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Porous carbon material with high specific surface area prepared by virtue of fungal pretreatment as well as method and application thereof

A high specific surface area, porous carbon technology, applied in the field of porous carbon materials, can solve the problems of complex process conditions, secondary pollution and high cost, and achieve the effects of simple process, no secondary pollution and low production cost

Pending Publication Date: 2019-04-05
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of the present invention is simple, and can effectively solve the problems of complex process conditions, high cost, and secondary pollution in the preparation method of porous carbon materials with specific pore structures, and the obtained porous carbon materials have high specific surface area, high adsorption capacity, and strong pertinence

Method used

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  • Porous carbon material with high specific surface area prepared by virtue of fungal pretreatment as well as method and application thereof
  • Porous carbon material with high specific surface area prepared by virtue of fungal pretreatment as well as method and application thereof
  • Porous carbon material with high specific surface area prepared by virtue of fungal pretreatment as well as method and application thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0036] A method for preparing microporous high specific surface area porous carbon by treating cellulose degrading bacteria, comprising the following steps:

[0037] (1) Dilute the freeze-dried powder of Trichodermaviride 10000 times with sterilized deionized water, draw 0.2mL of the dissolved dry powder bacteria liquid with a pipette gun and inoculate it on the solid potato medium, spread it evenly, and put it into the culture medium Cultivate in the box at 30°C for 6 days; then drop sterilized deionized water into the culture plate, stir gently with an inoculation needle, and filter with gauze to obtain T.viride spore suspension, which is sealed and stored in a refrigerator at 6°C for future ;

[0038](2) cleaning lotus leaf biomass, drying at 90°C, and cutting into 0.5-1.5cm fragments to obtain pretreated raw materials;

[0039] (3) Take 200g of peeled potatoes, wash, cut into small pieces, add 1L of deionized water and boil for 30min to obtain the filtrate; make up the fi...

Embodiment 2

[0045] The method for preparing mesoporous high specific surface area porous carbon by processing lignin degrading bacteria comprises the following steps:

[0046] (1) Dilute the freeze-dried powder of Phanerochaetechrysosporium chrysosporium 10000 times with sterilized deionized water, draw 0.2mL of the dissolved dry powder bacteria liquid with a pipette gun and inoculate it on the PDA medium, spread it evenly, and put it in Cultivate in an incubator at 30°C for 6 days; then drop sterilized deionized water into the culture plate, gently stir it with an inoculation needle, and filter it with gauze to obtain a spore suspension of Phanerochaete chrysosporium, that is, a suspension of P. liquid, sealed and stored in a refrigerator at 6°C, and set aside;

[0047] (2) cleaning lotus leaf biomass, drying at 90°C, and cutting into 0.5-1.5cm fragments to obtain pretreated raw materials;

[0048] (3) Take 200g of peeled potatoes, wash, cut into small pieces, add 1L of deionized water ...

Embodiment 3

[0054] A method for preparing a micro-mesoporous high specific surface area porous carbon material by treating hemicellulose degrading bacteria, comprising the following steps:

[0055] (1) Dilute the freeze-dried powder of Aspergillus tubingensis 10000 times with sterilized deionized water, draw 0.4mL of the dissolved dry powder bacteria liquid with a pipette gun and inoculate it on the Chapeau agar medium, spread it evenly, and put it into the culture medium Cultivate in the box at 30°C for 6 days, then drop sterilized deionized water into the cultured plate, gently stir with an inoculation needle, and filter with gauze to obtain A. tubingensis spore suspension, which is sealed and stored in a 6°C refrigerator for later ;

[0056] (2) cleaning lotus leaf biomass, drying at 90°C, and cutting into 0.5-1.5cm fragments to obtain pretreated raw materials;

[0057] (3) Take 30g of Cha's liquid medium and add it to 1L of deionized water, dissolve, sterilize, cool to room temperatu...

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Abstract

The invention belongs to the technical field of preparation of porous carbon materials, and discloses a porous carbon material with a high specific surface area by virtue of fungal pretreatment as well as a method and application thereof. The method comprises the following steps: (1) drying and crushing waste biomass to obtain crushed waste biomass; 2) carrying out the constant-temperature oscillation reaction for the crushed waste biomass and fungal spore suspension in a liquid culture medium, filtering, washing, and drying to obtain a carbonization precursor; carrying out the high-temperature carbonization treatment to obtain a primary carbonized substance; and 3) activating the primary carbonized substance and an activator in inert atmosphere to obtain the porous carbon material with ahigh specific surface area. According to the invention, the porous carbon material is prepared by virtue of the regulation of fungal treatment, so that the waste biomass is effectively utilized, the preparation process is simple, the production cost is low, and the method is environment-friendly; and the obtained porous carbon material is high in specific surface area and unique in aperture distribution and capable of obtaining micro-porous, mesoporous or micro-mesoporous carbon materials. The porous carbon material is applied to the field of adsorption.

Description

technical field [0001] The invention belongs to the technical field of porous carbon materials, and in particular relates to a carbon material with a high specific surface area and a method for preparing a specific pore structure (microporous, mesoporous or micro-mesoporous) by fungal pretreatment and its application in the field of adsorption. in the application. Background technique [0002] with O 3 Extreme air pollution such as photochemical smog pollution and haze caused by PM2.5 have seriously affected the quality of the air environment and human health. Volatile organic compounds (VOCs) as O 3 It is one of the key precursors for the formation of PM2.5 and its effective control and reduction is crucial to improving air quality. At present, the adsorption technology using common porous carbon materials as adsorbents has been widely used in the adsorption of VOCs due to its advantages of low cost and wide adaptability. However, such adsorbents have problems such as l...

Claims

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Application Information

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IPC IPC(8): C01B32/324C01B32/348B01D53/02
CPCB01D53/02C01B32/324C01B32/348B01D2257/70
Inventor 黄皓旻张伟霞成海荣叶代启
Owner SOUTH CHINA UNIV OF TECH
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