Composite aspartic acid polymer, and preparation method and application thereof
An aspartic acid and polymer technology, applied in the agricultural field, can solve the problems of difficulty in meeting the requirements of stable yield and quality of crisp pears, lack of scientificity and pertinence, poor water and fertilizer retention effects, etc. Stretching, soil improvement effect
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Embodiment 1
[0025] A preparation method of composite aspartic acid polymer, comprising the steps of:
[0026] S1. Mix 1kg lactic acid and 20kg triethylene glycol, prepolymerize for 2h, prepolymerize at 145°C, prepolymerize at 3kPa, remove water, add 0.2kg terephthalic acid, melt polycondensate for 4h, polycondensate The temperature is 170°C, the polycondensation pressure is 65Pa, the temperature is lowered, and the chloroform is dissolved to obtain a prefabricated material;
[0027] S2. Stir 20kg of polysuccinimide and 50kg of 2.2mol / L sodium hydroxide solution for 10min at a stirring temperature of 40°C, adjust the pH of the system to 4.5-5 with a 75wt% phosphoric acid solution, and add 25kg of prefabricated material Mix evenly, add 1 kg of ethylene glycol diglycidyl ether and react for 2 hours at a reaction temperature of 50° C., precipitate with methanol, purify, and dry in vacuum to obtain a composite aspartic acid polymer.
[0028] A soil conditioner for pear planting, its raw mater...
Embodiment 2
[0031] A preparation method of composite aspartic acid polymer, comprising the steps of:
[0032] S1. Mix 4kg of lactic acid and 10kg of triethylene glycol, prepolymerize for 4 hours, prepolymerize at 135°C, prepolymerize at 5kPa, remove water, add 0.1kg of terephthalic acid, melt and polycondense for 10 hours, polycondensate The temperature is 160°C, the polycondensation pressure is 75Pa, the temperature is lowered, and the chloroform is dissolved to obtain a prefabricated material;
[0033] S2. Stir 10kg of polysuccinimide and 80kg of 1.8mol / L sodium hydroxide solution for 20min at a stirring temperature of 30°C, adjust the pH of the system to 4.5-5 with a concentration of 85wt% phosphoric acid solution, and add 15kg of prefabricated material Mix evenly, add 1.6 kg of ethylene glycol diglycidyl ether and react for 1 hour at a reaction temperature of 59° C., precipitate with methanol, purify, and dry in vacuum to obtain a composite aspartic acid polymer.
[0034] A soil cond...
Embodiment 3
[0037] A preparation method of composite aspartic acid polymer, comprising the steps of:
[0038] S1. Mix 2kg of lactic acid and 18kg of triethylene glycol, prepolymerize for 2.5h, prepolymerize at 142°C, prepolymerize at 3.5kPa, remove water, add 0.18kg of terephthalic acid, melt polycondensate for 6h , the polycondensation temperature is 166°C, the polycondensation pressure is 68Pa, the temperature is lowered, and the chloroform is dissolved to obtain a prefabricated material;
[0039] S2. Stir 18kg of polysuccinimide and 60kg of 2.1mol / L sodium hydroxide solution for 12min at a stirring temperature of 37°C, adjust the pH of the system to 4.5-5 with a 78wt% phosphoric acid solution, and add 22kg of prefabricated material Mix evenly, add 1.2 kg of ethylene glycol diglycidyl ether and react for 1.7 hours at a reaction temperature of 52° C., precipitate with methanol, purify, and dry in vacuum to obtain a composite aspartic acid polymer.
[0040] A soil conditioner for pear plan...
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