Production method of polyphase structure high tenacity ship plate steel EH40

A production method and technology of multi-phase structure, applied in the field of metallurgy, can solve the problems of prolonged production cycle, coarse grains, poor toughness, etc., and achieve the effects of shortening the delivery cycle, reducing the alloy content and reducing the production cost.

Inactive Publication Date: 2019-01-11
HUNAN VALIN XIANGTAN IRON & STEEL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

For thick plates over 50mm, due to the limitation of the compression ratio, the original austenite grains cannot be fully recrystallized and refined during the rolling process, the structure is generally coarse, and the toughness deteriorates. Usually, an additional heat treatment process is required. In order to ensure the strength and toughness matching of the thick plate, this not only increases the production cost, but also prolongs the production cycle
In addition, the medium and heavy plate products produced by the TMCP process in the world are generally single-phase matrix structures of pure ferrite or pure bainite. Although by controlling the rolling parameters, sometimes a mixed structure of ferrite and bainite can be obtained. Or multi-phase structure, but generally it is a grain structure with relatively coarse grains. Although the strength is improved, the plasticity and toughness are deteriorated.
[0003] Chinese patent 200680039706.2 discloses a "method for manufacturing hot-rolled strip with multi-phase structure", a method for producing TRIP steel (transformation-induced plasticity steel) through hot rolling process, which adds higher carbon, and there is no requirement for the content of Ni, this composition system is only suitable for the production of strips or coils with a thickness of ≤16mm in hot continuous rolling or cold rolling, and is not applicable to single rolled medium and heavy plates
Chinese patent 201180011390.7 discloses a "Multiphase structure stainless steel plate and steel strip and their manufacturing method", through off-line multiphase annealing of cold-rolled stainless steel plate or steel strip to form a multiphase of ferrite and martensite Organization, there is obvious difference with the online rolling of the present invention
Chinese patent 201410791739.9 discloses "A X90 grade multi-phase pipeline steel plate for longitudinal seam welded pipe and its manufacturing method". The chemical composition of the content of the invention is different from that of the present invention. Significantly improve the strength of the steel plate, but it will inhibit the aggregation and diffusion of carbides, thereby inhibiting the generation of ferrite and promoting the formation of granular bainite. Unfavorable, so it is only suitable for pipeline steel products with a thickness below 30mm, not for thick gauge steel plates above 50mm
At the same time, the post-rolling cooling rate in the production process reaches 25-35°C / s. At present, the post-rolling cooling equipment capacity of wide and thick plate manufacturers is not enough, especially for steel plates with a thickness greater than 50mm, it is difficult to achieve such a large cooling rate.

Method used

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  • Production method of polyphase structure high tenacity ship plate steel EH40
  • Production method of polyphase structure high tenacity ship plate steel EH40

Examples

Experimental program
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Effect test

Embodiment 1

[0020] A production method of multi-phase structure high toughness ship plate steel EH40, the chemical composition weight percentage of the steel is: carbon=0.06, silicon=0.22, manganese=1.56, phosphorus=0.008, sulfur=0.0016, niobium=0.025, titanium= 0.014, aluminum = 0.046, nickel = 0.36, and the rest are Fe and unavoidable impurities. The process steps include: smelting: converter tapping [C]=0.0032, adopting LF+RH refining process, LF furnace refining full-process argon blowing, white slag retention time 22min, RH vacuum degassing treatment, outgoing molten steel [N]=38 ppm , [H]=1.2ppm; continuous casting adopts full protection casting, slab thickness is 300mm, slab low center segregation C class 0.5.

[0021] The used cast slab is rolled into EH40 ship plate with a thickness of 50mm. The heating temperature is 1152°C, and two-stage rolling is adopted. The first stage rough rolling finish rolling temperature is 1031°C, the intermediate billet is 120mm, and the second stage...

