40 results about "Copper selenide" patented technology

The invention relates to a modified current collector for a cathode-free metal battery and a preparation method and application thereof.The preparation method comprises the steps that an in-situ modification reaction is conducted on the surface of a copper current collector to obtain a current collector coated with a copper oxide nanometer material, and then selenium is introduced to the surface of the current collector coated with the copper oxide nanometer material through a partial in-situ substitution reaction to obtain the modified current collector coated with the copper oxide nanometer material. The preparation method comprises the following steps: preparing a copper selenide and copper oxide composite modified current collector, performing in-situ lithiation reaction through electrochemical deposition, and partially converting to generate corresponding lithiates, thereby obtaining the modified current collector for the non-anode metal battery. According to the invention, the functional artificial interface layer with lithium affinity, high stability and high ionic conductivity is constructed on the surface of the copper-based current collector in situ, so that the key problems of uneven metal deposition and unstable SEI layer on the surface of the negative electrode current collector in the current research of the metal secondary battery without the negative electrode are solved, the formation of dendritic crystals and the occurrence of side reactions are inhibited, and the service life of the metal secondary battery is prolonged. Therefore, the coulombic efficiency, the safety and the cycle life of the battery are improved.

The invention discloses copper selenide / tricalcium silicate bone cement. The bone cement comprises a liquid phase component and a solid phase component, the liquid phase component is water, and the solid phase component is tricalcium silicate powder and copper selenide nanoparticles. Compared with the existing tricalcium silicate bone cement, the tricalcium silicate bone cement has the advantages that by introducing a trace amount of copper selenide nanoparticles, not only can the hydration and coagulation time of tricalcium silicate be shortened, but also the porosity and degradation rate of the tricalcium silicate after coagulation and solidification can be reduced, the compressive strength can be improved, the stimulation effect on ALP activity of MC3T3-E1 cells can be enhanced, the survival rate of the MC3T3-E1 cells can be improved, and the application prospect is broad. The immunogenic apoptosis of K7M2-wt cells is promoted, and the tumor growth rate is reduced. Besides, the introduction of the copper selenide nanoparticles can also endow the tricalcium silicate bone cement with the performance of temperature rise under near-infrared light, so that in clinical application, the tricalcium silicate bone cement can be further combined with a near-infrared technology to realize ablation of bone tumors, and a new strategy is provided for treatment of the bone tumors.

The invention provides a slow saturable absorber, a preparation method of a mixed mode locking structure and a pulse laser, and the preparation method of the slow saturable absorber comprises the steps: adding selenium powder, sodium hydroxide and copper nitrate trihydrate into deionized water according to a first preset proportion, and obtaining a colloidal suspension; transferring the colloidal turbid liquid into a stainless steel high-pressure kettle for reaction to obtain copper selenide nanosheets; washing the copper selenide nanosheet by using alcohol; and depositing the washed copper selenide nanosheet on a D-type optical fiber, and coupling a laser to the D-type optical fiber in the deposition process to obtain the slow saturable absorber. According to the scheme, the problems that an existing real saturable absorber is low in anti-damage threshold value, mode-locked laser achieved based on the existing real saturable absorber is low in output power and poor in stability and long-term operation stability are solved, and the problems that an existing artificial saturable absorber is difficult to self-start, low in modulation depth and sensitive to polarization are solved.

The application provides a copper selenide-halloysite-mannose composite drug delivery system, which comprises a carrier, the carrier is halloysite nanotubes (HNTs), copper selenide nanoparticles (CuSe) are in situ grown on the tube wall of the halloysite nanotubes to form a composite CuSe@HNTs; and mannose is loaded in the lumen of the CuSe@HNTs to form a composite drug delivery system CuSe@HNTs@ME. The application also provides a preparation method and application of the copper selenide-halloysite-mannose composite drug delivery system. The drug delivery system can maintain stability in a gastric acid environment, directly reaches an intestinal inflammation site through an oral route, and significantly reduces intestinal inflammation symptoms.

