[0025] Take 5~10g Enteromorpha and place it in a Soxhlet extractor. Use 80~100mL of 20% ethyl acetate ethanol solution to extract at 85~90℃ for 6~8h. After removing the lipid extract , And then add 40-50mL of 20% sodium carbonate solution to the Soxhlet extractor to extract polysaccharides at 58-62℃, filter and separate Enteromorpha slag; use the above-mentioned Enteromorpha slag with a mass fraction of 10% Sodium chlorite solution is immersed and oxidized for 2~3h, the filtrate is filtered and removed to obtain the residue. The residue is immersed in 40% potassium hydroxide solution for 5~10min and then washed with absolute ethanol to neutrality to obtain purified seaweed fiber Element; Put 70~80g kyanite ore in a ball milling tank, add agate ball milling beads with a diameter of 6~8mm, and mill for 30~45min to obtain kyanite powder. Combine kyanite powder and aluminum fluoride trihydrate by mass The ratio of 3:1 is mixed and put into the ball milling tank to continue ball milling for 1~2h to obtain mixed mineral powder. Put the mixed mineral powder into the corundum crucible, heat to 1550~1600℃, heat preservation and calcination for 4~5h to obtain mullite ; Put the mullite into a mortar and grind for 3~4h, pass a 200-mesh sieve to obtain mullite powder, put 60~70g of mullite powder into 200~300mL silica sol with a mass fraction of 25%, stir and disperse After 10-15min, transfer to a high-speed shearing machine at a speed of 4000-5000r/min for high-speed shearing, add 40-50mL of aluminum nitrate solution with a mass fraction of 10% to the high-speed shearing machine, and then add a mass fraction of 50% The pH of the ammonia water adjustment system is 9-10, continue high-speed shearing for 15-20 minutes, stand and age for 20-24 hours to obtain the precursor sol; put 40-50g nanofiber sponge into 200-220mL precursor sol, stir Purified algae cellulose is obtained after dispersion for 30 to 45 minutes. The purified algae cellulose and the precursor sol are mixed at a mass ratio of 1:5, placed in a high-speed disperser, and dispersed at a high speed of 3000-4500r/min for 10-15min to obtain dispersion Pulp, the dispersed slurry is placed in a vacuum suction filter, and the filtrate is removed to obtain composite cotton fiber; in parts by weight, 40 to 45 parts of composite cotton fiber and 5 to 8 parts of polydimethylsiloxane , 10-15 parts of liquid paraffin, 10-12 parts of yeast powder, 20-25 parts of water are put into the fermentation tank, sealed and fermented at 35~37℃ for 3~5 days, and then filtered to remove the fermentation filtrate to obtain modified expansion The fiber residue is washed with absolute ethanol until it is neutral, and then placed in an oven at a temperature of 80-90° C. to dry for 4 to 5 hours, and then integrated with a knitting machine to obtain a high-friction grease-retaining wiping material.
[0026] Put 5g Enteromorpha into the Soxhlet extractor, extract with 80mL 20% ethyl acetate ethanol solution at 85℃ for 6h, remove the lipid extract, and then transfer it to the Soxhlet extractor Add 40 mL of 20% sodium carbonate solution to extract polysaccharides at 58℃, filter and separate Enteromorpha residues; The above-mentioned Enteromorpha residues are immersed and oxidized with 10% sodium chlorite solution for 2h, filtered and removed The filtrate is used to obtain the residue. The residue is immersed in 40% potassium hydroxide solution for 5 minutes and then washed with absolute ethanol to neutrality to obtain purified seaweed cellulose; 70g kyanite ore is placed in a ball milling tank, and the pellets are added Agate ball milling beads with a diameter of 6mm were milled for 30 minutes to obtain kyanite powder. The kyanite powder and aluminum fluoride trihydrate were mixed at a mass ratio of 3:1 and placed in a ball milling tank for 1 hour to obtain mixed mineral powder. Put the ore powder in a corundum crucible, heat to 1550℃, heat and calcine for 4h to obtain mullite; put the mullite in a mortar and grind for 3h, pass a 200-mesh sieve to obtain mullite powder. Put the powder into 200mL silica sol with a mass fraction of 25%, stir and disperse for 10 minutes, then transfer to a high-speed shearing machine for high-speed shearing at a speed of 4000r/min, and add 40mL of 10% nitric acid to the high-speed shearing machine Aluminum solution, then add 50% ammonia water to adjust the pH to 9 in the system, continue high-speed shearing for 15 minutes, and leave to stand for 20 hours to obtain the precursor sol; put 40g nanofiber sponge into 200mL precursor sol, stir After 30 minutes of dispersion, the purified seaweed cellulose is obtained. The purified seaweed cellulose and the precursor sol are mixed at a mass ratio of 1:5, placed in a high-speed disperser, and dispersed at a high speed of 3000r/min for 10 minutes to obtain a dispersed slurry. The material is placed in a vacuum suction filter, and the filtrate is removed to obtain composite cotton fiber; in parts by weight, 40 parts of composite cotton fiber, 5 parts of polydimethylsiloxane, 10 parts of liquid paraffin, and 10 parts of yeast powder , 20 parts of water was put into the fermentation tank, sealed and fermented at 35℃ for 3 days, and then filtered to remove the fermentation filtrate to obtain modified expanded fiber residue, washed with absolute ethanol to neutrality, and then placed at a temperature of 80℃ Dry it in an oven for 4 hours, and then integrate it with a knitting machine to obtain a high friction and oily wiping material.
