Preparation method of membrane material capable of promoting denitrification and for pond culture

A membrane material and denitrification technology, applied in the field of preparation of membrane materials for pond culture, can solve problems such as application limitation, no bacteriostatic or bactericidal function, membrane biological fouling, etc., achieve good mechanical properties, improve load stability, reduce The effect of nitrogen content

Inactive Publication Date: 2018-11-13
WUHU EDISON AUTOMATION EQUIP
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  • Abstract
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AI Technical Summary

Problems solved by technology

Usually, membrane materials can only retain bacteria and have no antibacterial or bactericidal functions. Therefore, membrane biofouling is a technical problem in the field of membrane use and separation technology.
[0005] Chitosan is a natural cationic polysaccharide, which has the advantages of wide sources, low price, non-toxic and harmless, and degradable. Its molecular chain contains a large number of amino groups and hydroxyl groups, which can form stable chelates with many metal ions. Due to the insoluble properties of chitosan in common solvents, its application is limited

Method used

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Embodiment Construction

[0021] A method for preparing membrane materials for pond culture that promotes denitrification, comprising the following steps:

[0022] (1) Mix silicon dioxide, 2-(4-chlorosulfonic acid phenyl)ethyltrimethoxysilane and anhydrous toluene at a mass ratio of 3:1:36, heat up to 110°C, react for 20 hours, and then filter And wash 3 times with anhydrous toluene, vacuum dry at 70 ℃ for 10 hours for later use;

[0023] (2) Mix the product obtained in step 1 with ammonia water with a mass concentration of 15-25% at a mass ratio of 1:12, react at 40°C for 6 hours, filter after completion, and then mix with glacial acetic acid and sodium hypochlorite with a mass concentration of 8%. The solution was mixed at a mass ratio of 1.2:0.8:13 and reacted at 6°C for 90 minutes, then filtered, washed with water, and dried to obtain the product for use;

[0024] (3) Dissolve chitosan in isopropanol solution at a solid-to-liquid ratio of 1:16g / mL, then slowly add sodium hydroxide with a total mas...

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Abstract

The invention discloses a preparation method of a membrane material capable of promoting denitrification and for pond culture. The membrane material is prepared from the following raw materials: silicon dioxide, 2-(4-phenyl chlorosulfonate)ethyl trimethoxysilane, corn starch, glucose, glacial acetic acid, chitosan, chloroacetic acid, silver nitrate, beta cyclodextrin and polyacrylic acid. Multi-step modification is conducted by selecting the silicon dioxide, the aim of adsorbing nitrite is fulfilled by depending on the huge specific surface area of the silicon dioxide and the stable and ordered pore channel structure, the obtained silver particle loaded chitosan, the modified silicon dioxide and the beta cyclodextrin are embedded on the basis, a stable fiber membrane structure is formed through electrostatic spinning and thermal crosslinking, organic carbon is supplemented for the membrane structure through dipping of the corn starch and the glucose, denitrifying bacteria occupy dominant position in sediment aquaculture, the nitrogen content of the sediment and aquatic water is reduced, a good environment is provided for biological breeding, the quality of aquatic products is improved, and the preparation method is suitable for being widely used in pond culture.

Description

technical field [0001] The invention relates to the technical field of water body purification, in particular to a preparation method of a membrane material for pond culture that promotes denitrification. Background technique [0002] Pond aquaculture occupies an important position in my country's aquaculture system. The 2016 China Fishery Statistical Yearbook shows that: my country's freshwater aquaculture ponds are 2.7×1010 square meters, accounting for more than 43.9% of the total aquaculture production. Due to the one-sided pursuit of high yield in the traditional freshwater pond culture, a large amount of bait and fertilization is used, and the accumulation of residual bait and excrement of the cultured objects will pollute the culture environment. In addition, the wide application of high-density intensive farming models has led to an increase in the concentration of nitrogen, phosphorus and other elements in the water body, and nitrogen, sulfur and other elements in o...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D71/82B01D67/00B01D69/02B01D71/02B01D71/08B01D71/40C02F3/28C02F101/16
CPCB01D71/82B01D67/0079B01D69/02B01D71/027B01D71/08B01D71/40B01D2325/12B01D2325/48C02F3/2853C02F2101/16C02F2103/007C02F2305/06
Inventor 汤广顺
Owner WUHU EDISON AUTOMATION EQUIP
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