This invention belongs to the field of composite electrode materials technology, and relates to a method for preparing a NiCoCu selenide composite MXene / carbon sphere thin film electrode material, comprising: first, dissolving ZIF-67 powder in a carbon sphere solution, then adding an MXene aqueous solution, stirring for 1-10 hours, filtering and drying to obtain ZIF-67@MXene / CS; second, preparing a solution according to the proportion of urea, copper source, nickel source and ethanol, immersing ZIF-67@MXene / CS, and reacting hydrothermally to obtain a NiCoCu-LDH@MXene / CS thin film; third, mixing the NiCoCu-LDH@MXene / CS thin film, selenium powder and sodium borohydride in a mass ratio of 0.5-1:1-2:1-2, reacting at 150-180°C for 12-24 hours, washing the obtained product with deionized water and drying to obtain the final product. MXene and carbon spheres together provide a flexible substrate for the self-supporting material, increasing its conductivity and specific surface area. Simultaneously, NiCoCu-Se intercalation into the MXene acts as an intermediate buffer, preventing MXene self-stabilization and making its structure more stable. When applied as the positive electrode material for supercapacitors, the self-supporting material avoids the use of binders, reducing the material's impedance and improving electrochemical performance.

The present invention relates to a copper-iron selenide / carbon-nitrogen composite carbon nanotube negative electrode material, its preparation method, negative electrode plate, and lithium battery. These materials belong to the technical field of electrode materials and address the problem of poor cycle and rate performance in prior art bimetallic selenide negative electrode materials due to severe volume expansion. The negative electrode material comprises carbon nanotubes and cubic secondary particles composed of copper-iron selenide primary particles; the copper-iron selenide primary particles are carbon-coated particles doped with nitrogen; the copper selenide and iron selenide in the copper-iron selenide primary particles form a heterogeneous structure; and the carbon nanotubes penetrate the cubic secondary particles to connect adjacent cubic secondary particles. This negative electrode material exhibits excellent cycle performance, rate performance, and electrical conductivity.

The invention belongs to the field of micro-nano motors, and provides a cell membrane camouflage light-driven nano motor and a preparation method and application thereof. The nano-motor Cu < 2-x > Se-PMO is composed of near-infrared light response copper selenide Cu < 2-x > Se nano-particles and periodic mesoporous organosilicon PMO nano-spheres, and the drug-loaded nano-motor and the cell membrane nano-vesicles are mixed and jointly pass through a microporous filter membrane to obtain the cell membrane disguise nano-motor CM (at) Cu < 2-x > Se-PMO. The nano-motor can actively find a target disease site, the cell membrane camouflage light-driven nano-motor can improve the efficiency and targeting property of drug transportation, and the preparation method has the characteristics of high loading rate, high targeting property, low cost and the like.

The invention provides a copper selenide-halloysite-mannose composite drug delivery system which comprises a carrier, the carrier is halloysite nanotubes (HNTs), copper selenide nanoparticles (CuSe) grow on the tube wall of the halloysite nanotubes in situ, and a compound CuSe-coated HNTs is formed; mannose is loaded in a tube cavity of the CuSe-coated HNTs, so that a composite drug delivery system CuSe-coated HNTs-coated ME is formed. The invention further provides a preparation method and application of the copper selenide-halloysite-mannose composite drug delivery system. The drug delivery system can keep stable in a gastric acid environment and directly reach an enteritis part through an oral administration way, so that the enteritis symptom is remarkably relieved.

This invention discloses a cerium copper selenide (CCuSe2) compound thin film, its preparation method, and its applications. The preparation method includes: S1, mixing a copper source and a cerium source to obtain a cerium copper powder mixture; S2, adding thioglycolic acid and ethanolamine to the cerium copper powder mixture, heating and stirring until the cerium copper powder mixture is completely dissolved to obtain a mixed solution; S3, cooling the mixed solution to room temperature, adding a selenium source to the mixed solution, heating and stirring, reacting until the selenium source is completely dissolved, centrifuging, and obtaining the supernatant as the cerium copper selenide precursor solution; S4, spin-coating and sintering the cerium copper selenide precursor solution to obtain a cerium copper selenide pre-film; S5, subjecting the cerium copper selenide pre-film to high-temperature annealing, and cooling to obtain a cerium copper selenide thin film. This invention marks the first experimental synthesis of the CeCuSe2 compound, which matches the theoretically calculated CeCuSe2 crystal structure. The optical and electrical properties of CeCuSe2 materials were also investigated, confirming that cerium copper selenide thin films can be applied to solar cells and photocatalysis.