[0027] Take 7g Enteromorpha and put it in the Soxhlet extractor, and extract it with 90mL 20% ethyl acetate ethanol solution at 87℃ for 7h. After removing the lipid extract, transfer it to the Soxhlet extractor. Add 45mL of 20% sodium carbonate solution to extract polysaccharides at 60℃, filter and separate enteromorpha residues; impregnate the above-mentioned Enteromorpha residues with 10% sodium chlorite solution to oxidize for 2.5h, filter The filtrate is removed to obtain the residue. The residue is immersed in 40% potassium hydroxide solution for 7 minutes and then washed with absolute ethanol to neutrality to obtain purified seaweed cellulose; 75g kyanite ore is placed in a ball milling tank and added Agate ball milling beads with a particle size of 7mm were ball milled for 40 minutes to obtain kyanite powder. The kyanite powder and aluminum fluoride trihydrate were mixed at a mass ratio of 3:1 and placed in a ball mill tank to continue ball milling for 1.5 hours to obtain mixed mineral powder. Put the mixed mineral powder into a corundum crucible, heat it to 1570℃, heat and calcine for 4.5h to obtain mullite; put the mullite in a mortar and grind for 3.5h, pass a 200-mesh sieve to obtain mullite powder. Put 65g of mullite powder into 250mL of silica sol with a mass fraction of 25%, stir and disperse for 12 minutes, then transfer to a high-speed shearing machine at a speed of 4500r/min for high-speed shearing, and add 45mL of mass fraction to the high-speed shearing machine. 10% aluminum nitrate solution, then add 50% ammonia water to adjust the pH to 9 in the system, continue high-speed shearing for 17 minutes, and stand for 22 hours to obtain a precursor sol; put 45g of nanofiber sponge into 210mL of precursor In the sol, the purified seaweed cellulose is obtained after stirring and dispersing for 40 minutes. The purified seaweed cellulose and the precursor sol are mixed at a mass ratio of 1:5, placed in a high-speed disperser, and dispersed at a high speed of 4000r/min for 12 minutes to obtain a dispersed slurry , The dispersed slurry is placed in a vacuum suction filter, and the filtrate is removed to obtain composite cotton fiber; in parts by weight, 42 parts of composite cotton fiber, 7 parts of polydimethylsiloxane, 12 parts of liquid paraffin, Put 11 parts of yeast powder and 22 parts of water into the fermenter, seal and ferment at 36℃ for 4 days, then filter to remove the fermentation filtrate to obtain modified expanded fiber residue, wash with absolute ethanol to neutrality, and then put it at temperature It is dried in an oven at 85°C for 4.5 hours, and then integrated with a knitting machine to obtain a high-friction and oily wiping material.
[0028] Take 10g Enteromorpha and place it in a Soxhlet extractor. Use 100mL of 20% ethyl acetate ethanol solution to extract at 90℃ for 8h. After removing the lipid extract, transfer it to the Soxhlet extractor. Add 50mL of 20% sodium carbonate solution to extract polysaccharides at 62℃, filter and separate Enteromorpha residues; The above-mentioned Enteromorpha residues are immersed and oxidized with a 10% sodium chlorite solution for 3h, filtered and removed The filtrate is used to obtain the residue. The residue is immersed in 40% potassium hydroxide solution for 10 minutes and then washed with absolute ethanol to neutrality to obtain purified seaweed cellulose; 80g kyanite ore is placed in a ball milling tank, and the pellets are added Agate ball milling beads with a diameter of 8mm were milled for 45 minutes to obtain kyanite powder. The kyanite powder and aluminum fluoride trihydrate were mixed at a mass ratio of 3:1 and put into the ball milling tank for 2 hours to obtain mixed mineral powder. Put the mineral powder in a corundum crucible, heat it to 1600℃, heat and calcine for 5 hours to obtain mullite; put the mullite in a mortar and grind for 4 hours, pass a 200-mesh sieve to obtain mullite powder. Put the powder into 300mL silica sol with a mass fraction of 25%, stir and disperse for 15 minutes, transfer to a high-speed shearing machine at a high speed of 5000r/min, and add 50mL of 10% nitric acid to the high-speed shearing machine Aluminium solution, then add 50% ammonia water to adjust the pH of the system to 10, continue high-speed shearing for 20 minutes, and stand for 24 hours to obtain a precursor sol; put 50g of nanofiber sponge into 220mL of precursor sol and stir After 45 minutes of dispersion, the purified seaweed cellulose is obtained. The purified seaweed cellulose and the precursor sol are mixed at a mass ratio of 1:5, placed in a high-speed disperser, and dispersed at a high speed of 4500r/min for 15 minutes to obtain a dispersed slurry. The material is sucked and filtered in a vacuum suction filter, and the filtrate is removed to obtain composite cotton fiber; in parts by weight, 45 parts of composite cotton fiber, 8 parts of polydimethylsiloxane, 15 parts of liquid paraffin, 12 parts of yeast powder , 25 parts of water was put into the fermentor, sealed and fermented at 37℃ for 5 days, and then filtered to remove the fermentation filtrate to obtain modified expanded fiber residue, washed with absolute ethanol to neutrality, and then placed at a temperature of 90℃ Dry it in an oven for 5 hours, and then integrate it with a knitting machine to obtain a high-friction, oil-retaining wipe material.