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A kind of sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalytic material and its preparation method and application

A technology of nano-catalytic material and hollow structure, which is applied in the preparation of amino compounds, chemical instruments and methods, and the preparation of organic compounds. It can solve the problems of low copper and nickel selenide, and achieve good catalytic hydrogenation performance.

Active Publication Date: 2021-11-26
ANHUI NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Both copper selenide and nickel selenide have excellent properties in light, electricity, catalysis, and medical treatment, but there are relatively few reports on the preparation and application of copper nickel selenide

Method used

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  • A kind of sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalytic material and its preparation method and application
  • A kind of sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalytic material and its preparation method and application
  • A kind of sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalytic material and its preparation method and application

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Embodiment 1

[0036] A nickel-copper-selenide ternary nano-catalysis material with a sea urchin-shaped hollow structure has a sea urchin-shaped hollow structure, and the diameter of the nickel-copper-selenium ternary nano-material with the structure is 400-600 nanometers.

[0037] A method for preparing a sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalyst material, the steps comprising:

[0038] A. Prepare the precursor of the sea urchin-shaped hollow structure nickel-copper-selenium ternary nanocatalytic material by solvothermal method: at room temperature, dissolve 2.4g copper nitrate trihydrate and 2.9g nickel nitrate hexahydrate in 200ml water and 100ml ethylene glycol Add 6.0g urea and 5.0g polyvinylpyrrolidone (K:30) to the mixed solution, stir and mix well, place in a 500ml polytetrafluoroethylene reactor lining, then place the polytetrafluoroethylene reactor lining Put it into a steel sleeve and tighten it, react at 80°C for 10 hours, naturally cool to r...

Embodiment 2

[0041] A nickel-copper-selenide ternary nano-catalysis material with a sea urchin-shaped hollow structure has a sea urchin-shaped hollow structure, and the diameter of the nickel-copper-selenium ternary nano-material with the structure is 200-600 nanometers.

[0042] A method for preparing a sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalyst material, the steps comprising:

[0043] A. Prepare the precursor of the sea urchin-shaped hollow structure nickel-copper-selenide ternary nanocatalytic material by solvothermal method: at room temperature, dissolve 2.9g copper nitrate trihydrate and 3.5g nickel nitrate hexahydrate in 150ml water and 150ml ethylene glycol Add 6.0g urea and 12.0g polyvinylpyrrolidone (K:60) to the mixed solution, stir and mix well, place in a 500ml polytetrafluoroethylene reactor lining, then place the polytetrafluoroethylene reactor lining Put it into a steel sleeve and tighten it, react at 70°C for 18 hours, naturally cool to ...

Embodiment 3

[0046] A nickel-copper-selenide ternary nano-catalysis material with a sea urchin-shaped hollow structure has a sea urchin-shaped hollow structure, and the diameter of the nickel-copper-selenium ternary nano-material with the structure is 200-600 nanometers.

[0047] A method for preparing a sea urchin-shaped hollow structure nickel-copper-selenium ternary nano-catalyst material, the steps comprising:

[0048] A. Prepare the precursor of the sea urchin-shaped hollow structure nickel-copper-selenide ternary nanocatalytic material by solvothermal method: at room temperature, dissolve 2.4g copper nitrate trihydrate and 2.9g nickel nitrate hexahydrate in 60ml water and 240ml ethylene glycol Add 6.0g of urea and 3.0g of polyvinylpyrrolidone (K:25) to the mixed solution, stir and mix evenly, place in a 500ml polytetrafluoroethylene reactor lining, then place the polytetrafluoroethylene reactor lining Put it into a steel sleeve and tighten it, react at 100°C for 6 hours, naturally co...

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Abstract

The invention provides a nickel-copper-selenium ternary nano-catalytic material with a sea urchin-like hollow structure and its preparation method and application. In the invention, copper nitrate trihydrate and nickel nitrate hexahydrate are dissolved in a mixed solvent of ethylene glycol and water, and then added Urea and polyvinylpyrrolidone react hydrothermally to form a hollow sea urchin-like precursor structure. Disperse the precursor in deionized water, add the sodium hydrogen selenide solution dropwise into the precursor dispersion, use the precursor as a template, and perform hydrothermal reaction to obtain a nickel-copper-selenide ternary nanocatalytic material with a sea urchin-like hollow structure . Compared with the prior art, the present invention successfully prepared the sea urchin-shaped hollow structure nickel-copper-selenium ternary nanomaterial for the first time through mild reaction conditions and a simple and easy-to-promote method. The sea urchin-shaped nickel-copper-selenide ternary The nanometer material can catalyze the hydrogenation reaction of p-nitrophenol, p-nitrostyrene and p-nitroaniline, and the material has good catalytic hydrogenation performance.

Description

technical field [0001] The invention belongs to the technical field of new material preparation, and relates to a preparation method and application field of micro-nano materials, in particular to a nickel-copper-selenide ternary nano-catalysis material with a sea urchin-shaped hollow structure and a preparation method and application thereof. Background technique [0002] Copper selenide is a very important metal chalcogenide compound, which is widely used in degradation dyes, light-emitting diodes, photocatalysts and electrochemical cells. In addition, copper selenide is also used in thermoelectric devices, nonlinear optics, etc. Materials, light-emitting and display devices, infrared detectors, lasers, and photothermal therapy have good application prospects. Zou Hong Yan and Huang Cheng Zhi (ACS Sustainable Chem.Eng., 2017, 5(5), pp 4154–4160) prepared dendritic copper selenide with side branches with good adsorption and photocatalytic ability. Li Can (J.Phys.Chem.C 201...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/057B01J35/02C07C213/02C07C215/76C07C209/36C07C211/45C07C211/51B01J35/00
CPCC07C209/36C07C213/02B01J27/0573B01J35/40C07C215/76C07C211/45C07C211/51
Inventor 余锐吴孔林魏先文蔡亚苗刘坤
Owner ANHUI NORMAL UNIV
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