The invention belongs to the technical field of photoelectric thin film materials, and particularly relates to a full-spectrum transparent conductive thin film material and a preparation method thereof.The thin film material is of a quasi-continuous homologous nanocrystalline enhanced amorphous composite structure and specifically comprises a transparent substrate serving as an amorphous phase, the chemical component of an amorphous area of the transparent substrate is CuSe < 1 + x >, x is 0.8-1, and the chemical component of the transparent substrate is CuSe < 1 + x >, the components of the whole amorphous region are uniform and present an amorphous structure; the invention relates to a copper-based composite material which is characterized in that the copper-based composite material serves as a conductive reinforcing phase of a crystal phase, a crystal region of the conductive reinforcing phase is composed of nanocrystal grains with a space group of Fm-3m, the chemical component of the nanocrystal grains is CuSe (1-y), and y is equal to 0.4-0.6. According to the invention, a copper selenide material is used as a conductive material, so that the material has good transmissivity in a full spectrum and has the characteristic of high conductivity; the quasi-continuous homologous nanocrystalline composite film is formed by carrying out magnetron sputtering, thermal annealing and other post-treatment methods on a copper selenide target material, and integration of full-wave band transparency and conductivity is achieved.

The application discloses a one-dimensional carbon-coated copper selenide nanowire coaxial heterostructure material, a preparation method and application thereof. The preparation method comprises the following steps: adopting a vacuum chemical vapor transport method to heat and decompose copper acetylacetonate under a sealed condition to form a carbon-coated copper nanowire material, and then performing annealing treatment to obtain a one-dimensional carbon-coated copper nanowire material; and adopting a chemical vapor deposition method to perform selenization on the one-dimensional carbon-coated copper nanowire material by using a selenium source to obtain a one-dimensional carbon-coated copper selenide nanowire coaxial heterostructure material. The one-dimensional carbon-coated copper selenide nanowire coaxial heterostructure material is synthesized by using a vacuum chemical vapor transport and secondary selenization method, and the preparation efficiency is improved. Meanwhile, the one-dimensional structure of the one-dimensional carbon-coated copper selenide nanowire material has a relatively high specific surface area, and the external carbon layer improves the electronic conductivity and stability of the copper selenide, and the one-dimensional carbon-coated copper selenide nanowire material has a relatively high charge and discharge specific capacity.

Provided in the present invention is a composite copper selenide-halloysite-mannose drug delivery system. The drug delivery system comprises a carrier, wherein the carrier is halloysite nanotubes (HNTs), copper selenide (CuSe) nanoparticles are grown in situ on the walls of the halloysite nanotubes to form composite CuSe@HNTs, and mannose is loaded in the lumen of CuSe-coated HNTs to form composite drug delivery system CuSe@HNTs@ME. Further provided in the present invention are a method for preparing the composite copper selenide-halloysite-mannose drug delivery system, and the use thereof. The drug delivery system of the present invention can remain stable in a gastric acid environment and directly reach the site of enteritis by means of oral administration, thereby significantly alleviating the symptoms of enteritis.

The application discloses a selenium-based functional composite material and a preparation method and application thereof, and belongs to the technical field of functional materials. The selenium-based functional composite material is a core-shell structure, the shell layer of the core-shell structure is carbon, and the selenium-based functional composite material is coated with copper selenide. The selenium-based functional composite material prepared by the application can be used as an electromagnetic wave absorber, and has excellent electromagnetic wave absorption performance. The maximum reflection loss value can reach -74 dB, and the frequency band width with a reflection loss value less than -10 dB can reach 5.5 GHz.

