Coating method of electrode material and coating thereof, and application of electrode material

An electrode material and coating technology, which is applied to the coating method of electrode materials and its coating and application fields, can solve the problems of increasing the cost of lithium-ion batteries, poor material cycle stability, poor conductivity, etc., and achieve improved surface interface structure Stability, reduce design and R&D costs, and facilitate the effect of industrialized mass production

Active Publication Date: 2019-06-28
INST OF CHEM CHINESE ACAD OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At present, lithium-ion battery electrode materials, especially negative electrode materials (C, Si, Ge, Sn, etc.) have problems such as large volume change, poor conductivity, and poor cycle stability of materials during cycling, which are also largely limited. The further improvement of the volume energy density of lithium-ion batteries, the further improvement of safety performance, the further optimization of cycle performance, etc., have seriously restricted the in-depth promotion of lithium-ion batteries and the development of industrial scale, especially limiting the development of high-energy-density lithium-ion batteries. further use
In the prior art, the methods for improving the performance of this type of lithium-ion battery electrode materials include polymer coating, oxide coating, fluoride coating, metal ion doping, electrolyte additives, etc., but the above solutions to battery problems The effect achieved by the method is still not ideal, and the above problems can only be alleviated by means of the optimization of the battery system and battery management system, which increases the cost of lithium-ion batteries to a certain extent, which is not conducive to the promotion of lithium-ion batteries

Method used

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  • Coating method of electrode material and coating thereof, and application of electrode material
  • Coating method of electrode material and coating thereof, and application of electrode material
  • Coating method of electrode material and coating thereof, and application of electrode material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] A method for coating an electrode with a composite material, comprising the following steps:

[0047] (1) First prepare the ethanol solution slurry of silicon nanoparticles and carbon nanotubes (mass ratio 9:1), load it evenly on the copper foil, and obtain a silicon loading per unit area of ​​1 mg / cm after drying. 2 electrode pads;

[0048] (2) The 10cm 2 Put the electrode sheet into a solution of tetrahydrofuran (20ml) and triethylamine (2ml) containing 2mg of compound 1, react at 40°C for 10 hours, and take out the electrode sheet;

[0049] (3) Treat the electrode sheet obtained in step (2) at 300°C for 1 hour under the protection of nitrogen to obtain a carbon-coated electrode sheet, the SEM image of which is shown in figure 1 . The electrochemical performance test was carried out on the uncoated electrode sheet and the carbon-coated electrode sheet. The test results are as follows: figure 2 shown.

[0050]from figure 1 It can be seen that a layer of carbon m...

Embodiment 2

[0053] A method for coating an electrode with a composite material, comprising the following steps:

[0054] (1) Firstly, the nickel oxide nanosheets are evenly loaded on the copper grid, and after drying, the nickel oxide loading per unit area is 2mg / cm 2 electrode pads;

[0055] (2) The 20cm 2 Put the electrode sheet into a solution of dichloromethane (30ml) and pyridine (2ml) containing 5mg of compound 4, react at 60°C for 20 hours, and take out the electrode sheet;

[0056] (3) Treat the electrode sheet obtained in step (2) at 150°C for 2 hours under the protection of nitrogen to obtain a carbon-coated electrode sheet, the SEM image of which is shown in image 3 .

[0057] from image 3 It can be seen that a layer of carbon material is uniformly coated on the electrode sheet supported by nickel oxide.

Embodiment 3

[0059] A method for coating an electrode with a composite material, comprising the following steps:

[0060] (1) Firstly, the iron oxide nanorods are evenly loaded on the copper foam, and after drying, the iron oxide loading per unit area is 3mg / cm 2 electrode pads;

[0061] (2) The 15cm 2 Put the electrode sheet into a solution of diethyl ether (20ml) and tetramethylethylenediamine (1ml) containing 3mg of compound 6, react at 25°C for 20 hours, and take out the electrode sheet;

[0062] (3) Treat the electrode sheet obtained in step (2) at 120°C for 3 hours under the protection of argon to obtain a carbon-coated electrode sheet. See the SEM image of Figure 4 .

[0063] from Figure 4 It can be seen that a layer of flaky carbon material can be uniformly coated on the electrode sheet supported by iron oxide.

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Abstract

The present invention discloses a coating method of an electrode material and a coating thereof, and application of an electrode material. The method comprises the following steps of: (1) putting an electrode material into a solution containing at least three alkynyl compounds for reaction, or, drying slurry comprising the electrode material and then putting the slurry comprising the electrode material to the solution containing the at least three alkynyl compounds for reaction; and (2) performing heat treatment of a reaction product obtained in the step (1) to obtain a carbon-coated electrodematerial. The method provided by the invention achieves carbon coating of various types of electrode materials difficult for carbon coating in the true sense to greatly improve the surface electricalconductivity of the electrode material, improve the low-temperature performance of the electrode, reduce the electrode structure damaging of the electrode material in the cycle process and obviouslyimprove the cycle performance and the safety performance of the electrode. The method is simple in process and easy to achieve the industrial production.

Description

technical field [0001] The invention belongs to the field of electrode materials, and in particular relates to a coating method of electrode materials, coating materials and applications thereof. Background technique [0002] In recent years, the application range of lithium-ion batteries has been expanding, from small consumer electronics products to large new energy vehicles and energy storage power stations. At the same time, consumers have higher and higher requirements for lithium-ion batteries, including energy density, fast charge and fast discharge performance, safety performance, and long cycle life of lithium-ion batteries. These requirements pose serious challenges to the system design and electrode material design of lithium-ion batteries. [0003] At present, lithium-ion battery electrode materials, especially negative electrode materials (C, Si, Ge, Sn, etc.) have problems such as large volume change, poor conductivity, and poor cycle stability of materials du...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/36H01M4/38H01M4/52H01M4/62H01M10/0525B82Y30/00B82Y40/00
CPCY02E60/10
Inventor 李玉良左自成商虹汪帆刘辉彪李勇军
Owner INST OF CHEM CHINESE ACAD OF SCI
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