toughness will greatly increase the damage rate of refractory products and affect their daily use.
[0005] The application number is CN201610172527.1, which discloses a periclase-spinel lightweight refractory material and its preparation method. The lightweight periclase-spinel with different density gradients is prepared by using the magnesia carbothermal reduction transport oxidation method. For stone refractory materials, the preparation process requires strict atmospheric conditions. The prepared material has a dense surface and a loose interior. Once the dense surface layer is damaged and the porous structure inside is in contact with the erosive medium, the material will be severely eroded and it is difficult to use it as an alternative fuel. cement rotary kiln
The application number is CN201410059476.2, which discloses a lightweight periclase-magnesia-alumina-spinel refractory material for cement rotary kiln and its preparation method. The dense magnesia aggregate is replaced by porous periclase-spinel aggregate , although the prepared lightweight periclase-magnesia-alumina-spinel refractory material has good thermal shock stability and high strength, it has large pore size, high air permeability, and poor corrosion resistance to saline-alkali and heavy metal oxides. Difficult to use in cement rotary kilns using alternative fuels

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] A high-strength refractory material, comprising the following raw materials in parts by weight: 13 parts of base material, 7 parts of refractory substrate, 9 parts of alumina, 8 parts of partially stabilized zirconia, 6 parts of zirconium carbide particles, 10 parts of acrylic amine, methylene 8 parts of base bisacrylamide, 12 parts of ammonium persulfate, 9 parts of organic binder, 6 parts of catalyst and 5 parts of organic solvent.

[0031] A method for preparing a high-strength refractory material, comprising the following preparation steps:

[0032] a. Mix base material, refractory base material and alumina into a ball mill tank for ball milling for 2.2 hours, then add an organic solvent, stir evenly, and obtain material 1;

[0033] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylenebisacrylamide and ammonium persulfate, introduce into the high mixer, stir at 800r / min for 35min, then use ultrasonic oscillation for 29min to disper...

Embodiment 2

[0043] A high-strength refractory material, comprising the following raw materials in parts by weight: 9 parts of base material, 10 parts of refractory substrate, 9 parts of alumina, 8 parts of partially stabilized zirconia, 13 parts of zirconium carbide particles, 14 parts of acrylic amine, methylene 11 parts of base bisacrylamide, 10 parts of ammonium persulfate, 7 parts of organic binder, 3 parts of catalyst and 10 parts of organic solvent.

[0044] A method for preparing a high-strength refractory material, comprising the following preparation steps:

[0045] a. Mix base material, refractory base material and alumina into a ball mill tank for ball milling for 2.9 hours, then add an organic solvent, stir evenly, and obtain material 1;

[0046] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylenebisacrylamide and ammonium persulfate, introduce into a high mixer, stir at a speed of 900r / min for 33min, and then use ultrasonic oscillation for...

Embodiment 3

[0056] A high-strength refractory material, comprising the following raw materials in parts by weight: 12 parts of base material, 11 parts of refractory substrate, 8 parts of alumina, 11 parts of partially stabilized zirconia, 12 parts of zirconium carbide particles, 13 parts of acrylic amine, methylene 12 parts of base bisacrylamide, 8 parts of ammonium persulfate, 8 parts of organic binder, 4 parts of catalyst and 9 parts of organic solvent.

[0057] A method for preparing a high-strength refractory material, comprising the following preparation steps:

[0058] a. Mix base material, refractory base material and alumina into a ball mill tank for ball milling for 2.9 hours, then add an organic solvent, stir evenly, and obtain material 1;

[0059] b. Mix partly stabilized zirconia, zirconium carbide particles, acrylic amine, methylenebisacrylamide and ammonium persulfate, introduce into the high mixer, stir at 800r / min for 35min, then use ultrasonic oscillation for 29min to dis...

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Abstract

The invention provides a high-strength refractory material and a preparation method thereof. The high-strength refractory material is prepared from the following components: a base material, a refractory base material, aluminum oxide, partially stabilized zirconia, zirconium carbide particles, acrylamide, methylene bisacrylamide, ammonium persulfate, an organic bonding agent, a catalyst and an organic solvent. The refractory material prepared in the invention also has relatively high fracture toughness; the service life of the refractory material can be prolonged while the using reliability ofthe refractory material can be enhanced; moreover, the preparation method is simple and efficient, and large-scale production can be easily realized on existing equipment.

Description

technical field [0001] The invention belongs to the technical field of refractory materials, and in particular relates to a high-strength refractory material and a preparation method thereof. Background technique [0002] In the traditional sense, refractory materials refer to inorganic non-metallic materials with a refractoriness of not less than 1580 °C. And parts of the material, and can withstand the corresponding physical and chemical changes and mechanical action. [0003] Most refractory materials are made of natural ores (such as refractory clay, silica, magnesite, dolomite), and some industrial raw materials and synthetic raw materials (such as industrial alumina, silicon carbide, synthetic mullite, Synthetic spinel, etc.) are also increasing, so there are many types of refractory materials. According to the mineral composition, refractories can be divided into silica, aluminum silicate, magnesia, dolomite, olivine, spinel, carbonaceous, zirconium-containing refra...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66C04B2/10
CPCC04B35/66C04B2/102C04B2235/3217C04B2235/3244C04B2235/3839
Inventor 王虎
Owner HEFEI MINGYOU HIGH TEMPERATURE TECH CO LTD
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