The invention discloses a selenium copper compound as well as a preparation method and application thereof. The preparation process of the selenium copper compound comprises the following steps: dissolving selenium powder in an alkaline solution under a heating condition, then adding a reducing agent, then carrying out a co-precipitation reaction with a mixed solution containing copper salt and a surfactant, and filtering, washing and drying a reaction product to obtain the selenium copper compound, or dissolving raw materials including copper salt in an alkaline solution, then adding a reducing agent to carry out precipitation reaction, filtering, washing and drying a reaction product to obtain orange red powder, and co-roasting the orange red powder and selenium powder to obtain the selenium-rich copper oxide. Compared with a common chalcogenide, the selenium copper compound has higher conductivity, also has multiple crystal structures, and endows the material with higher electrocatalytic activity and stability. Tests show that the energy efficiency of the flow battery adopting the selenium-copper compound modified negative electrode can reach about 80% under the current density of 80mA / cm < 2 >, and the energy storage performance of the flow battery is greatly improved.

The invention relates to a preparation method of a copper selenide and nickel core-shell heterostructure nano array. The preparation method comprises the following steps: (1) preparing copper hydroxide on the surface of a copper net by an anodic oxidation method; (2) putting two pieces of Cu (OH) 2 / CF into a tubular furnace, heating a certain amount of selenium powder, sealing the tubular furnace, continuously introducing argon at the flow rate of 20ml min <-1 >, heating to 400 DEG C, and preserving heat for 60 minutes to obtain a Cu < 2-x > Se-CF nano array; and (3) immersing a piece of Cu2-xSe-coated CF into a solution containing 0.1 M of nickel chloride and 0.1 M of ammonium chloride, taking copper selenide as a working electrode, taking a carbon rod as a counter electrode, and continuing for 15 minutes under the voltage of-1V vs Ag / AgCl to obtain the Ni-coated Cu2-xSe-coated CF nano array. The method provided by the invention is simple, and the core-shell heterostructure nano array of copper selenide and nickel maintains better morphology, and has good performance when being used as an electrocatalyst for ammonia production through nitrate reduction.

The application discloses a modified manganese iron lithium phosphate positive electrode material, a positive electrode sheet, a battery and a preparation method. The modified manganese iron lithium phosphate positive electrode material comprises a manganese iron lithium phosphate base body, a carbon coating layer coated on the surface of the manganese iron lithium phosphate base body and a selenide coating layer coated on the surface of the carbon coating layer. The selenide is selected from a mixture of one or more of copper selenide, cadmium selenide, indium selenide, lead selenide and antimony selenide. The problems of low conductivity, low discharge capacity, poor rate performance, poor cycle retention rate and high manganese dissolution rate of the existing manganese iron lithium phosphate positive electrode material are solved.

The present application relates to a kind of graphene nanobelt / copper selenide semiconductor heterostructure and its preparation method, belong to nanometer material technical field.The present application utilizes the strategy that intermolecular carbon hydrogen activation and intramolecular cyclization dehydrogenation will occur under the catalysis of four anthracene precursor in copper substrate, four anthracene precursor molecule is deposited on copper surface, and is kept at 100 ℃-400 ℃ temperature for 30 minutes to obtain one-dimensional graphene nanobelt.Then, the strategy that single-layer copper selenide semiconductor is generated by the chemical reaction of selenium powder and copper substrate is used, by depositing selenium powder on the above graphene nanobelt and copper substrate, and keeping at 100 ℃-400 ℃ temperature for 30 minutes, to obtain graphene nanobelt / copper selenide semiconductor heterostructure.

