The invention discloses a method for achieving defluorination and recycling of secondary aluminum ash with a series-parallel method. The method specifically includes the following steps that (1), theraw material secondary aluminum ash comprises high-
fluorine secondary aluminum ash and low-
fluorine secondary aluminum ash, and the low-
fluorine secondary aluminum ash is treated with a
Bayer process;(2), the high-fluorine secondary aluminum ash is treated with an alkali
sintering method, volatile
silicon fluoride gas is absorbed with alkali liquor, and sintered clinker is obtained; (3), the sintered clinker is immersed in water, a defluorination agent is added into
leachate, the materials are stirred, the materials are filtered, purified liquor is obtained, and after leached residues are washed, common
solid waste is obtained; and (4), a defluorinated solution is merged into the
Bayer process flow for treating the low-fluorine secondary aluminum ash according to the causticity ratio. Thelow-fluorine secondary aluminum ash and the high-fluorine secondary aluminum ash are treated with the series-parallel method, on one hand, the aqueous
leachate of the sintered clinker supplements losses of liquid alkali of the
Bayer process flow, on the other hand, most of the harmful element fluorine in the
raw material can be removed, and it is avoided that soluble fluorine enters a high-temperature high-pressure alkali
dissolution system, so that reaction equipment is corroded.