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A method for preparing waterborne epoxy coating used for an inner compartment of a ship

A water-based epoxy coating and ship technology, which is applied in the direction of epoxy resin coating, polyester coating, coating, etc., can solve the problems of harm to human health, insufficient adhesion, pollution of the environment, etc., to protect the environment, enhance adhesion performance, good mechanical properties

Inactive Publication Date: 2019-03-29
ANHUI KAILIN ADVANCED MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Traditional paints are mostly solvent-based, which contain a large amount of organic solvents, and often need to be diluted with organic solvents when used. These solvents evaporate into the atmosphere during construction and paint film drying, which is harmful to human health and pollutes the environment. fire hazard
With the increasingly stringent environmental protection regulations around the world, it is the general trend to develop environmentally friendly coatings to replace solvent-based coatings. At present, water-based epoxy coatings have technical problems of insufficient adhesion, which need to be solved urgently

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A method for preparing a water-based epoxy coating for an inner tank of a ship, comprising the steps of:

[0020] S1. Mix 3kg aluminum nitrate, 8kg zinc borate, 20kg polyvinyl alcohol 6000, and 150kg water evenly, add ammonia water with a concentration of 12wt% dropwise under stirring until the pH of the system is 8-8.4, stir to obtain a white milky suspension, and heat it with water React for 40 hours, the hydrothermal reaction temperature is 240°C, centrifuge, wash, dry, calcinate at 1080°C for 10 minutes, and cool to obtain material a with an average particle size of 120-180nm;

[0021] S2, 100kg bisphenol A type epoxy resin, 35kg bisphenol F type epoxy resin, 30kg epoxy alkyd resin, 1kg trimethylhexamethylenediamine were stirred for 44min, and the stirring speed was 120r / min to obtain the material b;

[0022] S3, 120kg material b, 4kg material a, 8kg nano talcum powder, 1kg vermiculite powder, 4kg diatomaceous earth, 2kg fly ash, 1.5kg zinc oxide, 1kg zinc phosphat...

Embodiment 2

[0024] A method for preparing a water-based epoxy coating for an inner tank of a ship, comprising the steps of:

[0025] S1. Mix 8kg of aluminum nitrate, 1kg of zinc borate, 28kg of polyvinyl alcohol 6000, and 50kg of water evenly, add ammonia water with a concentration of 18wt% dropwise under stirring until the pH of the system is 8-8.4, stir to obtain a white milky suspension, and heat it with water. React for 20 hours, the hydrothermal reaction temperature is 250°C, centrifuge, wash, dry, calcinate at 1000°C for 18 minutes, and cool to obtain material a with an average particle size of 120-180nm;

[0026] S2, 60kg bisphenol A type epoxy resin, 45kg bisphenol F type epoxy resin, 20kg epoxy alkyd resin, 1.8kg trimethylhexamethylenediamine were stirred for 32min, and the stirring speed was 200r / min to obtain material b;

[0027] S3, 80kg material b, 12kg material a, 2kg nano talcum powder, 4kg vermiculite powder, 1kg diatomaceous earth, 8kg fly ash, 0.2kg zinc oxide, 1.8kg zi...

Embodiment 3

[0029] A method for preparing a water-based epoxy coating for an inner tank of a ship, comprising the steps of:

[0030] S1. Mix 4kg aluminum nitrate, 6kg zinc borate, 22kg polyvinyl alcohol 6000, and 120kg water evenly, and add ammonia water with a concentration of 14wt% dropwise under stirring until the pH of the system is 8-8.4, and stir to obtain a white milky suspension. React for 35 hours, the hydrothermal reaction temperature is 242°C, centrifuge, wash, dry, calcinate at 1060°C for 12 minutes, and cool to obtain material a with an average particle size of 120-180nm;

[0031] S2, 90kg bisphenol A type epoxy resin, 38kg bisphenol F type epoxy resin, 28kg epoxy alkyd resin, 1.2kg trimethylhexamethylenediamine were stirred for 40min, and the stirring speed was 140r / min to obtain material b;

[0032] S3, 110kg material b, 6kg material a, 6kg nano talcum powder, 2kg vermiculite powder, 3kg diatomaceous earth, 4kg fly ash, 1kg zinc oxide, 1.2kg zinc phosphate, 5kg polyethylen...

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PUM

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Abstract

A method for preparing waterborne epoxy coating used for an inner compartment of a ship is disclosed. The method includes fully mixing aluminum nitrate, zinc borate, polyvinyl alcohol 6000 and water;adding ammonia water dropwise under stirring until the pH value of the system is 8-8.4; stirring the mixture to obtain a white emulsion suspension; performing a hydrothermal reaction, centrifugation,washing, drying, calcination and cooling to obtain a material a; stirring bisphenol A type epoxy resin, bisphenol F type epoxy resin, epoxy alkyd resin, and trimethylhexamethylenediamine to obtain a material b; and stirring the material b, the material a, nanometer talc powder, vermiculite powder, diatomite, fly ash, zinc oxide, zinc phosphate, polyethylene glycol, a film forming auxiliary agent,an antibacterial agent, a dispersing agent, an anti-mold agent, a defoamer, a wetting agent and water to obtain the coating.

Description

technical field [0001] The invention relates to the technical field of ship coatings, in particular to a method for preparing a water-based epoxy coating for ship inner tanks. Background technique [0002] Inner cabin paint is widely used in shipbuilding for the decoration and protection of inner cabin steel plates and soft cladding surfaces. Traditional paints are mostly solvent-based, which contain a large amount of organic solvents, and often need to be diluted with organic solvents when used. These solvents evaporate into the atmosphere during construction and paint film drying, which is harmful to human health and pollutes the environment. Fire hazard. With the increasingly stringent environmental protection regulations around the world, it is the general trend to develop environmentally friendly coatings to replace solvent-based coatings. At present, there are technical problems of insufficient adhesion of water-based epoxy coatings, which need to be solved urgently. ...

Claims

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Application Information

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IPC IPC(8): C09D163/00C09D167/08C09D7/61
CPCC08L2205/025C08L2205/035C09D7/61C09D7/70C09D163/00C08L63/00C08L67/08C08K13/04C08K7/26C08K3/34C08K3/346
Inventor 王厚国李子荣王和山王和东殷东楼殷芳荣曹文强张万霞张萍
Owner ANHUI KAILIN ADVANCED MATERIAL CO LTD
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