The invention discloses a vaginal cancer intelligent targeting nano-tablet based on multistage self-assembly biomimetic mineralization and a preparation method thereof, the vaginal cancer intelligent targeting nano-tablet comprises: an inner core, which is a co-inlay of a drug-loaded metal organic framework (MOF) and a liposome; and high drug loading and synergistic treatment are realized. The middle layer is a mesoporous silica and copper selenide hybrid shell layer formed by biomimetic mineralization; the material is used as a gating and photo-thermal medium. And long-acting circulation and precise targeting are realized. And the outer layer is a cancer cell membrane camouflage layer modified by double ligands of folic acid and hyaluronic acid. And an intelligent nano system with a'core-shell-crown 'three-layer structure is formed. The method has the advantages of complex process, high technical barrier and difficulty in reverse engineering; multiple synergistic effects of chemotherapy, photothermal therapy and immunoregulation are achieved; a triple targeting mechanism: passive targeting, active targeting and homologous targeting; quadruple response release: pH, GSH, enzyme and photo-thermal response; the stability and the biological safety are good.

The invention discloses a biosensor based on octahedral CuSe nano-enzyme and a sandwich aptamer and a preparation method and application thereof.The biosensor comprises a biological cathode and a biological anode, and the biological cathode and the biological anode both comprise carbon cloth and a composite material loaded on the carbon cloth; the composite material comprises a copper selenide inner core and a gold nanoparticle shell coated outside the copper selenide inner core, bilirubin oxidase is fixed on the surface of the composite material of the biological cathode; a first lysozyme aptamer modified by sulfydryl, 6-sulfydryl-1-hexanol and a second lysozyme aptamer modified by glucose oxidase are sequentially modified on the surface of a composite material of the biological anode, and biochemical energy is directly converted through an enzyme biological fuel cell due to the unique self-energy-supply design; according to the method, the energy supply-detection-inactivation integrated design is achieved, the preparation method is easy to operate, low in cost, rapid and convenient, large-scale production can be achieved, and a portable and economical innovative platform is provided for clinical lysozyme detection.

The invention discloses a superlattice copper selenide composite material based on small organic molecules as well as preparation and application of the superlattice copper selenide composite material, and belongs to the technical field of new materials and electrochemistry. Aliphatic amine organic micromolecules such as diethylenetriamine are used as morphology regulation and superlattice intercalation molecules, sodium selenite and copper ions in a precursor solution are reduced by hydrated electrons generated by water radiolysis, and the superlattice copper selenide composite material based on the organic micromolecules is synthesized. The composite material is of a nanosheet structure, has excellent conductivity and reversible zinc storage capacity, and shows excellent rate capability and cycling stability when being used as an electrode material of an aqueous zinc ion battery. And the one-step radiation reduction preparation method is mild in condition, flexible and controllable, low in energy consumption and small in environmental pollution, and is beneficial to the design of atomic-scale defects and weakening the damage to the structure and morphology of the copper selenide in the preparation process.

A hot-dip galvanized coating for iron casting materials and its hot-dip galvanizing method are disclosed. The coating comprises the following raw materials in parts by weight: Mg: 4-6 parts; Al: 3-5 parts; Pb: 6-8 parts; Zn: 90-95 parts; copper selenide: 0.5-1 parts. This application utilizes a typical Mg-Al-Zn system, adding Pb and copper selenide to improve the fluidity of various materials in the galvanizing bath, adapting to the uneven surface of the iron casting material, thereby ensuring its corrosion resistance.

The present invention provides a hollow copper selenide box, a preparation method thereof and an application thereof, belonging to the field of wireless communication technology. The present invention uses a Cu2O cube as a sacrificial template, and through a template-directed in-situ selenization reaction, the Cu2O microcube is successfully converted into Cu 2‑x Se microcube box at room temperature by a wet chemical method. The present invention realizes the construction of a self-supporting microcube-structured hollow Cu 2‑x Se heteroselenium copper box under the synergistic effect of the Kirkendall effect and the Ostwald ripening effect, and has rare low-frequency electromagnetic wave absorption performance. The composite product of the hollow copper selenide box prepared by the present invention and paraffin has good low-frequency electromagnetic wave absorption characteristics (from 4 GHz) when the filling amount is 40 wt%, and the minimum RL value of T5 / paraffin-40 wt% exceeds -20 dB at 2.6 mm - 5.0 mm.

