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Polyisobutylene modified building asphalt and preparation method thereof

A technology of polyisobutylene and building asphalt, which is applied in the direction of construction, building components, building structures, etc., can solve the problems of high low-temperature brittleness, thermodynamic instability, and long-term process, so as to improve the performance of high and low temperature resistance and avoid ineffectiveness. Obvious and economical operation

Inactive Publication Date: 2019-01-22
朱红艳
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Petroleum asphalt has good thermoplasticity, adhesion, and viscoelasticity, and is the basic material for building waterproofing projects. However, due to its strong sensitivity to temperature, it is easy to flow at high temperatures, brittle at low temperatures, and easy to crack. It has low strength and poor elasticity. 、Using only asphalt as a building waterproof material cannot meet the requirements of the current building
[0003] At present, a lot of reports have been made on the modification of asphalt, the most commonly used is to use polymer modifiers such as thermoplastic elastomers such as SBS and SBR, although these polymer modifiers can modify the asphalt in some aspects. However, the blending system of these polymers and base asphalt is often thermodynamically unstable and prone to segregation, resulting in unsatisfactory performance of the product during use, and the polymer modifier is expensive. The production process Complexity, serious energy consumption, resulting in high cost of prepared modified asphalt
[0004] A large amount of inorganic fillers are often added to construction asphalt to enhance the strength of asphalt. However, these inorganic fillers are inert seasonings and are often incompatible with asphalt. Under long-term standing conditions, it is easy to cause segregation of inorganic fillers and asphalt, resulting in the prepared asphalt Poor product storage stability and other issues
For example, the patent CN1935903A discloses a modified asphalt, adding a large amount of zinc borate, antimony trioxide, magnesium hydroxide, aluminum hydroxide and other fillers, which can easily lead to segregation of inorganic fillers in the asphalt, resulting in poor storage stability The problem
CN1935902A discloses a kind of modified asphalt, adding a large amount of inorganic fillers, through the high-speed shearing process, resulting in a long process time and increasing production costs, even so, long-term thermal storage hydrogen will also appear segregation phenomenon, resulting in unstable thermal storage stability it is good

Method used

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  • Polyisobutylene modified building asphalt and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] A polyisobutylene modified construction asphalt is composed of the following components by weight:

[0041] Basic asphalt 100 parts

[0042] 10 parts of epoxy polyisobutylene

[0043] lignin 5 parts

[0044] Inorganic filler 50 parts

[0045] Silane coupling agent 1 part

[0046] Anti-aging agent 0.5 parts

[0047] The base asphalt is selected from straight-run petroleum asphalt.

[0048] The inorganic filler is selected from 15 parts of magnesium hydroxide, 20 parts of barium sulfate and 15 parts of calcium carbonate.

[0049] The silane coupling agent is selected from aminosilane coupling agents, selected from 3-aminopropyltriethoxysilane.

[0050] The anti-aging agent is selected from phenolic antioxidants.

[0051] The preparation method of this polyisobutylene modified construction asphalt is:

[0052] 1) Add magnesium hydroxide, barium sulfate, and calcium carbonate to the planetary grinder, and add ethanol / water (50 / 50

[0053]parts by mass), then add an...

Embodiment 2

[0059] A polyisobutylene modified construction asphalt is composed of the following components by weight:

[0060] Basic asphalt 100 parts

[0061] 20 parts of epoxy polyisobutylene

[0062] Lignin 7.5 parts

[0063] Inorganic filler 60 parts

[0064] 1.5 parts of silane coupling agent

[0065] Anti-aging agent 1 part

[0066] The base asphalt is selected from straight-run petroleum asphalt.

[0067] The inorganic filler is selected from 20 parts of magnesium hydroxide, 20 parts of barium sulfate and 20 parts of calcium carbonate.

[0068] The silane coupling agent is selected from aminosilane coupling agents, selected from 3-aminopropyltriethoxysilane.

[0069] The anti-aging agent is selected from phenolic antioxidants.

[0070] The preparation method of this polyisobutylene modified construction asphalt is:

[0071] 1) Add magnesium hydroxide, barium sulfate, and calcium carbonate to the planetary grinder, and add ethanol / water (50 / 50

[0072] parts by mass), then ...

Embodiment 3

[0078] A polyisobutylene modified construction asphalt is composed of the following components by weight:

[0079] Basic asphalt 100 parts

[0080] 30 parts of epoxy polyisobutylene

[0081] lignin 10 parts

[0082] Inorganic filler 80 parts

[0083] 3 parts of silane coupling agent

[0084] Anti-aging agent 2 parts

[0085] The base asphalt is selected from straight-run petroleum asphalt.

[0086] The inorganic filler is selected from 25 parts of magnesium hydroxide, 25 parts of barium sulfate and 30 parts of calcium carbonate.

[0087] The silane coupling agent is selected from aminosilane coupling agents, selected from 3-aminopropyltriethoxysilane.

[0088] The anti-aging agent is selected from phenolic antioxidants.

[0089] The preparation method of this polyisobutylene modified construction asphalt is:

[0090] 1) Add magnesium hydroxide, barium sulfate, and calcium carbonate to the planetary grinder, and add ethanol / water (50 / 50

[0091] parts by mass), then ad...

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Abstract

The invention relates to a polyisobutylene modified building asphalt and a preparation method thereof. The polyisobutylene modified building asphalt is composed of the following raw materials in partsby weight: 100 parts of base asphalt, 10 to 30 parts of epoxidized polyisobutylene, 5 to 10 parts of reinforcing fiber, 50 to 80 parts of an inorganic filler, 0.5 to 3 parts of a silane coupling agent, and 0.5 to 2 parts of an anti-aging agent. The epoxidized polyisobutylene for modifying lignin and the inorganic filler can significantly improve the compatibility, and increases the thermal storage stability of the modified asphalt, polyisobutylene is used to toughen asphalt, and can significantly improve the high and low temperature resistance and brittleness of the asphalt, moreover, the polyisobutylene has good hydrophobic property, weather resistance, and the like, and can significantly improve the weather resistance of the asphalt.

Description

technical field [0001] The invention belongs to the technical field of organic polymer composite materials, and in particular relates to a polyisobutylene modified building asphalt and a preparation method thereof. Background technique [0002] Petroleum asphalt has good thermoplasticity, adhesion, and viscoelasticity, and is the basic material for building waterproofing projects. However, due to its strong sensitivity to temperature, it is easy to flow at high temperatures, brittle at low temperatures, and easy to crack. It has low strength and poor elasticity. 1. Only adopting asphalt as a building waterproof material cannot meet the requirements of the current building. [0003] At present, a lot of reports have been made on the modification of asphalt, the most commonly used is to use polymer modifiers such as thermoplastic elastomers such as SBS and SBR, although these polymer modifiers can modify the asphalt in some aspects. However, the blending system of these pol...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L95/00C08L97/00C08L23/26C08K13/06C08K9/06C08K9/04C08K3/22C08K3/30C08K3/26C08K3/34C08K13/08C08K11/00
CPCC08K2003/2224C08K2003/265C08K2003/3045C08L95/00C08L2205/03C08L97/005C08L23/26C08K13/06C08K9/06C08K9/08C08K3/22C08K3/30C08K3/26C08K13/08C08K3/34C08K11/005
Inventor 朱红艳
Owner 朱红艳
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