The invention relates to a liquid or powder persimmon tannin derived from a green persimmon and a corresponding separating extracting process thereof. The tannin content is from 2% to 99% in the product of liquid persimmon tannin or powder persimmon tannin, wherein the liquid persimmon tannin is obtained through the processes of persimmon resource selecting, juicing, fermenting, alcohol removing, ageing, purifying, and the like, and the powder persimmon tannin is obtained after the liquid persimmon tannin is dried and crushed. The invention overcomes the defects of the present persimmon tannin products and processes; the treatment is respectively performed according to the characteristics of different components in the persimmon; and the invention provides a series of extracting processes for effectively separating and purifying the persimmon tannin, such as, adopting yeast fermentation for converting sugar in the persimmon juice into alcohol, separating the alcohol through vacuum evaporation, ageing and boosting the persimmon tannin to polymerize into macromolecule, filtering and removing micro-molecular odor matters, such as, acetic acid, and the like. During the production process of the product provided by the invention, no chemical reagent is added; the end product is pure natural persimmon component and can be used as a clarifying agent for beer and wine, an additive of cosmetics, the additive of various deodorants, a sewage treating agent, an absorbing agent for noble metal, and the like; and the market prospect is wide.