The invention relates to an egg shell structure cuprous selenide-selenium doped carbon composite material and a preparation method thereof, and belongs to the technical field of nano functional materials. The preparation method comprises the following steps: by taking commercial copper powder and asphalt as raw materials, firstly coating the commercial copper powder with the asphalt, and then carrying out high-temperature carbonization on a copper-asphalt precursor to obtain a copper-carbon intermediate; the preparation method comprises the following steps: preparing a copper-carbon intermediate, partially etching the copper-carbon intermediate to obtain an egg-shell structure copper-carbon intermediate, and finally performing hydrothermal selenylation to simultaneously realize selenium doping of asphalt derived carbon and confined growth of copper selenide particles to obtain the egg-shell structure cuprous selenide-selenium doped carbon composite material. The preparation method is simple, the morphology structure of the material is controllable, and the method can be used for large-scale production. In the obtained cuprous selenide-selenium-doped carbon composite material with the egg shell structure, a large cavity exists between cuprous selenide particles and a selenium-doped carbon shell, selenium-doped carbon has electronegativity and has a strong adsorption effect on positive ions, and the composite material has potential application prospects in the fields of metal secondary batteries, electrochemical capacitors and the like.

The invention discloses an in-situ composite BiCuSeO-based thermoelectric material and a preparation method thereof, and belongs to the technical field of new energy conversion. The preparation method comprises the following steps: weighing Bi2O3, Bi, Cu, Se and PbO high-purity powder raw materials according to the stoichiometric ratio of BiCu0. 95PbxSe1 + xO (x is greater than 0 and less than or equal to 0.03) by adopting a solid-phase synthesis combined vacuum hot-pressing sintering process, grinding and uniformly mixing, packaging into a quartz tube in vacuum for carrying out high-temperature solid-phase synthesis reaction, grinding an obtained ingot product into powder, filling into a graphite mold, and carrying out vacuum hot-pressing sintering to obtain a high-density block, and the in-situ composite type BiCuSeO-based thermoelectric material is obtained. According to the in-situ composite BiCuSeO-based thermoelectric material prepared by the invention, PbSe can be generated in situ in a matrix, so that the carrier concentration and mobility are effectively improved, and the conductivity and the power factor are optimized; and meanwhile, the in-situ composite PbSe also enables the thermal conductivity to be maintained, so that the final thermoelectric performance is improved. The invention provides a good method for in-situ compounding and performance optimization of the thermoelectric material.

The invention belongs to the technical field of heavy metal adsorption materials, and discloses application of sodium alginate-copper selenide in heavy metal ion adsorption. The sodium alginate-copper selenide is prepared by adopting sodium alginate as a template, reducing Na2SeO3 through Vc and adding CuSO4. The sodium alginate-copper selenide has a certain adsorption effect on three heavy metal ions of Pb < 2 + >, Cr < 3 + > and Cd < 2 + >, has the strongest removal effect on the Pb < 2 + > ions, has the removal rate up to 41.3%, and has a very good application prospect in the aspect of environmental protection.

The invention relates to a magnesium battery electrolyte for constructing a negative electrode rich in an inorganic interface and a preparation method. A solute is an electrolyte magnesium salt, a solvent is an organic ether compound, and additives are aniline and piperazine organic compounds; the optimization of the solvated structure not only enhances the migration and diffusion capability of magnesium ions, but also greatly improves the coulombic efficiency, has super-long cycle stability, has high compatibility with a copper selenide positive electrode, remarkably improves the oxidation-reduction stability of an electrolyte system, and is suitable for large-scale production. And a key material basis is provided for constructing a magnesium ion battery with high energy density and long cycle life.