Embodiment 2

[0023] A production method of multi-phase structure high toughness ship plate steel EH40, the chemical composition weight percentage of the steel is: carbon = 0.07, silicon = 0.22, manganese = 1.56, phosphorus = 0.008, sulfur = 0.0018, niobium = 0.026, titanium = 0.015, aluminum = 0.044, nickel = 0.37, and the rest are Fe and unavoidable impurities. The key process steps include: smelting: converter tapping [C]=0.0036, adopting LF+RH refining process, LF furnace refining full-process argon blowing, white slag retention time 21min, RH vacuum degassing treatment, outbound molten steel [N]=36ppm , [H]=1.5ppm; continuous casting adopts full protection casting, tundish slab thickness is 300mm, slab low center segregation C class 0.5.

[0024] In this example, the cast slab is used to roll the EH40 ship plate with a thickness of 80 mm. The heating temperature is 1188 ° C. Two-stage rolling is adopted. The first stage rough rolling finish rolling temperature is 1042 ° C, the intermed...

Embodiment 3

[0026]A production method of multi-phase structure high-toughness ship plate steel EH40, the chemical composition weight percentage of the steel is: carbon = 0.05, silicon = 0.25, manganese = 1.55, phosphorus = 0.009, sulfur = 0.0017, niobium = 0.028, titanium = 0.015, aluminum = 0.046, nickel = 0.37, and the rest are Fe and unavoidable impurities. The key process steps include: smelting: converter tapping [C]=0.0024, adopting LF+RH refining process, argon blowing throughout the LF furnace refining, white slag retention time 20min, RH vacuum degassing treatment, outbound molten steel [N]=36ppm , [H]=1.5ppm; continuous casting adopts full protection casting, tundish slab thickness is 300mm, slab low center segregation C class 0.5.

[0027] In this example, the EH40 ship plate with a thickness of 100 mm is rolled from cast slabs, and the heating temperature is 1195 ° C. Two-stage rolling is adopted. The rough rolling and finishing rolling temperature of the first stage is 1002 °...

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Abstract

The present invention discloses a production method of polyphase structure high tenacity ship plate steel EH40. The steel includes the following chemical compositions by weight percentage: carbon=0.04-0.08, silicon 0.15-0.35, manganese=1.50-1.60, phosphorus less than and equal to 0.015, sulfur less than and equal to 0.005, niobium less than and equal to 0.02-0.03, titanium less than and equal to 0.008-0.02, aluminum=0.015-0.05, nickel=0.30-0.40, and the remaining of Fe and inevitable impurities. The process steps include smelting, continuous casting, rolling, relaxation and cooling. The methodof the present invention breaks through the limitation of compression ratio for rolling continuously cast bloom by the traditional TMCP process without additional thermal treatment process; high tenacity steel plate with a low temperature impact requirement of below -40 DEG C is produced, the maximum thickness may reach 100 mm, and the product can be widely applied to manufacturing of thick plates in various fields such as shipbuilding, maritime work, wind power, bridge, architecture and engineering machinery; and the method of the present invention can be realized by using the current equipment and process condition of a steel mill, which does not increase investment and equipment upgrading, and further improve the production efficiency and realizes energy conservation and consumption reduction.

Description

technical field [0001] The invention belongs to the technical field of metallurgy, and relates to a production method of ship plate steel EH40 with multiphase structure and high toughness. technical background [0002] When continuous casting slabs are used to produce medium and heavy plate products with high toughness requirements, the traditional rolling method can only produce ferritic pearlite structure or Only the bainite structure has good strength and toughness, so the traditional TMCP process can generally only be used for rolling thin plates below 50mm. For thick plates over 50mm, due to the limitation of the compression ratio, the original austenite grains cannot be fully recrystallized and refined during the rolling process, the structure is generally coarse, and the toughness deteriorates. Usually, an additional heat treatment process is required. Only in this way can the strength and toughness of the thick plate be matched, which not only increases the producti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C21D8/02C22C38/02C22C38/04C22C38/06C22C38/08C22C38/12C22C38/14
Inventor 于青罗登刘丹肖大恒高海亮脱臣德刘琴
Owner HUNAN VALIN XIANGTAN IRON & STEEL CO LTD
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