Technology for repairing holes and cracks on surface of carbon fiber by using graphene films

A technology of graphene film and surface holes, which is applied in carbon fiber, fiber treatment, textiles and papermaking, etc., can solve the problems of intertwining and forming clusters, affecting the spraying effect, etc., and achieve high tensile strength, low cost and simple process Effect

Active Publication Date: 2019-05-17
XI AN JIAOTONG UNIV
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Problems solved by technology

Cheng Bowen etc. adopt a method of electrostatically spraying carbon nanotubes to enhance the strength of carbon fibers in Chinese patent application numbers 201010211436.7, 201010211437.1, 201010122410.2, etc. The method is simple in process and the strength of carbon fibers is increased by 100%. However, due to the length range of carbon nanotubes in Between a few microns and tens of microns, which is much higher than the size of carbon fiber surface structure defects (about tens to hundreds of nanometers), thus restricting the entry of carbon nanotubes into carbon fiber surface structure defects during electrospraying (radial injection ) format, so that most of the carbon nanotubes are covered on the surface of the carbon fiber; in addition, due to the relatively large length of the carbon nanotubes, the carbon nanotubes are easy to entangle with each other during the electrostatic spraying process, which affects the spraying effect

Method used

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  • Technology for repairing holes and cracks on surface of carbon fiber by using graphene films
  • Technology for repairing holes and cracks on surface of carbon fiber by using graphene films

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Embodiment 1

[0022] Embodiment 1, a kind of technique of graphene film repairing carbon fiber surface hole and crackle, comprises the following steps:

[0023] 1) Carbon fiber surface treatment: use domestic unglued carbon fiber for the test, the specification of carbon fiber is 3K, and the diameter of single fiber is 7.2 microns; the carbon fiber is soaked in the nitric acid aqueous solution with a concentration of 10mol / L, the weight of the nitric acid aqueous solution and the carbon fiber The ratio is 25:1, the soaking temperature is 120°C, and the cleaning time is 10 minutes. Then immerse the cleaned carbon fiber in a 5% hydrogen peroxide solution with deionized water, and perform oxidation treatment in an ultrasonic instrument for 20 minutes; after the treatment is completed, use a deionized Rinse the surface of the carbon fiber with water for 5 minutes, and finally place the rinsed carbon fiber in an oven at 120°C for 2 hours;

[0024] 2) Heating stage: Send the baked carbon fiber to...

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Abstract

A technology for repairing holes and cracks on the surface of carbon fiber by using graphene films comprises the following steps: cleaning carbon fiber with a nitric acid aqueous solution, immersing the carbon fiber in a hydrogen peroxide solution, performing oxidation treatment in an ultrasonic instrument, washing the surface of the carbon fiber with deionized water, and placing the carbon fiberin an oven for baking; then, sending the baked carbon fiber into a horizontal chemical vapor deposition furnace, performing vacuumizing treatment on the chemical vapor deposition furnace, introducingargon, and then, turning on a heating device for heating; introducing argon for annealing, and continuously drawing the carbon fiber; then, switching the argon into methane and hydrogen for growth, and continuously drawing the carbon fiber; finally, removing the hydrogen and performing cooling; then, removing methane, and decreasing the temperature to room temperature or keeping the temperature atconstant temperature of 30-37 DEG C. Structure defects on the surface of the carbon fiber are repaired by graphene, the strength of the carbon fiber is improved, and effects and efficiency both adaptto industrial implementation.

Description

technical field [0001] The invention belongs to the technical field of carbon fiber surface structure defect repairing, and in particular relates to a technique for repairing holes and cracks on the carbon fiber surface with a graphene film. Background technique [0002] Because carbon fiber has high axial strength and modulus, no creep, good fatigue resistance, specific heat and electrical conductivity between non-metal and metal, small thermal expansion coefficient, good corrosion resistance, low fiber density, X-ray Due to its good permeability and other advantages, it has been extensively studied as a reinforcement material for composite materials in the fields of aerospace, transportation, energy, sports, civil engineering, etc.; however, its active specific surface area is small and its surface energy is low. The bonding force between the matrix is ​​small, so that the shear strength and bending strength of the carbon fiber composite material are very low; moreover, th...

Claims

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Application Information

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IPC IPC(8): D06M11/74D06M101/40
Inventor 刘红忠李大超陈邦道赖国泉蒋维涛叶国永
Owner XI AN JIAOTONG UNIV
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