The invention relates to a preparation method of copper selenide / polydopamine / new indocyanine green composite nanoparticles, which comprises the following steps: 1) mixing Se powder, NaBH4 and deionized water to react for 3-5 hours in a room-temperature inert gas atmosphere to obtain a solution A; cuCl2.H2O and PVP are uniformly dispersed in deionized water, a NaOH solution is added for a reaction for 3-8 min, an ascorbic acid solution is added for a reaction for 3-8 min, then a solution A is added for a reaction for 15-30 min, centrifugation and washing are performed, and hollow Cu2-xSe is obtained; and 2) dispersing the hollow Cu2-xSe in a Tris buffer solution, then adding dopamine hydrochloride and IR820, shaking in a dark place at room temperature for 1.5-3 hours, centrifuging and washing to obtain the hollow Cu2-xSe composite nanoparticle. The hollow Cu2-xSe composite nanoparticle can play a good effect in the aspect of tumor treatment.

This invention relates to a single-layer Cu 2 / 3 Na 1 / 3 This paper describes a method for preparing copper (Se) materials, belonging to the field of nanomaterials technology. The method involves preparing a copper single-crystal substrate; evaporating and depositing selenium powder onto the copper single-crystal substrate to obtain the substrate and a copper-selenium compound deposited on it, controlling the temperature of the copper-selenium compound and the copper single-crystal substrate at 25–30°C during the deposition process; heating the substrate and the deposited copper-selenium compound to the growth temperature and holding them thereafter; then evaporating and depositing elemental sodium onto the substrate and the copper-selenium deposit to obtain a sodium-doped copper selenide deposit and the substrate, controlling the temperature of the substrate and the deposit at 25–30°C during the deposition process; and finally, holding the obtained sodium-doped copper selenide deposit and the substrate at room temperature to obtain a large-area monolayer of Cu. 2 / 3 Na 1 / 3Se material. The large-area monolayer Cu prepared by this invention... 2 / 3Na 1 / 3 Se materials have a two-dimensional network structure with an area greater than 250 square nanometers and uniformly oriented atoms.

The invention discloses a cerium-copper-selenium compound film and a preparation method and application thereof.The preparation method comprises the steps that S1, a copper source and a cerium source are mixed, and a cerium-copper powder mixture is obtained; s2, thioglycollic acid and ethanolamine are added into the cerium-copper powder mixture, heating and stirring are conducted till the cerium-copper powder mixture is completely dissolved, and a mixed solution is obtained; s3, cooling the mixed solution to room temperature, adding a selenium source into the mixed solution, heating and stirring, reacting until the selenium source is completely dissolved, and centrifuging to obtain supernate, namely a cerium-copper-selenium precursor solution; s4, spin-coating and sintering the cerium-copper-selenium precursor solution to obtain a cerium-copper-selenium prefabricated film; and S5, performing high-temperature annealing on the cerium-copper-selenium prefabricated film, and cooling to obtain the cerium-copper-selenium film. A CeCuSe2 compound is synthesized on an experiment for the first time, the CeCuSe2 compound is matched with a CeCuSe2 crystal structure calculated theoretically, meanwhile, the properties of a CeCuSe2 material in the aspects of optics and electricity are explored, and it is proved that the cerium-copper-selenium film can be applied to the fields of solar cells and photocatalysis.

The invention relates to an impurity removal agent for deeply removing silver from an electrolyte prepared from high-purity copper, application of the impurity removal agent and a method for deeply removing silver from the electrolyte, and belongs to the technical field of metallurgical engineering. The impurity removal agent is a copper selenide, a copper telluride or a mixture of the copper selenide and the copper telluride. The silver removal method comprises the following steps: adding the impurity removal agent into the electrolyte according to the ratio of the total molar weight of selenium and tellurium to the molar weight of silver being (1: 1)-(500: 1), reacting for 1-6 hours under the conditions of 25-95 DEG C and 400-800 rpm, standing, and sequentially separating through filter cloth (20-38 microns) and a fine filter (0.1-10 microns) to obtain a purified solution. According to the method, the silver content of the electrolyte can be deeply removed to 0.01 mg / L or below, new metal impurities are not introduced, the process is simple and efficient, and the method is suitable for industrial purification production of a copper sulfate or copper nitrate system.